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Article
Technological Ways of Reducing the Sintering Temperature of Ceramics Based on Cubic Pyrochlore
Ceramics of a Bi2O3–ZnO–Nb2O5 system (cubic pyrochlore) with homogeneous microstructures, high densities, and high dielectric parameters (30% higher than in traditional ceramic technology) are obtained via spark ...
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Article
Nature of Dielectric Relaxation in SrTiO3:Mn Single Crystals
Dielectric spectra of SrTiO3 and SrTiO3:Mn single crystals have been studied in the frequency range of 10‒3000 cm–1 and in the temperature range of 5–297 K using time-domain terahertz spectroscopy and Fourier-tra...
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Article
Switching Processes in a 0.725NaNbO3–0.20KNbO3–0.075CdNb2O6 Ferroelectric Solid Solution
Results are presented from experiments on the dielectric hysteresis loops and relative dielectric permeability of 0.725NaNbO3–0.20KNbO3–0.075CdNb2O6 ceramics in strong (5–40 kV cm–1) and weak (0–0.3 kV cm–1) alte...
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Article
Multiorder and the Structural Mechanism of the LiRh2O4 Tetragonal Phase Formation
Results are presented from a group-theoretical analysis of phase transitions in LiRh2O4. It is found that the critical irreducible representation inducing phase transitions and multiorder in this substance is eig...
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Article
Bi4Ti3O12-Based Ferroelectric Ceramics Designed for Extreme Conditions
A comparative study is performed of Bi4Ti3O12-based high-temperature ferroelectric ceramics fabricated with three different types of sintering. The dependences of the microstructure, dielectric and piezoelectric ...
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Article
Effect of the Type of Sintering on the Dielectric Hysteresis of a Hard Piezoceramic Material based on Lead Zirconate Titanate
An experimental study is performed of the sintering technology effect of hard piezoceramic material PCR-8 has on its dielectric hysteresis. It is established that hot pressing and modifications of it allow the...
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Article
Dielectric Response of Ceramic 16BiScO3–42PbMg1/3Nb2/3O3–42PbTiO3 Solid Solutions in an Electrical Field
Some results of studying the dielectric and electromechanical properties of ceramic 16BiScO3–42PbMg1/3Nb2/3O3–42PbTiO3 relaxor ferroelectric samples in electrical fields (0 < E < 20 kV/cm) are presented. An appre...
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Article
Group-Theoretical Classification of Aristotypes of Cation and Anion Orders in Perovskites
A group-theoretical classification of cation and anion orders of crystals with a perovskite structure is presented. Aristotypes are idealized structures (phases), from which the low-symmetry ordered modificati...
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Article
Phase Diagrams of Solid Solutions of Relaxor Ferroelectrics from the Dielectric Spectroscopy Data
The dielectric spectra of Pb(1–z)Ba z (Mg1/3Nb2/3) m (Zn1/3Nb2/3) y (Ni1/3Nb2/3) n ...
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Article
Effect of PbNi1/3Nb2/3O3 on the Dielectric and Piezoelectric Properties of Multicomponent Solid Solutions Based on PbMg1/3Nb2/3O3–PbTiO3
The effect of PbNi1/3Nb2/3O3 addition on the dielectric and piezoelectric responses of the mPbMg1/3Nb2/3O3–nPbNi1/3Nb2/3O3–yPbZn1/3Nb2/3O3–xPbTiO3 ceramic system doped with barium is investigated. It is found tha...
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Article
Unique hyper-kagome atomic order in geometrically frustrated iridium spinel-like structures
The review briefly outlines the results of authors’ theoretical research into unique hyperkagome atomic and orbital order in geometrically frustrated iridium spinel-like structures. The structural mechanism of...
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Article
Formation of the structure and piezoelectric and dielectric properties of NaNbO3−KNbO3−CuNb2O6 solid solutions
Ceramics of the 0.5NaNbO3−(0.5–2x)KNbO3−xCuNb2O6 system at x = 0−0.05 are produced via solid phase synthesis with subsequent sintering, according to the conventional technique. It is shown that introducing copper...
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Article
Synthesis and properties of Na1–x K x NbO3-based solid solutions in the CuNb2O6–NaNbO3–KNbO3 system
(1–x–z)NaNbO3 · xKNbO3 · zCuNb2O6 (x = 0.05–0.50, z = 0.025−0.050) ceramics have been prepared by solid-state reactions followed by sintering using standard ceramic processing. Phase relations in a portion of the...
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Article
Unique hyper-kagome atomic order in the noncentrosymmetric structure of Na3Ir3O8
The formation of a unique hyper-kagome atomic order in the structure of the ordered spinel phase Na3Ir3O8 has been analyzed in terms of the Landau theory of phase transitions. We have identified a critical six-co...
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Article
Dielectric spectroscopy of Pb1–x Ba x (Mg1/3Nb2/3) m (Zn1/3Nb2/3) y (Ni1/3Nb2/3) n Ti z O3 solid solutions in a wide temperature interval
The dielectric spectra of Pb1–x Ba x (Mg1/3Nb2/3) m (Zn1/3Nb2/3) y (Ni1/3Nb2/3
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Article
Theory of the formation of P4132(P4332)-phase spinels
A group-theoretical, thermodynamic, and structural study of the formation of P4132(P4332) spinel modification has been performed. In particular, the occurrence of unique hyper-kagome atomic order is analyzed. The...
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Chapter and Conference Paper
Features of Electromagnetic Microwave Radiation Absorption by Ferroelectric Complex Niobium Oxides
The solid solutions of the niobium oxides were prepared using two-stage solid-phase synthesis and sintering by conventional technology. The dissipative characteristics of the solutions were studied experimen...
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Article
Theory of structural phase transition in MgTi2O4
A theory of phase transition in MgTi2O4 is proposed based on a study of the order-parameter symmetry, thermodynamics, and mechanisms of formation of the atomic and orbital structure of the low-symmetry MgTi2O4 ph...
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Article
Phase equilibria and electrical properties of barium-containing relaxor-based solid solutions
We have studied the effect of modification with Ba on the phase composition, structure, and electrical properties of ceramic samples of Pb(1−x)Bax(Mg1/3Nb2/3) m (Zn1/3Nb2/3) ...
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Article
Group-theoretical study of cationic ordering in perovskite structure
Atomic ordering in the structure of cubic perovskite has been investigated by the group-theoretical method. The possibility of existence of 13 ordered phases in the 1(a) position (including four binary, two terna...