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Hydrogenation of Furfural over Ruthenium Catalysts Supported on Porous Aromatic Frameworks

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Abstract

The paper describes an investigation into hydrogenation of furfural over ruthenium catalysts supported on porous aromatic frameworks. The supports were designated as PAF-30-SO3H, PAF-30-NH2, and PAF-30. The synthesized catalysts were tested in furfural hydrogenation carried out in water and in tetrahydrofuran (with a concentration of 10 wt %) at 90–250°C and a hydrogen pressure of 3 MPa. Although the highest furfural conversion (96%) was achieved in the case of its hydrogenation in water at 250°C over Ru-PAF-30, these conditions did not favor product selectivity. The reaction products mainly consisted of furfuryl alcohol, tetrahydrofurfuryl alcohol, and cyclopentanone. The highest yield of cyclopentanone, 71% (with 80% conversion and 89% selectivity) was observed in furfural hydrogenation over Ru-PAF-30 at 200°C, whereas the conditions optimal for selective hydrogenation of furfural into furfuryl alcohol were found to include either tetrahydrofuran as a solvent or water as a solvent and low temperatures (90–150°C).

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ACKNOWLEDGMENTS

The authors are sincerely grateful to Dr. R.S. Borisov and the Laboratory of Spectral Research of TIPS RAS for their technical and consulting assistance.

Funding

The study was supported by the Russian Science Foundation (RSF project no. 20-19-00380).

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    L. A. Kulikov, D. A. Makeeva, A. M. Dubiniak, M. V. Terenina, Yu. S. Kardasheva, S. V. Egazar’yants, A. F. Bikbaeva, A. L. Maximov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maximov

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  1. L. A. Kulikov
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Contributions

L.A. Kulikov: development of test procedure and processing of experimental data; D.A. Makeeva: synthesis of supports and catalysts; A.M. Dubiniak and A.F. Bikbaeva: catalytic testing; M.V. Terenina and Yu.S. Kardasheva: processing of experimental data; S.V. Egazar’yants: identification of product composition and structure; A.L. Maximov and E.A. Karakhanov: conceptual development; All co-authors: discussion of results.

Corresponding author

Correspondence to A. M. Dubiniak.

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A.L. Maksimov and E.A. Karakhanov, co-authors, are members of the editorial board of the journal Nanogeterogennyi kataliz (Nanoheterogeneous Catalysis). The other co-authors declare no conflict of interest requiring disclosure in this article.

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Kulikov, L.A., Makeeva, D.A., Dubiniak, A.M. et al. Hydrogenation of Furfural over Ruthenium Catalysts Supported on Porous Aromatic Frameworks. Pet. Chem. (2024). https://doi.org/10.1134/S0965544124020191

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