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    Article

    Autocatalytic Character of Anodic Polymerization of Aniline in Water–Organic Acid Solutions

    A cyclic voltammetry study shows the anodic polymerization of aniline in 2 M HClO4 water–acetonitrile solutions to proceed via an EC: EC mechanism. In the chemical reaction, pernigraniline catalyzes the aniline o...

    E. V. Ovsyannikova, M. Yu. Grosheva, N. M. Alpatova in Russian Journal of Electrochemistry (2004)

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    Article

    Poly(3,4-ethylenedioxythiophene) Heterogeneity: A Differential Cyclic Voltabsorptometry Study

    A voltabsorptometry study of the redox behavior of poly(3,4-ethylenedioxythiophene) films in tetrabutylammonium tetrafluoroborate solutions in acetonitrile shows the polymer to exhibit heterogeneous properties...

    N. M. Alpatova, Z. A. Rotenberg, E. V. Ovsyannikova in Russian Journal of Electrochemistry (2004)

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    Article

    Electrosynthesis of Poly(3,4-ethylenedioxythiophene) and Its Composite with a Polymer Perfluorinated Sulfo-Cationite from Water–Acetonitrile Solutions

    Films of poly(3,4-ethylenedioxythiophene) (PEDT) are synthesized during anodic polarization from a water-acetonitrile mixture containing sulfo-cationite MF-4SK and without it. A comparison of electrochemical a...

    E. V. Ovsyannikova, M. Yu. Grosheva, V. V. Topolev in Russian Journal of Electrochemistry (2004)

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    Article

    Polybithiophene Heterogeneity: A Differential Cyclic Voltabsorptometry Study

    The redox behavior of polybithiophene in 0.1 M Bu4NBF4 solutions in acetonitrile is studied using cyclic voltammetry, potentiostatic spectroelectrochemical measurements, and differential cyclic voltabsorptometry....

    N. M. Alpatova, E. V. Ovsyannikova, V. V. Topolev in Russian Journal of Electrochemistry (2004)

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    Redox Conversions of Poly(3,4-ethylenedioxythiophene) and Its Copolymer with Bithiophene in Aprotic Media of Different Donor Capability

    Electrochemical oxidation and reduction of poly(3,4-ethylenedioxythiophene) in solvents of different donor capabilities is studied by cyclic voltammetry. The reversibility of the anodic process is dependent on...

    N. M. Alpatova, E. V. Ovsyannikova, F. Jonas in Russian Journal of Electrochemistry (2002)

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    Article

    Diffusion Impedance of Electrodes of Different Size in Isothermal and Nonisothermal Natural Convection Conditions

    The impedance for a reversible K3[Fe(CN)6 ]/K4[Fe(CN)6 ] system is measured at vertical platinum disk electrodes of different diameter in isothermic natural convection conditions and during nonisothermal heating ...

    Z. A. Rotenberg, M. Yu. Grosheva, V. P. Lukovtsev in Russian Journal of Electrochemistry (2002)