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Magnetic structure of TlFeS2 and TlFeSe2 chalcogenides

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Abstract

The crystal and magnetic structures of TlFeS2 and TlFeSe2 chalcogenides are studied by neutron diffraction in the temperature range 10–300 K. The investigated compounds feature monoclinic crystal symmetry with the C2/m space group. Antiferromagnetic ordering occurs in TlFeS2 and TlFeSe2 at the Néel temperature TN = 210(5) and 295(5) K, respectively. The temperature dependences of magnetic moments, Fe–Fe bond lengths, and unit-cell volume are established. The coefficients of thermal expansion for the paramagnetic and antiferromagnetic phases are calculated.

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Authors and Affiliations

  1. Joint Institute for Nuclear Research, Dubna, 141980, Russia

    E. B. Asgerov, A. I. Beskrovnyy & A. I. Madadzada

  2. Institute of Radiation Problems, National Academy of Sciences of Azerbaijan, Baku, Az-, 1143, Azerbaijan

    E. B. Asgerov & R. N. Mehdiyeva

  3. Institute of Research and Development, Duy Tan University, Da Nang, 550000, Vietnam

    N. T. Dang

  4. Abdullaev Institute of Physics, National Academy of Sciences of Azerbaijan, Baku, Az-1143, Azerbaijan

    A. I. Madadzada, D. I. Ismayilov & S. H. Jabarov

  5. Bayerisces Geoinstitut, Universitet Bayreuth, Bayreuth, D-95440, Germany

    S. H. Jabarov & E. M. Karimova

Authors
  1. E. B. Asgerov
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  2. N. T. Dang
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  3. A. I. Beskrovnyy
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  4. A. I. Madadzada
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  5. D. I. Ismayilov
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  6. R. N. Mehdiyeva
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  7. S. H. Jabarov
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  8. E. M. Karimova
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Corresponding author

Correspondence to E. B. Asgerov.

Additional information

Original Russian Text © E.B. Asgerov, N.T. Dang, A.I. Beskrovnyy, A.I. Madadzada, D.I. Ismayilov, R.N. Mehdiyeva, S.H. Jabarov, E.M. Karimova, 2015, published in Fizika i Tekhnika Poluprovodnikov, 2015, Vol. 49, No. 7, pp. 899–903.

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Asgerov, E.B., Dang, N.T., Beskrovnyy, A.I. et al. Magnetic structure of TlFeS2 and TlFeSe2 chalcogenides. Semiconductors 49, 879–882 (2015). https://doi.org/10.1134/S1063782615070039

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  • DOI: https://doi.org/10.1134/S1063782615070039

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