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Article
Long-term continuous ammonia electrosynthesis
Ammonia is crucial as a fertilizer and in the chemical industry and is considered to be a carbon-free fuel1. Ammonia electrosynthesis from nitrogen under ambient conditions offers an attractive alternative to the...
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Article
Open AccessPhenol as proton shuttle and buffer for lithium-mediated ammonia electrosynthesis
Ammonia is a crucial component in the production of fertilizers and various nitrogen-based compounds. Now, the lithium-mediated nitrogen reduction reaction (Li-NRR) has emerged as a promising approach for ammo...
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Article
Calcium-mediated nitrogen reduction for electrochemical ammonia synthesis
Ammonia (NH3) is a key commodity chemical for the agricultural, textile and pharmaceutical industries, but its production via the Haber–Bosch process is carbon-intensive and centralized. Alternatively, an electro...
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Article
Open AccessA spin promotion effect in catalytic ammonia synthesis
The need for efficient ammonia synthesis is as urgent as ever. Over the past two decades, many attempts to find new catalysts for ammonia synthesis at mild conditions have been reported and, in particular, man...
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Article
Monitoring oxygen production on mass-selected iridium–tantalum oxide electrocatalysts
Development of low-cost and high-performance oxygen evolution reaction catalysts is key to implementing polymer electrolyte membrane water electrolysers for hydrogen production. Iridium-based oxides are the st...
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Article
Author Correction: A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements
An Amendment to this paper has been published and can be accessed via a link at the top of the paper.
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Article
Considerations for the scaling-up of water splitting catalysts
A wealth of candidates are being investigated to improve the catalysts found in acidic and alkaline electrolysers. However, attention should be focused on develo** stable water oxidation catalysts with impro...
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Article
A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements
The electrochemical synthesis of ammonia from nitrogen under mild conditions using renewable electricity is an attractive alternative1–4 to the energy-intensive Haber–Bosch process, which dominates industrial amm...
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Article
Polyol Synthesis of Cobalt–Copper Alloy Catalysts for Higher Alcohol Synthesis from Syngas
Novel catalysts for the selective production of higher alcohols from syngas could offer improved pathways towards synthetic fuels and chemicals. Cobalt–copper alloy catalysts have shown promising results for t...
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Article
Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2− clusters
Identifying and understanding the active sites responsible for reaction turnover is critical to develo** improved catalysts. For the hydrogen-evolution reaction (HER), MoS2 has been identified as an active non-...
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Article
Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
Controlling surface structure at the atomic scale is paramount to develo** effective catalysts. For example, the edge sites of MoS2 are highly catalytically active and are thus preferred at the catalyst surface...
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Article
Size-dependent structure of MoS2 nanocrystals
Molybdenum disulphide nanostructures are of interest for a wide variety of nanotechnological applications ranging from the potential use of inorganic nanotubes in nanoelectronics to the active use of nanoparti...
