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Article
Autocatalytic Character of Anodic Polymerization of Aniline in Water–Organic Acid Solutions
A cyclic voltammetry study shows the anodic polymerization of aniline in 2 M HClO4 water–acetonitrile solutions to proceed via an EC: EC mechanism. In the chemical reaction, pernigraniline catalyzes the aniline o...
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Article
Poly(3,4-ethylenedioxythiophene) Heterogeneity: A Differential Cyclic Voltabsorptometry Study
A voltabsorptometry study of the redox behavior of poly(3,4-ethylenedioxythiophene) films in tetrabutylammonium tetrafluoroborate solutions in acetonitrile shows the polymer to exhibit heterogeneous properties...
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Article
Electrosynthesis of Poly(3,4-ethylenedioxythiophene) and Its Composite with a Polymer Perfluorinated Sulfo-Cationite from Water–Acetonitrile Solutions
Films of poly(3,4-ethylenedioxythiophene) (PEDT) are synthesized during anodic polarization from a water-acetonitrile mixture containing sulfo-cationite MF-4SK and without it. A comparison of electrochemical a...
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Article
Polybithiophene Heterogeneity: A Differential Cyclic Voltabsorptometry Study
The redox behavior of polybithiophene in 0.1 M Bu4NBF4 solutions in acetonitrile is studied using cyclic voltammetry, potentiostatic spectroelectrochemical measurements, and differential cyclic voltabsorptometry....
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Article
Redox Conversions of Poly(3,4-ethylenedioxythiophene) and Its Copolymer with Bithiophene in Aprotic Media of Different Donor Capability
Electrochemical oxidation and reduction of poly(3,4-ethylenedioxythiophene) in solvents of different donor capabilities is studied by cyclic voltammetry. The reversibility of the anodic process is dependent on...
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Article
Diffusion Impedance of Electrodes of Different Size in Isothermal and Nonisothermal Natural Convection Conditions
The impedance for a reversible K3[Fe(CN)6 ]/K4[Fe(CN)6 ] system is measured at vertical platinum disk electrodes of different diameter in isothermic natural convection conditions and during nonisothermal heating ...