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Article
Hyperpolarization of Nuclei by the Method of Spin-Exchange Optical Pum**
A review of theoretical concepts of the ways of producing 129Xe nuclei hyperpolarized in magnetic moment by optical pum** of alkali atoms with their subsequent collisional spin exchange (SEOP) with noble gas is...
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Article
Determination of the Shape and Dimensions of the Polymer Molecules in Solutions Using Diffusional NMR Relaxation
A new method of determining the dimensions and shapes of polymer molecules in solutions is proposed and verified in experiments. The method is based on the measurements of the relaxation of the transverse magn...
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Article
NMR Studies of Porous Media: Specific Features
A model water-filled porous medium is investigated using NMR techniques, and the results of these measurements are interpreted theoretically. A rigorous theoretical description of the near-surface layer, quali...
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Article
Bound States of Repulsing Adsorbed Atoms
The interaction between two slow atoms adsorbed on the surface is considered. It is shown that, similar to Efimov states of three particles, this system has a bound state at any sign of the scattering length.
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Article
Acceleration of Ion Rings by Collapsing Liners
We have established the conditions for the absence of Alfvén ion-cyclotron instability in the formation and subsequent acceleration of ion rings by collapsing cylindrical plasma liners.
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Article
Conditions for the Stable Acceleration of Ion Rings by Collapsed Liners
The conditions of suppressing the collective slowing-down of an ionic beam on electrons, which is caused by the excitation of electron plasma oscillations (beam instability) by ions, are found. In contrast to ...
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Article
Preparation of phthalates via carbonylation of o-dibromobenzenes in solutions of Pd catalysts and reactivity of Ar−Br bonds
Carbonylation of o-dibromobenzene and its derivatives in the presence of palladium phosphine complexes with NaOAc or Et3N additive leads to the formation of phthalates in high yield under mild conditions. Correla...
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Article
Specific features of proton NMR relaxation of hydrocarbons and water in the pore space of silicates
The relaxation of the proton magnetization of water and hydrocarbons in a model medium of glass beads and quartz sand is studied by the NMR method. The spectrum of relaxation times of fluids is one-component i...
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Article
On the state of CH4 molecule in the octahedral void of C60 fullerite
Methane-intercalated fullerite (CH4)0.56C60 was obtained by low-temperature precipitation from solution. Methane transition from the gas phase to the octahedral void of fullerite is accompanied by a bathochromic ...
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Article
Structure and hydration processes in perfluorinated bilayer cation-exchange membranes
Based on perfluorinated polymers MF-4SK and F-4KF bilayer composite ion-exchange membranes are studied by using the magic-angle-rotation NMR, electrochemical impedance spectroscopy, scanning electron microscop...
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Chapter and Conference Paper
The Temperature Dependence of Chemical Shifts of Individual Peaks in the 13C NMR Spectrum of the Fullerite C60, Doped with Molecular Oxygen
The methods of solid-state high-resolution NMR have been applied to investigate samples of fullerite C60, doped with molecular oxygen. It was found that in the case of well-crystallized (O2)0.44C60 sample the tem...
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Article
A NMR study of the hydration of sulfo and carboxyl groups in perfluorinated cation exchange membranes
The mobility of the polymer matrix and the structure of the hydration complex in the acid forms of perfluorinated ion exchange membranes MF-4SK and F-4KF depending on moisture content were studied by 1H, 13C, and...
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Article
The structure of fullerite C60 intercalated with molecular oxygen
A (O2) x C60 sample with a high content of oxygen (x ≥ 0.4) and free of technological solvent impurities was obtained by precipitation from solution. For the first time, the resu...
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Article
Phase transitions and ion transport in NASICON materials of composition Li1 + x Zr2 − x In x (PO4)3(x = 0–1)
NASICON materials of composition Li1 + x Zr2 − x In x (PO4)3(x = 0–1) were synthesized. The phase constitution, particle size, and...
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Article
Mechanism of proton conductivity in polyvinyl alcohol-phenolsulfonic acid membranes from 1H and 13C NMR data
With line narrowing during magic angle spinning in solid-state NMR, molecular mobility and hydration in composite membranes based on polyvinyl alcohol (PVA) and phenol-2,4-disulfonic acid (PSA) were studied as...
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Article
Space and Time Correlations in a Dissipative Structure Emerging in an Electrochemical System with a Cation-Exchange Membrane
The mechanism of electromasstransfer in a system containing a cation-exchange membrane at a current density exceeding the limiting diffusion current is studied by analyzing the electric potential fluctuations....
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Article
Wavelet and fourier analysis of electric fluctuations in semiconductor and electrochemical systems
Wavelet analysis and Fourier spectroscopy were used to study electric noise observed in InSb photodiodes and in electric systems with a cation-exchange membrane in NaCl solution.
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Article
Electrophysical characteristics of several organic compounds at high pressures and high pressures combined with shearing strains
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The application of high pressures results in an increase in the dielectric constant of organic compounds, whi...
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