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Article
Fluorination of 4-nitroisoxazoline salts. Synthesis of 4-fluoro-4-nitroisoxazolines and 4-fluoroisoxazoles
Methods for the synthesis of hitherto unknown 4-fluoro-4-nitroisoxazolines by fluorination of 4-nitroisoxazoline salts with FClO3 in MeOH and 4-fluoroisoxazoles by treatment of fluoronitroisoxazolines bearing the...
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Article
Tver' Fibres of the Armos Type: Manufacture and Properties
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Article
Tver' fibres of the Armos type: Manufacture and properties
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Article
Synthesis of several derivatives of trifluoromethyl alkyl sulfones
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The nitration of trifluoromethanesulfonylacetic acid results in the formation of trifluoromethyl nitromethyl ...
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Article
Bromination of CH-acid polynitro compounds by α-Bromopolynitroalkanes
It was shown that the nonionized CH-acid polynitro compounds HC(NO2)2R and their anions are capable of being brominated byα-bromopolynitroalkanes to give BrC(NO2)2R.
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Article
Study of the formation of free radicals in reactions of aliphatic nitro compounds by the method of radical trap**. 4. Formation of short-lived radicals when nucleophilic reagents are reacted with difluorodinitromethane in aprotic solvents
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In the reaction of difluorodinitromethane with nucleophilic reagents able to generate the anion-radical, the ...
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Article
A study of free-radical formation in reactions of aliphatic nitro compounds using radical-trap methods 3. Generation of α-halodinitromethyl radicals and their identification as nitroxyl radicals by ESR methods
Radical-trap** methods have been used to show that the photodecomposition of the halotrinitronethanes XC(N02)3 (X=F, Cl, Br) in solution (acetonitrile, diglyme) proceeds through C-N bond cleavage. Electron spin...
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Article
Dipole moments of polynitro- and α-halopolynitroalkanes
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The dipole moments of a series of polynitro-and α-halopolynitroalkanes have been measured.
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Article
Investigation of the formation of free radicals in reactions of aliphatic nitro compounds by the method of radical traps
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A series of nitroxyl radicals -products of the addition of shortlived radicals [(NO2)3Ċ, CH3Ċ(NO2)2, (CH3)2ĊN...
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Article
Reaction of polynitro- and α-halopolynitroalkanes with copper metal and cuprous salts
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Article
Formation of free radicals in reactions of tetranitromethane with nucle ophilic reagents
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Article
Investigation of the structure of diethylthallium salts of polynitroalkanes
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The structure of diethylthallium (DET) derivatives of trinitromethane, dinitromethane, and 1,1-dinitroethane ...
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Article
Electrolysis of aliphatic nitro compounds Communication 2. Electrochemical denitration of tetranitromethane and 1,1,1-trinitroethane
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On the example of the electrolysis of tetranitromethane and 1,1,1-trinttroethatie, some rules for the electro...
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Article
Electrolysis of aliphatic nitro compounds Communication 1. Electrochemical denitration of fluorctrinitromethane
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A new method was proposed for the preparation of fluorodinitromethane by the electrochemical denitration of f...
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Article
One-electron transfer during reaction of difluorodinitromethane with nucleophilic agents
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Using the ESR method it was shown that difluorodinitromethane can form the anion-radical CF2(CO2) ...
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Article
Electrochemical denitration of polynitroalkanes
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Article
Bis(fluorodinitromethyl)mercury complexes
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The complexes of bis(fluorodinitromethyl)mercury (BFM) with various aprotic solvents, which are p-donors (dim...
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Article
Detection of free radicals by the method of radical traps in the reaction of perchloryl fluoride with nucleophilic agents
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Article
Study of the association of fluorodinitromethane with aprotonic solvents by the PMR method
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The chemical shifts of the proton of fluorodinitromethane in a series of aprotonic solvents were studied at v...
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Article
Raman spectra of polynitro- andα-halopolynitroalkanes
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The intensities of a number of lines of the symmetric stretching and deformation vibrations of the C-NO2 grou...
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