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Article
Influence of oligomeric unsaturated polyketone on the vulcanization of elastomeric compositions in the presence of sulfenamide C
Effect of the oligomeric unsaturated polyketone (UPK) additive on the rheological properties, vulcanization, and structural characteristics of elastomeric compositions based on butadiene and nitrile-butadiene ...
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Article
Modification of Compounds Based on Ethylene–Propylene–Diene Rubbers Using an Oligomeric Unsaturated Polyketone
The efficiency of using an oligomeric unsaturated polyketone prepared by ketonization of cis-1,4-butadiene rubber with nitrogen(I) oxide (N2O) for the modification of physicomechanical properties of elastomer com...
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Article
Preparing High-Octane Motor Fuel Components via the Oxidation of an Industrial Isobutane Fraction
The deep processing of heavy oil increases the production of hydrocarbon gases. The resulting butanes do not always find an equivalent market. A mixture of oxygenates with a high octane number is obtained in t...
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Article
Gas Chromatography Columns Based on Functionalized Polymer for the Analysis of Catalytic Reaction Products
For the first time in this work, two methods of modification of poly(1-trimethylsilyl-1-propyne) (PTMSP) and the possibilities of its application for the determination of catalytic reaction products are descri...
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Article
Hydrodeoxygenation of methyl-substituted ketones using the composite loading of hydrogenation and dehydration catalysts
The hydrogenation/hydrodeoxygenation of methyl-substituted carbonyl compounds to preserve the isomeric structure of a product is one way of controlling its amount of oxygen and improving the chemical stability...
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Article
New methods for the preparation of high-octane components from catalytic cracking olefins
A new method has been suggested for the preparation of high-octane components from the butane–butylene fraction (BBF) in two stages. At the first stage, the BBF olefins are oxidized with N2O into carbonyl compoun...
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Article
Use of carbon–oligomer filler prepared from rubbers reclaimed with dinitrogen monoxide as a component of elastomer compounds
Samples of carbon–oligomer filler prepared by ketonization of tire rubber crumb with dinitrogen monoxide were characterized. The effect of the oligomeric component of the filler on the kinetic parameters of cr...
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Article
Phenol oxidation by nitrous oxide: The role of zeolite catalyst acidity
Gas-phase phenol oxidation using nitrous oxide on zeolite catalysts is of great interest as an alternative method of dihydroxybenzene (DHB) synthesis. Catalysts for conducting this reaction with high selectivi...
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Article
Interaction of Nylon Cord with a Polymer—Oligomer—Solvent System
The interphase interaction of nylon cord 23RYNC with a polymer—oligomer—solvent system was investigated in order to predict the properties of resin—cord composites. It was found that functional oligodienes at ...
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Article
Modification of coal tar by nitrous oxide
The modification of coal tar by nitrous oxide is considered. Preliminary N2O treatment of the tar increases the yield of light distillate fractions and reduces the content of unsaturated indene compounds and poly...
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Article
Phenol hydroxylation with nitrous oxide
Phenol hydroxylation with nitrous oxide opens up a new, promising way to the gas-phase synthesis of dihydroxybenzenes, which are among the most important semiproducts of contemporary organic chemistry. A proce...
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Article
Modification of the organic matter of brown coals with nitrous oxide
The results of the treatment of brown coals from the Kansk-Achinsk Basin in an atmosphere of nitrous oxide are given. It was established that the main products of nitrous oxide interaction with the organic mat...
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Article
Study of the local structure of supported nanostructural platinum catalysts
The possibility of controlling the state of platinum deposited on the support surface via minor changes in the catalyst preparation procedure is demonstrated using a series of highly dispersed Pt/γ-Al2O3 catalyst...
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Article
Modification of the organic matter of boghead with nitrous oxide
The modification of the organic matter of boghead with nitrous oxide at elevated temperature and pressure was studied. It was found that unselective carbonylation observed in reactions with synthetic polymers ...
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Article
Liquid-phase hydroamination of cyclohexanone
Activity and selectivity of supported Ni, Pt, and Pd catalysts were studied in the liquidphase reductive amination of cyclohexanone at temperatures ranging from 100 to 150 °C. The catalyst 20% Ni/SiO2 is most act...
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Article
Mechanism of Coke Influence on the Catalytic Activity of FeZSM-5 in the Reaction of Benzene Oxidation into Phenol
The influence of coke formation in the reaction of benzene oxidation by nitrous oxide into phenol on the catalytic activity and concentration of iron-containing active sites (α-sites), which are stabilized in ...