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Article
Polyoxometalate as the assembly material to self-assembled Ni(OH)2 nanosheets with electrocatalytic performance
Develo** non-noble metal-based electrocatalyst with high catalytic activity is essential for advancing hydrogen energy technologies. This study introduces a hydrothermal method for synthesizing order Ni(OH)2 na...
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Article
A new 4-Ti-added polyoxometalate
A new inorganic–organic hybrid 4-Ti-added polyoxometalate: [H2N(CH3)2]2Na3H5[{Ti(C2O4)(H2O)}2{Ti(C2O4)}2(B-β-SbW9O33)2]·22H2O (1) has been successfully made and further characterized by infrared spectroscopy, the...
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Article
Open AccessPseudorabies virus hijacks the Rab6 protein to promote viral assembly and egress
Pseudorabies virus (PRV) is recognized as the aetiological agent responsible for Aujeszky’s disease, or pseudorabies, in swine populations. Rab6, a member of the small GTPase family, is implicated in various m...
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Article
Nanocomposite: Keggin-type Co4-polyoxometalate@cobalt-porphyrin linked graphdiyne for hydrogen evolution in seawater
Polyoxometalate-based nanocomposites with electrocatalytic activity have been applied in hydrogen evolution reactions (HER). Seawater as the main water resource on the earth should be developed as the water el...
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Article
Open AccessRhoA suppresses pseudorabies virus replication in vitro
The porcine pseudorabies virus (PRV) is one of the most devastating pathogens and brings great economic losses to the swine industry worldwide. Viruses are intracellular parasites that have evolved numerous st...
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Article
Optimization of mammalian expression vector by cis-regulatory element combinations
The regulation of gene expression in mammalian cells by combining various cis-regulatory features has rarely been discussed. In this study, we constructed expression vectors containing various combinations of ...
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Article
Preface to the special issue on Oxo clusters and coordination polymers (Part one)
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Article
Atomically-precise Janus polyoxometalate catalyst with tunable water splitting activity
The development of bifunctional catalysts for solar-driven hydrogen and oxygen evolution has been regarded as a challenging but interesting research topic. As promising multi-electron-transfer catalysts, repor...
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Article
A new 28-Ni-added poly(polyoxometalate) with B atoms: synthesis, structure and catalysis for Knoevenagel condensation
The synergistic effect of trivacant B-α-GeW9O34 fragments as structure-directing agents and inorganic B-O segments as intramolecular decoration afforded an unprecedented 28-Ni-added huge cluster K2Na14H10[{Ni6(OH...
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Article
Cooperation between covalent organic frameworks (COFs) and metal organic frameworks (MOFs): application of COFs-MOFs hybrids
The application and development of porous materials have a long history. With the deepening of study, more and more advanced organic porous materials and organic–inorganic porous materials have been designed a...
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Article
Recent advances of mixed-transition-metal-substituted polyoxometalates
Polyoxometalates (POMs) have been emerging as one of the most widely-studied interdisciplinary research fields of inorganic chemistry due to their structural diversities and versatile physicochemical propertie...
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Article
A Zr-Substituted Polyoxotungstate Built by [β-GeW10O38]12− and [A-α-PW9O34]9− Fragments: Synthesis, Structure and Properties
A new Zr-substituted polyoxotungstate, [H2N(CH3)2]11KNa5H7[Zr4K2(β-GeW10O38)2(A-α-PW9O34)2]·39H2O (1), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR spectrum, UV–vi...
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Article
A ring-shaped 12-Ti-substituted poly(polyoxometalate): synthesis, structure, and catalytic properties
A new ring-shaped 12-Ti-substituted poly(polyoxometalate) (poly(POM)), K10H15[{K2Na(H2O)3}@{(Ti2O)2(Ti4O4)2(A-α-1,3,5-GeW9O36)2(A-α-2,3,4-GeW9O36)2}]·45H2O (1), has been made under hydrothermal conditions, showin...
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Article
An unprecedented dumbbell-shaped pentadeca-nuclear W-Er heterometal cluster stabilizing nanoscale hexameric arsenotungstate aggregate and electrochemical sensing properties of its conductive hybrid film-modified electrode
Cluster-based functional materials have made remarkable progress owing to their wonderful structures and distinctive physicochemical performances, one of on-going advancements of which is basically driven by s...
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Article
A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units
A new mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, U...
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Article
Open AccessCRISPR/Cas9-based generation of a recombinant double-reporter pseudorabies virus and its characterization in vitro and in vivo
Pseudorabies, caused by pseudorabies virus (PRV) variants, has broken out among commercial PRV vaccine-immunized swine herds and resulted in major economic losses to the pig industry in China since late 2011. ...
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Article
Impact of the disclosure of diagnosis on posttraumatic stress and growth and quality of life in Chinese patients with hepatocellular carcinoma
To evaluate the impact of disclosure/nondisclosure of cancer diagnosis on patients’ posttraumatic stress symptoms (PTSS), posttraumatic growth (PTG), and quality of life (QOL).
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Article
Two α2-Monozirconium-Substituted Dimeric Silicotungstates: Hydrothermal Synthesis, Structural Characterization and Catalytic Oxidation of Thioethers
A novel di-ZrIV-substituted sandwich-type silicotungstate (NH4)2(TMA)6[Zr2(μ-OH)2(α-HSiW11O39)2]·18H2O (1, TMA = tetramethylammonium) and a previously unknown EDTA bridging mono-ZrIV-substituted silicotungstate d...
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Article
Syntheses, Structures and Characterizations of Two New Polyborates Containing Heptaborate Sub-clusters
Two new polyborates [(CH3NH3)4][B14O20(OH)6] (1) and [Zn(en)2{B7O10(OH)3}] (2, en = ethylenediamine), which are constructed by different types of B7 clusters, had been synthesized under solvothermal conditions by...
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Article
Five Transition-Metal-Substituted Polyoxometalates: Syntheses, Structures and Electrochemical Properties
A series of transition metal, such as Ni/Mn/Zn, substituted sandwich-type polyoxometalates, H9Na(enMe)3[Ni4(H2O)2(PW9O34)2]·31H2O (1), H8Na2[Ni4(H2O)2(PW9O34)2]·34H2O (2), H8Na2[Mn4(H2O)2(PW9O34)2]·29H2O (3), H4N...
