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Ruthenium catalysts based on mesoporous aromatic frameworks for the hydrogenation of arenes

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Abstract

Novel catalysts consisting of ruthenium nanoparticles supported on diamond-like porous aromatic frameworks (PAFs) with 3 and 4 benzene rings in the edges have been synthetized with a narrow particle size distribution (0.85 and 1.10 nm respectively). Several techniques, such as N2 physisorption, Fourier transform infrared spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and solid-state nuclear magnetic resonance were used for characterizing the synthesized materials. The obtained catalysts appeared to be active in the hydrogenation of various aromatic substances (specific catalytic activity reached activities up to 2660 mol(Sub) h−1 mol −1(Ru) in the case of phenol). Notably, a size-selective hydrogenation was observed for catalysts based on PAFs.

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Acknowledgments

The study was supported by the Russian Science Foundation within a framework of Project N 15-19-00099.

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Authors and Affiliations

  1. Department of Petroleum Chemistry and Organic Catalysis, Moscow State University, Leninskiye Gory 1-3, GSP-1, Moscow, Russian Federation, 119991

    Anton Maximov, Anna Zolotukhina, Leonid Kulikov, Yulia Kardasheva & Eduard Karakhanov

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  1. Anton Maximov
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  2. Anna Zolotukhina
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  3. Leonid Kulikov
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  4. Yulia Kardasheva
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  5. Eduard Karakhanov
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Correspondence to Eduard Karakhanov.

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Maximov, A., Zolotukhina, A., Kulikov, L. et al. Ruthenium catalysts based on mesoporous aromatic frameworks for the hydrogenation of arenes. Reac Kinet Mech Cat 117, 729–743 (2016). https://doi.org/10.1007/s11144-015-0956-7

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  • DOI: https://doi.org/10.1007/s11144-015-0956-7

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