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105 Result(s)
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Article
Reforming of Refinery Gas, Air and Steam to Syngas for Ammonia Feedstock Over Modified Ni/α-Al2O3 Catalysts
Stability and 40 h life tests of modified Ni/α-Al2O3 catalysts for refinery gas/air/H2O (g) were carried out by a flow-reactor and XRD. The results indicate that the resistance to carbon deposition, activity and ...
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Article
Preparation and properties of polytetrafluoroethylene-modified polyacrylate via emulsion polymerization
One method of preparation of polytetrafluoroethylene(PFTE)-modified polyacrylate emulsion has been studied. Through pre-emulsion technology, PTFE powder could be dispersed by high speed shearing with high-spee...
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Article
Computer Simulation of Surface Tension for Complex Emulsion System
The computer simulation of surface tension for the complex emulsion systems of polytetrafluoroethylene (PTFE) modified polyacrylate were carried out in this paper. A mathematical model was founded using statis...
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Article
Synthesis of polytetrafluoroethylene/polyacrylate core-shell nanoparticles via emulsifier-free seeded emulsion polymerization
Polytetrafluoroethylene (PTFE)/polyacrylate core-shell nanoparticles were produced via the emulsifier-free seeded emulsion polymerization of acrylate monomers with PTFE latex as seed. The monomer conversions u...
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Article
Effect of the Ratio of Precipitated SiO2 to Binder SiO2 on Iron-based Catalysts for Fischer–Tropsch Synthesis
The effects of the ratio of precipitated SiO2 to binder SiO2 (Si(P)/Si(B)) on the reduction, carburization and catalytic behavior of precipitated Fe–Cu–K–SiO2 catalysts for Fischer–Tropsch synthesis (FTS) were in...
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Article
Electrochemiluminescence of tri(2,2′-bipyridine)ruthenium in aqueous solution on a gold-nanoparticle-modified glassy carbon electrode
The electrochemical behavior of electrochemical deposition of Au nanoparticles onto a glassy carbon electrode (GCE) and its application for the electrocatalytic electrogenerated chemiluminescence (ECL) of Ru(bpy)
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Article
Supramolecular self-assembly of two Cu(II) complexes with 1,2,4-triazole derivatives: syntheses, crystal structures and magnetic properties
Two two-dimensional coordination complexes, {[Cu4(BTM)6(OPA)4] · 4DMF · 3H2O} n (1) and {[Cu(BDTM)(OH)](ClO4) · 2H2O} n (2) (BTM = bis(1,2,4-t...
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Article
Kinetics of the Electrocatalytic Oxidation of 2,2-Dimethylolpropionaldehyde
A new method of synthesis 2,2-dimethylolpropionic acid from 2,2-dimethylolpropionaldehyde was put forward. The electrochemical oxidation behavior of 2,2-dimethylolpropionaldehyde has been investigated on a Ti/SnO
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Article
Direct Conversion of Glycerol into 1,3-Propanediol over Cu-H4SiW12O40/SiO2 in Vapor Phase
Using a SiO2 supported copper and H4SiW12O40 catalyst, it is demonstrated that glycerol can be directly converted to 1,3-Propanediol (1,3-PD) through vapor-phase process under pressure below 0.54 MPa, without emp...
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Article
Theoretical study of water-assisted hydrolytic deamination mechanism of adenine
The water-assisted hydrolytic deamination mechanism of adenine was studied using density functional method at B3LYP/6-311G(d,p) level. Intrinsic reaction coordinate (IRC) calculations were performed on the tra...
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Article
Multi-objective simultaneous prediction of waterborne coating properties
Multi-objective simultaneous prediction of waterborne coating properties was studied by the neural network combined with programming. The conditions of network with one input layer, three hidden layers and one...
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Article
Synthesis, characterization and spectra studies on Zn(II) and Cu(II) complexes with thiocarbamide ligand containing Schiff base group
The ligand of 4-phenyl-1-(1-phenylethylidene)thiosemicarbazide (HL) and its metal complexes of ZnL2 (1) and CuL2 (2) have been synthesized. Elemental analysis, IR and X-ray single crystal diffraction characteriza...
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Article
Transient Brewster angle reflectometry of spiropyran monolayers
Brewster angle reflectometry has been developed as a tool for determining the absorbance and refractive index changes in molecular monolayers containing spiropyran. The method is sensitive to changes in both t...
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Article
Selective synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over MCM-22 modified by MgO
Selective synthesis of ethylbenzene by vapor phase alkylation of benzene with diethyl carbonate was carried out over MCM-22 modified by MgO. Characterization results show that the number of Brønsted acid sites...
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Article
Multi-scales association modeling of membrane water resistance indexes
In order to quantify and predict the water resistance of membrane, a multi-scales association model was built up based on the Fick’s second law. Two water resistance indexes, balance time and seepage velocity,...
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Article
Characterization and thermal behavior of kaolin
The decomposition behavior of kaolin samples has been carried out by simultaneous TG–DTA experiments. New layer-structure formation during the calcination process was found, and metakaolin compound was detecte...
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Article
Selective Catalytic Reduction of NO with CH4 Over In–Fe/Sulfated Zirconia Catalysts
In–Fe loaded sulfated zirconia (SZ) was firstly studied for the selective catalytic reduction (SCR) of NO with methane and exhibited higher activity than In/SZ and Fe/SZ. The addition of iron to the In/SZ incr...
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Article
Silver nanoparticles/poly(2-(N-morpholine) ethane sulfonic acid) modified electrode for electrocatalytic sensing of hydrogen peroxide
A sensitive amperometric hydrogen peroxide (HP) sensor was constructed based on silver nanoparticles/poly(2-(N-morpholine) ethane sulfonic acid) (PMES) modified glassy carbon electrode. PMES and silver nanopartic...
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Article
Crystal structure and thermal decomposition mechanism of a 5-aminotetrazole copper(II) complex
A novel 5-aminotetrazole mixed ligands complex of formula [Cu(PTS)2(ATZ)2(H2O)2] (C16H24CuN10O8S2, PTS = p-toluenesulfonate, ATZ = 5-aminotetrazole) has been obtained by the reaction of 5-aminotetrazole with copp...
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Article
Preparation of Porous Hollow SiO2 Spheres by a Modified Stöber Process Using MF Microspheres as Templates
Using the surface charged and acid dissolvable melamine formaldehyde (MF) microspheres as sacrificial hard templates, silica coated MF core–shell composite microspheres, denoted as MF@SiO2, were synthesized via a...