SpringerLink
Log in

Magnetic properties of chain antiferromagnets RbFeSe2, TlFeSe2, and TlFeS2

  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Single crystals of ternary ion chalcogenides RbFeSe2, TlFeSe2, and TlFeS2 are studied by X-ray diffraction, SQUID magnetometry, and Mössbauer spectroscopy. Common structural units of these chalcogenides are tetrahedra of FeCh4 (chalcogen Ch = Se, S), arranged in chains by sharing an edge. It is found that RbFeSe2, TlFeSe2, and TlFeS2 undergo transition to a collinear antiferromagnetic state below temperatures T N = 248, 290, and 196 K, respectively. Their magnetic moments are oriented perpendicular to the axes of the chains of FeCh4 tetrahedra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kamihara, Y., Watanabe, T., Hirano, M., and Hosono, H., J. Am. Chem. Soc., 2008, vol. 130, p. 3296.

    Article  Google Scholar 

  2. Stewart, G., Rev. Mod. Phys., 2011, vol. 83, p. 1589.

    Article  ADS  Google Scholar 

  3. Dagotto, E., Rev. Mod. Phys., 2013, vol. 85, p. 849.

    Article  ADS  Google Scholar 

  4. Takahashi, H., Sugimoto, A., Nambu, Y., et al., Nat. Mater., 2015, vol. 14, p. 1008.

    Article  ADS  Google Scholar 

  5. Harrison, M.R. and Grazia-Francesconi, M., Coord. Chem. Rev., 2011, vol. 255, p. 451.

    Article  Google Scholar 

  6. Zabel, M. and Range, K.-J., Z. Naturforsch., 1979, vol. 34b, p. 1.

    Article  Google Scholar 

  7. Bronger, W. and Müller, P., J. Alloys Compd., 1997, vol. 246, p. 27.

    Article  Google Scholar 

  8. Seidov, Z., Tsurkan, V., Vagizov, F., et al., Phys. Rev. B, 2016, vol. 94, p. 134414.

    Article  ADS  Google Scholar 

  9. Klepp, D. and Boller, H., Monatsh. Chem., 1979, vol. 110, p. 1045.

    Article  Google Scholar 

  10. Pauling, L., The Nature of the Chemical Bond, Ithaca: Cornell Univ. Press, 1940.

    MATH  Google Scholar 

  11. Rodriguez-Carvajal, J., Phys. B, 1993, vol. 192, p. 55.

    Article  ADS  Google Scholar 

  12. Bronger, W., Kyus, A., and Müller, P., J. Solid State Chem., 1987, vol. 70, p. 262.

    Article  ADS  Google Scholar 

  13. Tiwary, S. and Vasudevan, S., Phys. Rev. B, 1997, vol. 56, p. 7812.

    Article  ADS  Google Scholar 

  14. Bonner, J.C. and Fisher, M.E., Phys. Rev., 1964, vol. 135, p. A640.

    Article  ADS  Google Scholar 

  15. Asgerov, E.B., Dang, N.T., Beskrovnyy, A.I., Madadzada, A.I., Ismayilov, D.I., Mehdiyeva, R.N., Jabarov, S.H., and Karimova, E.M., Semiconductors, 2015, vol. 49, p. 879.

    Article  ADS  Google Scholar 

  16. Welz, D. and Nishi, M., Phys. Rev. B, 1992, vol. 45, p. 9806.

    Article  ADS  Google Scholar 

  17. Welz, D., Deppe, P., Schaefer, W., et al., J. Phys. Chem. Solids, 1989, vol. 50, p. 297.

    Article  ADS  Google Scholar 

  18. Seidov, Z., Krug von Nidda, H.-A., Hemberger, J., et al., Phys. Rev. B, 2001, vol. 65, p. 014433.

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135, Augsburg, Germany

    Z. Seidov, H. -A. Krug von Nidda, V. Tsurkan, A. Günther & A. Loidl

  2. Institute of Physics, Azerbaijan National Academy of Sciences, Baku, AZ-1143, Azerbaijan

    Z. Seidov & A. Najafov

  3. Institute of Applied Physics, Moldova Academy of Sciences, Chisinau, MD-20208, Moldova

    V. Tsurkan & I. Filippova

  4. Faculty of Solid State Physics, Baku State University, Baku, AZ-1148, Azerbaijan

    M. N. Aliyev

  5. Institute of Physics, Kazan Federal University, Kazan, 420008, Russia

    F. G. Vagizov, A. G. Kiiamov & L. R. Tagirov

  6. Zavoisky Physicotechnical Institute, Russian Academy of Sciences, Kazan, 420029, Russia

    L. R. Tagirov & T. Gavrilova

  7. Institute of Advanced Studies, Tatarstan Academy of Sciences, Kazan, 420111, Russia

    L. R. Tagirov

Authors
  1. Z. Seidov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. -A. Krug von Nidda
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. Tsurkan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. Filippova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Günther
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Najafov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. N. Aliyev
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. F. G. Vagizov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. A. G. Kiiamov
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. L. R. Tagirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. T. Gavrilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  12. A. Loidl
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. R. Tagirov.

Additional information

Original Russian Text © Z. Seidov, H.-A. Krug von Nidda, V. Tsurkan, I. Filippova, A. Günther, A. Najafov, M.N. Aliyev, F.G. Vagizov, A.G. Kiiamov, L.R. Tagirov, T. Gavrilova, A. Loidl, 2017, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2017, Vol. 81, No. 7, pp. 977–980.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Seidov, Z., Krug von Nidda, H.A., Tsurkan, V. et al. Magnetic properties of chain antiferromagnets RbFeSe2, TlFeSe2, and TlFeS2 . Bull. Russ. Acad. Sci. Phys. 81, 885–887 (2017). https://doi.org/10.3103/S1062873817070267

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873817070267

Search

Navigation