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504 Result(s)
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Chapter
Application of Statistical Mechanics in the Study of Liquid Water
“Theories of the statistical mechanics of fluids have either been very formal and based upon first principles or they have been extremely heuristic, depending largely upon models”.(898)
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Chapter
Recent Interfaces Between Mass Spectrometry and Art
CHEMISTS have long been aware of the limitations imposed on their studies by the limits of sensitivity of many of those currently available analytical methods which permit a number of elements to be determined...
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Chapter
Molecular Theories and Models of Water and of Dilute Aqueous Solutions
“Models are, for the most part, caricatures of reality, but if they are good, then, like good caricatures, they portray, though perhaps in distorted manner, some of the features of the real world.”(721) ...
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Article
Hydrophobic interaction in water-ethanol mixtures
The solubility, free energy, entropy, and enthalpy of solutions of methane and ethane were determined in various mixtures of water and ethanol. The hydrophobic interaction for the pair methane-methane was comp...
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Article
Molar volumes and ion pairing of lithium halides in alcohols
The concentration dependence of the apparent molar volumes of lithium halides (and electrolytes in general) in alcohols (and solvents permitting association in general) is, in the first instance, due to change...
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Chapter and Conference Paper
Progress in Cloning the Transforming Gene from Chemically-Transformed Mouse Cells
DNA was extracted from a variety of chemically-transformed mouse fibroblast lines, and used as a donor for the transfection of NIH3T3 cells. Some of these DNAs were able to induce the appearance of transformed...
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Chapter and Conference Paper
Hyperfine, Superhyperfine, Fine Structures
It has been shown that an unpaired electron in a magnetic field has its energy levels split into two levels : $${{\rm{E}}_{{\rm{o }}}...
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Chapter and Conference Paper
An NMR and EPR Investigation of the Interaction of Chromium and Molybdenum Hexacarbonyl with Faujasite Type Y Zeolite
Zerovalent metal carbonyls have often been supported over various inorganic carriers (1 – 10) with the general purpose of obtaining well dispersed transition metal phases over inert or semi inert supports. Mol...
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Chapter
Very Dilute Solutions and Hydrophobic Interaction
In the previous chapter we noted that there are essentially two different concepts which are discussed in the literature under the same term, hydrophobic interaction (or hydrophobic bond). One is represented by t...
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Chapter
Hydrophobic Interaction among Many Solute Particles
In the previous chapter we were concerned with the HI between two solute particles. This has been considered to be the first and most important step towards the full characterization and understanding of the p...
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Chapter and Conference Paper
ESR Study of Powders’ g Factor, Transition Metal Ions, Various Symmetries
Excellent text books and reviews are given in (1). The basic principle of EPR spectroscopy lies in the fact that the electron spin $$ ...
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Chapter
Introduction and Fundamental Equations
The term “hydrophobic interaction” (HI) has been used in connection with several closely related phenomena. It is difficult to trace the origin of this term [or of its predecessor—the “hydrophobic bond”—appare...
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Chapter
Pairwise Hydrophobic Interaction (HI)
This chapter forms the kernel of the whole book. Here we shall survey the available information on the most elementary, but fundamental, process to which the term hydrophobic interaction (HI) may be applied. T...
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Chapter
Temperature and Pressure Dependence of the Hydrophobic Interactions
The study of the temperature and the pressure dependence of the HI is of interest for several reasons. The first is its relevance to biological processes. It is well known that proteins undergo a process of de...
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Book
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Chapter
Chemical Lasers
Chemical lasers are defined as lasers in which population inversion results from a chemical reaction. This broad definition refers to a variety of pum** processes involving, for example, exoergic reactive co...
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Chapter
Lasers and Chemical Change
The dictionary defines laser as a. device for the amplification of light. Clearly there is more to it since the acronym itself stands for light amplification by stimulated emission of radiation. Moreover there...
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Chapter
Photons, Molecules, and Lasers
To make full use of the unique properties of lasers, one needs an understanding of the fundamental principles which govern their operation. In the first two sections of this chapter we provide an introductory ...
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Chapter
Laser Chemistry
This chapter examines the practice of laser chemistry, in the gas phase. It deals mostly with the use of lasers as means for the preparation of a selectively excited initial state and also documents their appl...
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Chapter
Disequilibrium
Our concern in this volume is with molecular systems that have been displaced from thermal equilibrium, often to a considerable extent. Lasers and chemical lasers in particular operate because such displacemen...
