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Article
α-Fe2O3 and Fe3O4 hollow nanospheres as high-capacity anode materials for rechargeable Li-ion batteries
α-Fe2O3 and Fe3O4 hollow nanospheres of size 30 ± 2 nm were synthesized by using polymeric micelles as a soft template for the first time. The hollow nanospheres were thoroughly characterized by transmission elec...
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Article
Preparation and electrochemical properties of Li1.1Mn2O3.9F0.1 material for lithium secondary battery
Li1.1Mn2O4 and Li1.1Mn2O3.9F0.1 materials have been synthesized at 900 ‡C by using the melt-impregnation method. Li1.1Mn2O4 showed fairly large capacity fading at room temperature; however, Li1.1Mn2O3.9F0.1 exhib...
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Article
Valence Determination of Manganese in Battery Cathode Materials by High-Resolution Mn Kα1 Spectra
High-resolution the Mn Kα1 X-ray fluorescence spectra (HRXRF) were measured for a variety of manganese compounds, the oxidation number (valence) of which was from II to VII. Plots of the valence against the full ...
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Article
The Effects of Lithium and Oxygen Contents Inducing Capacity Loss of the LiMn2O4 Obtained at High Synthetic Temperature
Well-crystallized LiMn2O4 has been synthesized at different calcination temperatures using the melt-impregnation method. The lattice constant of LiMn2O4 increased with increasing calcination temperatures. Li/LiMn
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Article
The effects of oxygen flow rate and anion do** on the performance of the LiNio2 electrode for lithium secondary batteries
This work presents the effects of O2 flow rate and S-do** on structural and electrochemical properties of LiNiO2. Layered LiNiO2 were prepared using a sol-gel method. It was found that oxygen plays an important...
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Article
Dependence of Battery Performance of Spinel Li1+XMn2O4 on the Preparation Method
The formation process of the spinel phase by the melt-impregnation method was extensively investigated by the pore volume distribution measurement. Two kinds of the spinel structure compounds Li1+xMn2O4 optimized...
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Article
Stability Constants of Crown Ether Complexes with Aqueous Hydronium Ion
Stability constants of complexes of hydronium ion with three crown ethers were determined by a solvent extraction method. By thermodynamic experiments on these complexes in 0.5 mol dm-3 hydrochloric acid at 25.0°...
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Article
High-rate plating of aluminium from the bath containing aluminium chloride and lithium aluminium hydride in tetrahydrofuran
An electrolyte for the high-rate plating of aluminium from the tetrahydrofuran solutions of aluminium chloride and lithium aluminium hydride has been developed. A smooth and coherent deposit of aluminium has b...