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Article
Photochemistry of 1-amino-2,4,6-triphenylpyridinium perchlorate
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Article
Reactions of heterocyclic cations with N-containing nucleophiles. 16. Study of the interaction of 2,6-diphenylpyrylium perchlorate with diazoles
The direct interaction of 2,6-diphenylpyrylium perchlorate with pyrazoles and pyrazolones led to the synthesis of 4-azolylpyrylium salts, which readily cleave a molecule of perchloric acid in the case of the N...
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Article
Reactions of heterocyclic cations with n-containing nucleophiles. 15. Reaction of 2,6-diphenylpyrylium perchlorate with semi- and thiosemicarbazides
The reaction of 2,6-diphenylpyrylium perchlorate with semi- and thiosemicarbazides in ethanol leads to 1-carbamoyl- and 1-thiocarbamoyl-3-phenyl-5-phenacyl-4,5-dihydropyrazoles, the cyclization of which yields...
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Article
Pharmacological properties of pyridinium salts, pyrazolines, and pyrazoles
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Article
Reactions of heterocyclic cations with N-containing nucleophiles. 14. Recyclization of 2,6-diphenylpyrylium perchlorate under the influence of nucleophiles with an N-C-N fragment
The recyclization of 2,6-diphenylpyrylium perchlorate under the influence of isothioureas, guanidine, 2-aminobenzimidazoles, 2-aminonaphth[1,2-d]imidazole, 2-aminothiazole, 2-aminobenzothiazole, and 2-aminopyr...
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Article
Reactions of heterocyclic cations with N-containing nucleophiles. 13. Investigation of the reaction of 2,4,6-triarylpyrylium salts with hydrazines, semicarbazide, and thiosemicarbazide
The recyclization reactions of 2,4,6-triphenylpyrylium perchlorate with hydrazine and methyl-, phenyl-, benzoyl-, and benzalhydrazines in dimethylformamide (DMF), which proceed differently than in ethanol, wer...
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Article
Synthesis of 4-(4-pyrazolyl)-substituted pyrylium salts and pyridines
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Article
Reactions of heterocyclic cations with nitrogen-containing nucleophiles. 10. Synthesis of 3,5,7-triaryl-1,2-oxazepinium perchlorates by the reaction of 2,4,6-triarylpyrylium salts with nitrones and substituted hydroxylamines
2-Substituted 3,5,7-triaryl-1,2-oxazepinium perchlorates were obtained by the reaction of 2,4,6-triarylpyrylium salts in dimethylformamide with nitrones and N-arylhydroxylamines. The products are the first rep...
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Article
Reactions of heterocyclic cations with nitrogen-containing nucleophiles. 12. Reaction of pyrylium salts with azomethines
The reaction of pyrylium salts with azomethines leads to the formation of styrylpyrylium, styrylpyridinium, and 4-arylbenzylaminopyrylium salts. The reaction of the latter with ammonia and amines gave pyridine...
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Article
Reactions of heterocyclic cations with nitrogen-containing nucleophiles. 11. Reaction of 2,6-diphenylpyrylium perchlorate with primary amines, hydrazine, and hydroxylamine
The reaction of 2,6-diphenylpyrylium perchlorate with methylamine and various anilines in acetic acid leads to pyridinium salts; 3,4-bispyridinium perchlorates were obtained in dimethylformamide. The reaction ...
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Article
Synthesis of pyrimidine derivatives by reaction of pyrylium salts with guanidine and compounds of the guanidine series
2,4,6-Triphenylpyrylium perchlorate reacts with methylguanidine to give 1-methyl-2-amino-4,6-diphenylpyrimidinium perchlorate, which undergoes the Dimroth rearrangement to give 2-methylamino-4,6-diphenylpyrimi...
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Article
Synthesis of pyrimidine derivatives by reaction of pyrylium salts with guanidine and compounds of the guanidine series
2,4,6-Triphenylpyrylium perchlorate reacts with methylguanidine to give 1-methyl-2-amino-4,6-diphenylpyrimidinium perchlorate, which undergoes the Dimroth rearrangement to give 2-methylamino-4,6-diphenylpyrimi...
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Article
Antimicrobial activity of some pyridinium salts and compounds of the pyrimidine series
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Article
Synthesis of pyridine and pyrimidine derivatives by reaction of pyrylium salts with ureas, thioureas, and isothioureas
2,4,6-Triphenylpyrylium perchlorate is converted to 2,4,6-triphenylpyridine in reactions with urea and N-acetyl- and N,N-dimethylureas, whereas it is converted to 1,2,4,6-tetraphenylpyridinium perchlorate on r...
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Article
Synthesis and properties of N-hetarylpyridinium salts
Methods for the synthesis of N-hetarylpyridinium perchlorates are examined. The basicity constants of a number of the indicated compounds were measured. It is shown that 2,4,6-trimethyl- and 2,4,6-triphenylpyr...
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Article
Reaction of pyrylium salts with amidines
2,4,6-Substituted pyrimidines were obtained by reaction of 2,4,6-triarylpyrylium perchlorates with amines. 2,4-Substituted pyrimidines were similarly synthesized from 2,6-diphenylpyrylium perchlorate.
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Article
Reaction of methyl-substituted pyrylium salts with tertiary amines
2,4,6-Trimethylpyrylium perchlorate reacts with heterocyclic compounds containing apyridine nitrogen atom and having basicities higher than 9 pKa units (in acetonitrile) through a step involving the formation of ...
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Article
Basicities and transformations of pyrylium and pyridinium salts containing p-aminophenyl substituents
On the basis of the measured basicity constants of pyrylium and pyridinium salts containing p-aminophenyl substituents it is shown that the positive charge in the pyrylium cation is considerably higher than in...
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Article
Fifth Symposium on the Chemistry of Heterocyclic Compounds
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Article
Synthesis of condensed pyrimidine systems based on 2,4,6-triphenylpyrylium perchlorate
1,3-Diphenylpyrimido[1,2-a]benzimidazolium perchlorates were obtained by reaction of 2,4,6-triphenylpyrylium perchlorate with 2-aminobenzimidazoles.