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    Article

    Effect of violations of the structure and layer packing on the diffraction pattern of gibbsite and bayerite

    Using the simulation method for the diffraction patterns of one-dimensionally disordered materials, the effect of different violations in the layered structure of aluminum trihydroxides (gibbsite and bayerite)...

    K. I. Shefer, S. V. Cherepanova, S. V. Tsybulya in Journal of Structural Chemistry (2013)

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    Article

    Mechanism of formation of nanosized copper particles in a nanoreactor based on the [LiAl2(OH)6]2[Cuedta]·nH2O supramolecular system

    The formation of nanosized copper particles in a nanoreactor based on the [LiAl2(OH)6]2[Cuedta]·nH2O supramolecular system [Li-Al-Cu(edta)] was studied by the DTA, XRPA, FMR, IR, and mass spectrometry methods. Th...

    V. P. Isupov, R. P. Mitrofanova, L. É. Chupakhina in Journal of Structural Chemistry (2007)

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    Article

    Mechanism of formation of cobalt nanoparticles in a nanoreactor based on supramolecular system [LiAl2(OH)6]2[Coedta]·nH2O

    DTA (differential thermal analysis), XPA (XRD phase analysis), FMR (ferromagnetic resonance), and IR (infrared spectroscopy) methods were used to study the formation of nanosized particles of cobalt in a nanor...

    V. P. Isupov, R. P. Mitrofanova, L. É. Chupakhina in Journal of Structural Chemistry (2005)

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    Article

    Investigation of the formation of nickel and cobalt nanoparticles upon thermal decomposition of Ni,Al-and Co,Al-layered double hydroxides pillared with complexes [Ni(edta)]2− and [Co(edta)]2−

    Double layered hydroxides [M0.7Al(OH)3.6] [M(edta)]0.4·nH2O (M,Al-M(edta), M = Ni, Co) containing nickel or cobalt edta complexes in the interlayer space were obtained for the first time. Vacuum thermal decomposi...

    E. V. Starikova, V. P. Isupov, K. A. Tarasov in Journal of Structural Chemistry (2004)

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    Article

    Using NMR in Structural Studies of Aluminum Hydroxide Intercalation Compounds with Lithium Salts

    The effect of the anion charge on the structure of [LiAl2(OH)6]nX (X = Cl-, Br-, I-, SO4 2-, C6H8O4 2-) intercalation compounds and the water effect on the structure of [LiAl2(OH)6]Cl·nH2O have been studied using...

    S. G. Kozlova, S. P. Gabuda, V. P. Isupov in Journal of Structural Chemistry (2003)

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    Article

    Structural Effects of Intercalation in [LiAl2(OH)6]Cl ⋅ xH2Os (1H, 7Li, 27Al NMR)

    1H, 7Li, and 27Al NMR was used to study [LiAl2(OH)6]Cl ⋅ xH2O systems (x = 0, 1.6, and 2.8). At larger x values, the amplitude of the librational motion of the hydroxyl groups increases and the chloride ions are...

    S. G. Kozlova, S. P. Gabuda, V. P. Isupov in Journal of Structural Chemistry (2001)

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    Article

    Intercalation compounds of aluminum hydroxide

    Crystalline aluminum trihydroxides Al(OH)3 (gibbsite, baverite, and nordstrandite) can serve as layered intercalation matrices in which metal salts are arranged in a specific way. Small cations (lithium, magnesiu...

    V. P. Isupov in Journal of Structural Chemistry (1999)

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    Article

    Using intercalation compounds of aluminum hydroxide for syntheses of nanoscale systems

    Routes for synthesizing intercalation compounds of aluminum hydroxide [MxAly(OH)z]n X · pH2O (M=Li, Mg, Ni, Co, …) are suggested, and application of these schemes to syntheses of nanoscale systems is examined. It...

    V. P. Isupov, L. É. Chupakhina, R. P. Mitrofanova in Journal of Structural Chemistry (1998)

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    Article

    Structural mechanism of selective binding of lithium on a solid matrix of Al(OH)3 from aqueous solutions

    The structure of intercalation complexes of aluminum hydroxide with lithium salts is investigated by X-ray diffractometry and by21Al,7Li, and1H NMR. The lithium ions occupy vacant positions in the octahedral void...

    V. P. Isupov, S. P. Gabuda, S. G. Kozlova in Journal of Structural Chemistry (1998)

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    Article

    Crystallochemical features of the anion varieties of aluminum and lithium binary hydroxide

    Crystallochemical features of anion (Cl, Br, I, NO 3 , CO 3 2− , SO 4 ...

    I. A. Poroshina, N. P. Kotsupalo, L. T. Menzheres in Journal of Structural Chemistry (1994)