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Article
Near-field photoconductivity imaging of a conjugated polymer blend
We report combined scanning near-field optical microscopy (SNOM) and near-field photocurrent (NPC) imaging of a binary conjugated polymer blend. We find phase separation on a scale of about 5 μm, with a good c...
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Article
Managing the dispersal of ladybird beetles (Col.: Coccinellidae): Use of artificial honeydew to manipulate spatial distributions
We tested whether large-scale distributions of aphidophagous ladybirds could be manipulated by localized application of artificial honeydew. In addition to enhancing local build-up of ladybird numbers (e.g., in a...
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Article
Chemistry and structural modulations in Bi2Sr2CuO6
A series of samples along the composition lines Bi2+xSr2−xCuOy, and Bi2Sr2−xCuOy have been used to study the structural modulation, chemistry, and superconducting properties of pseudo-tetragonal Bi2Sr2CuO6 (2201)...
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Chapter and Conference Paper
Phase Instability at the Maximum Tc in Oxide Superconductors: Phase Separation in La2CuO4+x, Nd2−xCexCuO4, and La2−xSrxCuO4
Observation of similar behavior in three different superconducting oxides suggests that the maximum Tc is limited by phase instability. These conclusions are based on previously published neutron powder diffracti...
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Chapter
Powder Neutron Diffraction Study of the Structural Phase Diagram of the Ba1−xKxBiO3 System
In this article we present a brief report of recent work carried out to elucidate the phase diagram of the Ba1−xKxBiO3 system. A full account of this investigation will be published shortly.1
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Article
Structural Phase Diagram and Superconducting Behavior of the Ba1-Xkxbio3 System
We have determined the crystal structures of five phases in the Bal-xKxBiO3 system for 0≤x≤0.5 and 10K≤T≤473K. Superconductivity occurs only in a cubic perovskite phase with the maximum Tc at the transition to an...
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Article
Evidence for Phonon-Mediated Coupling in Superconducting Ba0.6K0.4BiO3
Superconducting Ba0.6K0.4BiO3, with a Tc of 30K, shows a large18O isotope effect which indicates that phonons are involved in the pairing mechanism. Infrared reflectivity measurements indicate a value for the sup...
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Article
Superconducting and Structural Properties of the (Ba0.6K0.4) (Bi1-YSbY)O3 System
Single-phase samples of (Ba1-xKx)(Bi1-xSby)O3 have been synthesized over a limited compositional range using a two-step procedure: high-temperature firing in a low oxygen partial pressure followed by low-temperat...
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Article
Composition of Superconducting La2CuO4+δ a Superconductor Doped by excess Oxygen Defects
We have studied mixed-phase samples of bulk LazCuO4 using neutron powder diffraction, thermogravimetric analysis and resistivity measurements. Samples fired at 950°C and slowly cooled form in the K2NiF4 structure...
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Chapter
La2MO4+δ (M=Cu, Ni, Co): Phase Separation and Superconductivity Resulting from Excess Oxygen Defects
The structural, superconducting and normal-state properties of La2MO4+δ (M=Cu, Ni, Co) were studied by neutron powder diffraction, thermogravimetric analysis and resistivity measurements. La2CuO4+δ was found to u...
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Article
Erratum: The oxygen isotope effect in Ba0.625K0.375BiO3
Nature 335, 419-421 (1988). THE correct version of Fig. 16 is shown below.
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Article
The oxygen isotope effect in Ba0.625K0.375BiO3
The nature of the superconducting pairing mechanism in the high-temperature superconducting oxides is still an open question. Shortly after the discovery of these materials, several groups began an intensive s...
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Article
Synthesis, structure and superconductivity in the Ba1−xKxBiO3−y system
The recent discovery of superconductivity near 30 K in Ba1−xKxBiO3−y (x≈0.4)1,2 is remarkable for two reasons. It is the first copper-free oxide superconductor that has a transition temperature (Tc) above that fo...