Abstract
The possibility of controlling the state of platinum deposited on the support surface via minor changes in the catalyst preparation procedure is demonstrated using a series of highly dispersed Pt/γ-Al2O3 catalysts with different particle size of the active component. Dispersity, local structure and electronic state of supported platinum were examined by a combination of high resolution transmission electron microscopy and X-ray absorption spectroscopy (EXAFS/XANES). It was shown that various platinum species can be obtained on the surface of the support: bulk or surface Pt(II) or Pt(IV) oxides, mixed metal-oxide structures, bulk particles of metallic platinum, and two-dimensional surface Pt0 particles strongly interacting with the support.
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Original Russian Text Copyright © 2010 by I. É. Beck, V. V. Kriventsov, D. P. Ivanov, E. P. Yakimchuk, B. N. Novgorodov, V. I. Zaikovskii, and V. I. Bukhtiyarov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 51, Supplement, pp. S17–S25, 2010.
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Beck, I.É., Kriventsov, V.V., Ivanov, D.P. et al. Study of the local structure of supported nanostructural platinum catalysts. J Struct Chem 51 (Suppl 1), 11–19 (2010). https://doi.org/10.1007/s10947-010-0185-x
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DOI: https://doi.org/10.1007/s10947-010-0185-x