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Article
Open AccessCoordination cages integrated into swelling poly(ionic liquid)s for guest encapsulation and separation
Coordination cages have been widely reported to bind a variety of guests, which are useful for chemical separation. Although the use of cages in the solid state benefits the recycling, the flexibility, dynamic...
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Article
Graphite paste electrodes modified with a sulfo-functionalized metal-organic framework (type MIL-101) for voltammetric sensing of dopamine
The metal-organic frameworks MIL-101 and sulfo-MIL-101 were used to modify graphite paste electrodes (GPEs) to obtain sensors for determination of dopamine (DA). Taking advantage of the catalytic activity of m...
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Article
Synthesis, Structure, and Properties of a Cadmium Coordination Polymer with 4-sulfonyl-2,6-naphthalenedicarboxylate
A novel coordination polymer with 4-sulfonyl-2,6-naphthalenedicarboxylic acid (H3SNDC), {[Cd3(NDSC)2(H2O)10]·6H2O}n (1), has been prepared and characterized by single-crystal X-ray diffraction. The title compound...
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Article
Synthesis, structure, and photoluminescence of a zinc(II) coordination polymer with 4-(tetrazol-5-yl)benzoate
A new coordination polymer with interesting supramolecular architecture, [Zn(4-tzbz)] n (1) (4-tzbz = 4-(tetrazol-5-yl)benzoate), has been synthesized and characterized structur...
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Article
Supramolecular Network via Hydrogen Bonding and π–π Stacking in 4,4′-Bipyridin-1-ium Perchlorate Dihydrate
The crystal structure of 4,4′-bipyridin-1-ium perchlorate dihydrate, [C10H9N2](ClO4) · 2H2O, is determined by room temperature X-ray diffraction. The compound crystallizes in the triclinic space group P-1 with a ...
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Article
Synthesis, crystal structure, and properties of copper(II) and manganese(II) complexes with azide and 3,4-di(2′-pyridyl)-1,2,5-oxadiazole
Two transition metal complexes with azide and 3,4-di(2′-pyridyl)-1,2,5-oxadiazole (dpo), [Cu2(dpo)2(N3)4] (1), and [Mn(dpo)2(N3)2] (2), have been synthesized and characterized by single-crystal X-ray diffraction....
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Article
Crystal structure of the addition compound of [Ni(meso-cth)][Cr(ox)2(bpy)](H2O)(ClO4) with weak coordination bonds and hydrogen bonds
A new ionic complex [Ni(meso-cth)][Cr(ox)2(bpy)](H2O)(ClO4) [meso-cth = meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, ox = oxalato ainon, bpy = 2,2′-bipyridine] was prepared and its structure ...
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Article
Spin topology and ferromagnetic coupling: synthesis and magnetic properties of [CuII3CrIII] tetranuclear complexes of [14]N4 macrocyclic oxamides
Three novel tetranuclear macrocyclic complexes, [(CuL1)3Cr](ClO4)3·3H2O (1), [(CuL2)3Cr](ClO4)3·3H2O (2) and [(CuL3)3Cr](ClO4)3·3H2O (3) [L1, L2 and L3 are the dianions of three [14]N4 and [15]N4 macrocyclic oxam...
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Article
Magnetic properties of new copper(II) and [copper(II)]3-manganese(II) complexes of [14]N4 macrocyclic oxamides
Four new complexes of [14]N4 macrocyclic oxamides, namely [CuL1], [CuL2], [(CuL1)3Mn](ClO4)3 and [(CuL2)3 Mn](ClO4)3 [L1 and L2 are the dianions of 2,3-dioxo-5,6: 3,14-dibenzo-7,12-bis(ethoxycarbonyl)-1,4,8,11...