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Article
Thermal Behaviour of Transition Metal-Containing Zirconium Phosphate
The thermal behaviour of Co(II), Ni(II) and Zn(II)-containing zirconium phosphate of α type was investigated. XRPD analysis revealed that, for the samples containing Co(II) or Ni(II), the first reflection of t...
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Article
FT-IR studies on intercalates and organic derivatives of crystalline (α- and γ-forms) zirconium phosphate and zirconium phosphate-phosphite
FT-IR studies were carried out for various α- and γ-crystalline intercalates of zirconium phosphate (ZrP) and also for zirconium phosphatephosphite (ZrPP). The characteristic peaks of n-alkanols, n-alkylamines...
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Article
Thermoanalytical Investigation of Several Layered Zirconium Salts and their Derivatives Part II
The comparison of data of thermal analysis partly with XRD and/or analytical results permits determination of the exact quantity of crystal water of the investigated samples having quite different behaviour. T...
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Article
Thermoanalyncal Investigation of Some Layered Zirconium Salts and Their Various Derivatives I.
The thermal behaviour of zirconium phosphate and its salt forms and also mixed zirconium-titanium phosphate were investigated. Based on TA data, in combination with other analytical results the composition, th...
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Article
Structural investigations on zirconium phosphate-phosphite and on itsn-butylamine intercalate
Zirconium phosphate-phosphite have various structure belonging to the drying heat of the sample. While sample dried above sat. NaCl solution had interlayer distance of 1.30 nm (result fromd 1=0.74 nm andd 2=0.56 ...
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Article
Investigations of crystalline structure of gamma-zirconium phosphate
The γ-crystalline form zirconium phosphate was investigated. For its lattice parameters was found:a=0.538 nm,b=0.664 nm,c=2.459 nm, β=94.2° and basal spacing (d)=1.22 nm. It was determined by IR spectrophotometri...
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Article
Thermal decomposition of organic derivatives of crystalline zirconium phosphate
The diethylene glycol, benzyl alcohol and benzylamine derivatives ofα- andγ-zirconium phosphates were prepared and their thermal behaviour was investigated by means of differential thermal analysis. In all cases,...
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Article
Thermal decomposition of organic derivatives of crystalline zirconium phosphate
The thermal decompositions ofn-alkylamine (ethylamine, propylamine, butylamine and pentylamine) derivates ofγ-zirconium phosphate were investigated. The samples exhibited similar mechanisms of decomposition.
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Article
Thermal decomposition of organic derivatives of crystalline zirconium phosphate
Organic derivatives ofγ-zirconium phosphate were investigated. Then- alkanol derivatives lost their crystal and structural water in several steps. The thermal stability of the molecules increased with increasing ...
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Article
Thermal decomposition of organic derivatives of crystalline zirconium phosphate-phosphite
Organic derivatives of crystalline zirconium phosphate-phosphite (ZrPP) are easily obtained by direct contact of the given organic solution with the crystalline material. The thermal decomposition of benzyl al...
