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Article
An interior penalty approach to a large-scale discretized obstacle problem with nonlinear constraints
We propose an interior penalty method to solve a nonlinear obstacle problem arising from the discretization of an infinite-dimensional optimization problem. An interior penalty equation is proposed to approxim...
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Article
A power penalty approach to a discretized obstacle problem with nonlinear constraints
A novel power penalty method is proposed to solve a nonlinear obstacle problem with nonlinear constraints arising from the discretization of an infinite-dimensional optimization problem. This approach is based...
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Article
Electrochemical Proton Reductions Catalyzed by the Simpler Hexacoordinate Iron Compounds as Functional Mimics of the Active Site in [FeFe] Hydrogenase
Ligand-substitution reaction of [(μ-S2C4N2H2)Fe2(CO)6] (1) generated a normal mono-substituted diiron dithiolate derivative [(μ-S2C4N2H2)Fe2(CO)5(PMe3)] (1P) and a simpler hexacoordinate mononuclear compound [(μ-...
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Article
Influence of the methylene group between azadithiolate nitrogen atom and phenyl moiety on the protophilic properties of [FeFe]-hydrogenase model complexes
An [FeFe]-hydrogenase mimic 4 with functional benzyl moiety covalently linked to the azadithiolate ligand was synthesized. The structure, protonation, and electrochemical properties of 4 and a phenyl substituted ...
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Article
An artificial [FeFe]-hydrogenase mimic with organic chromophore-linked thiolate bridges for the photochemical production of hydrogen
An artificial [FeFe]-hydrogenase ([FeFe]-H2ase) mimic 3II, consisting of dual organic chromophores covalently assembled to the [Fe2S2] active site, was constructed for light-driven hydrogen evolution. The structu...
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Article
Improved outcomes after complete resection of underlying tumors for patients with paraneoplastic pemphigus: a single-center experience of 22 cases
Paraneoplastic pemphigus (PNP) is an autoimmune-related acquired bullous disease. Delayed diagnosis and treatment of this clinically rare disease often result in poor prognosis.
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Article
Carcinoma of the Ampulla of Vater: Factors Influencing Long-term Survival of 127 Patients with Resection
The prognosis for patients with carcinoma of the ampulla of Vater is improved relative to other periampullary neoplasms. Identification of independent prognostic factors in ampullary carcinomas has been limite...