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Article
Process Improvements in Methanol Oxidation to Formaldehyde: Application and Catalyst Development
Compared with oxide catalysts for many other selective oxidation and ammoxidation processes, the commercial iron molybdate type catalyst for the oxidation of methanol to formaldehyde has an outstanding perform...
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Chapter
Combination of many-body perturbation theory and quantum electrodynamics
A procedure for energy-dependent perturbation expansion has been developed, based upon the covariant evolution operator method. This makes it possible to treat energy-dependent perturbations very much like the...
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Article
Combination of many-body perturbation theory and quantum electrodynamics
A procedure for energy-dependent perturbation expansion has been developed, based upon the covariant evolution operator method. This makes it possible to treat energy-dependent perturbations very much like th...
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Article
Substituted Mo–V(Ti)–Te(Ce)-oxide M2 Catalysts for Propene Ammoxidation
One of the most effective propane to acrylonitrile ammoxidation catalyst is comprised of the two phases M1 (orthorhombic) Mo7.5V1.5NbTeO29 and M2 (pseudo-hexagonal) Mo4V2Te2O20. Under reaction conditions, the two...
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Article
On the Synergy Effect in MoO3–Fe2(MoO4)3 Catalysts for Methanol Oxidation to Formaldehyde
Methanol oxidation to formaldehyde was studied over a series of Fe–Mo–O catalysts with various Mo/Fe atomic ratio and the end compositions Fe2O3 and MoO3. The activity data show that the specific activity passes ...
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Article
Catalytic effects in propene ammoxidation achieved through substitutions in the M2 phase of the Mo–V–Nb–Te-oxide system
M2-type phases M3TeO10 (M = Mo and V), belonging to the Mo–V–Nb–Te-oxide system, were prepared by substituting to various degrees the M-metal with W, Ti, Nb or Fe, and Te with Ce. The compositions were characteri...
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Article
Active centers, catalytic behavior, symbiosis and redox properties of MoV(Nb,Ta)TeO ammoxidation catalysts
Selective as well as waste forming active centers were defined for MoVNbTeO and MoVTaTeO catalysts in the ammoxidation of propane to acrylonitrile and all catalytic functionalities were assigned to specific el...
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Article
A Study of the Functionalities of the Phases in Mo–V–Nb–Te Oxides for Propane Ammoxidation
Catalysts belonging to the Mo–V–Nb–Te–O system have been prepared with both a slurry method and hydrothermal synthesis and were tested for propane and propylene ammoxidation to acrylonitrile. All samples were ...