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Article
Kinetic Measurements of Singlet Oxygen Phosphorescence in Hydrogen-Free Solvents by Time-Resolved Photon Counting
Solvents lacking hydrogen atoms are very convenient models for elucidating the properties of singlet oxygen, since the lifetime of singlet oxygen in these solvents reaches tens milliseconds. Measuring intrinsi...
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Article
Primary mechanisms of photoactivation of molecular oxygen. History of development and the modern status of research
This review starts from a brief historical account devoted to the principles of the Bach-Engler peroxidation theory and experiments and ideas which led A. N. Bach to its creation. Then, the discovery of photod...
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Article
Molecular arrangement of pigment-protein complex of photosystem 1
The circular dichroism (CD) method was applied to study the molecular organization of P700, antenna chlorophyll and protein of photosystem 1 complexes (CP1), isolated from chloroplasts under mild treatment wit...
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Article
Some remarks on the origin and evolution of photosynthesis
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Article
Chemical evolution of photosynthesis
The principles of biological evolution of photosynthesis are established, but the ways of chemical evolution are unclear yet. The model systems will help to elucidate the problem. Every type of photosynthesis ...
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Article
Pathways of chemical evolution of photosynthesis
The primary metabolism of protobionts was probably based on the electron transfer reactions regulated by catalysts or photosensitizing pigments. The action of photoreceptive pigments was inevitable in the case...
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Chapter
Abiogenic Formation of Porphin, Chlorin and Bacteriochlorin
Oparin’s hypothesis (1) maintaining that a prolonged chemical evolution preceded the emergence of life on Earth gave impetus to numerous investigations whose purpose was to reveal probable pathways of biosynth...