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  1. No Access

    Chapter

    Romp and Related Chemistry: Past, Present and Fututre

    The history of the development of ring-opening metathesis polymerization (ROMP), and the related reactions of olefin metathesis (OM), ring-closing metathesis (RCM), asymmetric ring-closing metathesis (ARCM), a...

    K. J. Ivin in Ring Opening Metathesis Polymerisation and Related Chemistry (2002)

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    Chapter

    Overture

    The development of the subject is traced from its origins in the discovery of ring-opening polymerization of cycloalkenes and the disproportionation of olefins, via the demonstration of double bond cleavage to...

    K. J. Ivin in Olefin Metathesis and Polymerization Catalysts (1990)

  3. No Access

    Chapter

    Tacticity in Polymers Initiated by Metathesis Polymerization: Effect of Catalyst

    Tacticity is defined in relation to ring opening metathesis polymerization and some predictions about tacticity are made on the basis of a mechamsm in which the propagating metal-carbene complex has a chiral m...

    K. J. Ivin in Olefin Metathesis and Polymerization Catalysts (1990)

  4. No Access

    Chapter

    The Metathesis Polymerization of Norbornene and Its Derivatives Initiated By Tungsten-Carbene Complexes: Relative Stability of the Intermediate Tungstenacyclo-Butane Complexes

    The early stages of the metathesis polymerization of norbomene and some of its endo derivatives, initiated by tungsten-carbene complexes of the type W(CR1R2)(OR3)2Br2.GaBr3, were followed in CD2Cl2 at 200–260 K b...

    K. J. Ivin, J. Kress, J. A. Osborn, J. J. Rooney in Advances in Metal Carbene Chemistry (1989)