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Article
Open AccessElectrosynthesis of buckyballs with fused-ring systems from PCBM and its analogue
[6,6]-Phenyl-C61-butyric acid methyl ester (PCBM), a star molecule in the fullerene field, has found wide applications in materials science. Herein, electrosynthesis of buckyballs with fused-ring systems has been...
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Living Reference Work Entry In depth
Transition Metal Salt-Catalyzed Reactions of [60]Fullerene
Transition metal salt-catalyzed reactions of [60]fullerene have been one of the most powerful methods for the chemical modifications of [60]fullerene and have attracted extensive attention due to their high se...
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Reference Work Entry In depth
Transition Metal Salt-Catalyzed Reactions of [60]Fullerene
Transition metal salt-catalyzed reactions of [60]fullerene have been one of the most powerful methods for the chemical modifications of [60]fullerene and have attracted extensive attention due to their high se...
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Article
Tribocatalysis: challenges and perspectives
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Chapter
Functionalization of [60]Fullerene via Palladium-Catalyzed C–H Bond Activation
The palladium-catalyzed C–H bond activation strategy has been successfully applied to fullerene chemistry, and several types of [60]fullerene-fused heterocycles and carbocycles have been obtained. The synthesi...
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Article
Ruthenium carbene initiated ring-open metathesis polymerization of endo-bicyclo[3.2.0]hept-6-en-3-yl benzoates with tacticity studies
After tentative ring-opening cross metathesis (ROCM) of endo-bicyclo[3.2.0]hept-6-en-3-yl 4-bromobenzoate with PhCH=CH2 initiated by (Cy3P)2Cl2Ru=CHPh in CH2Cl2, ring-opening metathesis polymerization (ROMP) of a...
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Article
Calculations and assignments of endohedral helium-3 chemical shifts of open-cage fullerenes and higher fullerenes
The endohedral 3He NMR chemical shifts of open-cage fullerene compounds and higher fullerenes 3He@C n (n = 82, 84, 86) have been calculated at the GIAO-B3LYP/3-21G//AM1 level. T...
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Article
A novel coenzyme NADH model 1-benzyl-1,4-dihydronicotinamide-mediated reaction: a single intermediate serves two mechanisms
Thermal reaction of ethyl (2Z)-4-bromo-2-cyano-3-(2-naphthyl)but-2-enoate (BCNB) with coenzyme NADH model 1-benzyl-1,4-dihydronicotinamide (BNAH) gives the debrominated cyclized product (E)-1-cyano-2-methyl-2-(2-...
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Article
Erratum: Synthesis and X-ray structure of dumb-bell-shaped C120
Nature 387, 583–586 (1997) In this Letter, we overlooked a citation of G. Oszlanyi et al. , Phys. Rev. B 54, 11849 (1996), who reported the observation of covalently bound (C60)22− dianions from the X-ray powd...
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Article
Synthesis and X-ray structure of dumb-bell-shaped C120
The discovery and large-scale synthesis of fullerenes have aroused interdisciplinary interest in these closed-cage molecules1,2,3,4,5,6. C60 can be photopolymerized into a form in which the cages are thought to b...
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Article
Synthesis and characterization of cleavable cationic surfactants with a 1,3-dioxane ring
A series of cationic cleavable surfactants was prepared by condensation of 2-alkyl-1,3-propanediols with 3-bromopropanal, followed by reaction with triethylamine. Each surfactant is a mixture of two diastereom...
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Article
Preparation and properties of sulfonate salt-type cleavable surfactants with a 1,3-dioxane ring
A series of di-anionic cleavable surfactants were prepared by the condensation of aldehydes with 2,2-bis(hydroxymethyl)-1,3-propanediol, followed by reaction with 1,3-propanesultone in the presence of sodium hydr...
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Article
Preparation and properties of cleavable dianionic surfactants with a 1,3-dioxane ring
Some cleavable dianionic surfactants were prepared by the reaction of aldehydes with diethylbis(hydroxymethyl)-malonate, followed by saponification with sodium hydroxide. The critical micelle concentrations of th...