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Article
Reduction of NO by CH4 with Microwave Heating
The reduction of NO by CH4 in the presence of excess O2 over Co/HZSM-5, Ni/HZSM-5 and Mn/HZSM-5 catalysts with microwave heating was studied. By comparing the activities of the catalysts in the microwave heating ...
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Article
Enhancement of Molar Heat Capacity of Nanostructured Al2O3
The nanosized alumina prepared by the hydrolysis method with an average particle size of 20 nm was characterized by X-ray diffraction. The heat capacity measurements of the prepared sample were carried out usi...
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Article
Kinetics of the Selective Reduction of NO with CH4 Over an In-Fe2O3/HZSM-5 Catalyst
A kinetic model presented for the selective reduction of NO with CH4 over an In-Fe2O3/HZSM-5 catalyst by considering the process as a combination of two simultaneous reactions: NO+O2+CH4 (reaction 1) and O2+CH4 (...
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Article
Studies of the roles of Sn or Fe on γ-Al2O3-supported Pt catalysts by CO adsorption microcalorimetry and dehydrogenation reaction of C4 alkanes
CO adsorption microcalorimetry was employed in the study of γ-Al2O3-supported Pt, Pt-Sn and Pt-Fe catalysts. The results indicated that the initial differential heat of CO adsorption of the Pt/γ-Al2O3 catalyst wa...
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Article
A study on the reduction behavior of silica supported iron and platinum-iron catalysts
The reduction behavior of silica supported iron and platinum-iron catalysts were studied by combinedin situ temperature programmed reduction (TPR)-Mössbauer Spectroscopy (MBS). The results indicated that the TPR ...
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Article
Pt LIII-edge XANES and EXAFS studies on γ-Al2O3 supported Pt catalysts
Pt LIII-edge XANES and EXAFS were employed to investigate the nature of Pt/γ-Al2O3, Pt−Sn/γ-Al2O3 and Pt−Fe/γ-Al2O3 catalysts. The results indicated that Pt species on these catalysts were all in the oxidized sta...
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Article
Interaction of methane with surfaces of silica, aluminas and HZSM-5 zeolite. A comparative FT-IR study
Infrared investigations on the interaction of methane with silica, aluminas (η,γ and α) and HZSM-5 zeolite have been carried out. At low temperature (173 K), methane adsorption was observed over these oxides a...