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Article
Ferric perchlorate-mediated radical reactions of [60]fullerene
Transition-metal-salt-mediated radical reactions of fullerenes have attracted extensive attention as a new and important method for fullerene functionalization. The application of relatively cheap and easily a...
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Article
Open AccessFerric perchlorate-promoted reaction of [60]fullerene with β-keto esters
The ferric perchlorate-promoted reaction of [60]fullerene (C60) with ethyl 2-methylacetoacetate generates fullerenyl hemiketal as a mixture of trans and cis isomers, while the reaction with ethyl acetoacetate giv...
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Article
Manganese(III) acetate-mediated radical reaction of [60]fullerene with bromoacetic acid, 3-chloropropionic acid or 1-naphthylacetic acid
The manganese(III) acetate-mediated radical reaction of [60]fullerene (C60) with three carboxylic acids, that is, bromoacetic acid, 3-chloropropionic acid, and 1-naphthylacetic acid, was investigated. The reactio...