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Photochromic and Photoswitchable Study of Pyrazolone-Based Compound and Its Ni(II) ion Sensing Ability

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Abstract

A new Schiff base compound 4[(1,5-dimethyl-3-oxo-2-phenyl-pyrazolidin-4-ylimino)-phenyl-methyl]-5-methyl-2-phenyl-2,4-dihydro-pyrazol-3-one was synthesized and characterized by elemental analysis, LC-MS, FTIR, and 1H-NMR spectra. The photochromic property of the synthesized compound was investigated under UV irradiation at 365 nm using solid-state absorption spectra. The photoisomerization is due to photoinduced intermolecular hydrogen bond which results in enol to keto transformation. The binding studies show its good selectivity toward Ni(II). The study of the photoswitching behavior in solution has revealed that the sensing can be photocontrollable. The logic behavior was investigated for Ni(II) in acidic media for two input systems (Ni2+ and H+) using the UV absorption spectra which showed NOR logic gate behavior.

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  1. Department of Chemistry, M.L. Parmar Science College, Veer Narmad South Gujarat University, Surat, Gujarat, India

    Pratima R. Surati

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  1. Pratima R. Surati
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Correspondence to Pratima R. Surati.

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Surati, P. Photochromic and Photoswitchable Study of Pyrazolone-Based Compound and Its Ni(II) ion Sensing Ability. J Anal Chem 77, 1010–1014 (2022). https://doi.org/10.1134/S106193482208010X

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  • DOI: https://doi.org/10.1134/S106193482208010X

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