Chemically activating MoS2 via spontaneous atomic palladium interfacial do** towards efficient hydrogen evolution

Luo, Zhaoyan; Ouyang, Yixin; Zhang, Hao; **ao, Meiling; Ge, Junjie; Jiang, Zheng; Wang, **lan; Tang, Daiming; Cao, **nzhong; Liu, Changpeng; **ng, Wei

doi:10.1038/s41467-018-04501-4

Chemically activating MoS₂ via spontaneous atomic palladium interfacial do** towards efficient hydrogen evolution

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Published: 29 May 2018

Volume 9, article number 2120, (2018)
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Chemically activating MoS₂ via spontaneous atomic palladium interfacial do** towards efficient hydrogen evolution

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Zhaoyan Luo^1,2^na1,
Yixin Ouyang³^na1,
Hao Zhang⁴,
Meiling **ao¹,
Junjie Ge¹,
Zheng Jiang ORCID: orcid.org/0000-0003-4297-464X⁴,
**lan Wang^3,5,
Daiming Tang⁶,
**nzhong Cao⁷,
Changpeng Liu¹ &
…
Wei **ng¹

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Abstract

Lacking strategies to simultaneously address the intrinsic activity, site density, electrical transport, and stability problems of chalcogels is restricting their application in catalytic hydrogen production. Herein, we resolve these challenges concurrently through chemically activating the molybdenum disulfide (MoS₂) surface basal plane by do** with a low content of atomic palladium using a spontaneous interfacial redox technique. Palladium substitution occurs at the molybdenum site, simultaneously introducing sulfur vacancy and converting the 2H into the stabilized 1T structure. Theoretical calculations demonstrate the sulfur atoms next to the palladium sites exhibit low hydrogen adsorption energy at –0.02 eV. The final MoS₂ doped with only 1wt% of palladium demonstrates exchange current density of 805 μA cm⁻² and 78 mV overpotential at 10 mA cm⁻², accompanied by a good stability. The combined advantages of our surface activating technique open the possibility of manipulating the catalytic performance of MoS₂ to rival platinum.

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Introduction

The lack of a cost-effective replacement for Pt has plagued the scale-up of hydrogen electrochemical production $\left( {2H^ + + 2{\mathrm{e}}^ - \to H_2} \right)$ for decades; the alternative catalytic materials are fundamentally limited by either a low catalytic efficiency or a short lifetime^{1, 2}. Lamellar MoS₂ has been regarded highly promising towards hydrogen evolution reaction (HER) since the activity of its metallic edges (ΔG_H = 0.06 eV) was theoretically predicted by Norskøv and co-workers³, and was later on proved experimentally by Jaramillo and co-workers^{4, 5}. The current guiding principles for advancing the MoS₂ catalytic efficiency are as follows: First, increase the atomically undercoordinated active sites density in the trigonal prismatic phase (2H) MoS₂, either through the preferentially exposing edge sites or through creating in-plane sulfur vacancies (SVs)^6,7,8. However, unleashing the intrinsically high activity is retarded by the semiconductive feature of 2H–MoS₂, where the charge transfer efficiency is limited by a deficiency of electrons at the reaction interface^{9, 10}. Second, drive the 2H phase MoS₂ into the conductive and therefore more catalytically active 1T phase^{11, 12}. The basal-plane S atoms are regarded as active sites in 1T–MoS₂; however, these S sites suffer from less favorable hydrogen adsorption features (ΔG_H = 0.17 eV) despite the greatly increased site density¹³. Beyond the above mentioned problems of 2H–MoS₂ and 1T–MoS₂, one major issue that both these materials encounter is their reduced stability because defective 2H–MoS₂ suffers from a high sulfur leaching rate¹⁴ and 1T–MoS₂ is intrinsically metastable¹⁵. Apparently, MoS₂ only become truly applicable towards the HER when the electronic conductivity, site density, intrinsic activity, and stability issues are simultaneously solved.

Here, we report a highly active and long-life MoS₂-based HER catalyst, which is achieved by chemically activating its surface basal plane. We accomplish this by devising a thermodynamically spontaneous interfacial MoS₂/Pd (II) redox reaction. Pd was atomically doped into the original Mo sites, causing the generation of SVs, the conversion to the stabilized 1T phase, the stabilization of defective sites, and the intrinsic activation of the 1T basal plane. The final Pd–MoS₂ exhibits the highest HER performance ever achieved on heteroatom-doped MoS₂-based materials in an acidic solution, along with good cycling stability and an exceptional anti-leaching feature that exceed those of undoped MoS₂.

Results

Design of Pd–MoS₂

We began by recognizing the redox characteristics of the chemically synthesized MoS₂. Unlike the standard MoS₂ samples, chemically synthesized MoS₂ generally contains a certain concentration of defects, thus resulting a final Mo to S stoichiometry deviated from the theoretical ratio of 1:2. According to the principles of the conservation of charge in defect chemistry, a mixed valence can thus be created, thereby endowing MoS₂ with redox power. We synthesized MoS₂ through a typical wet chemical method (homemade, MoS₂-HM, further denoted as MoS₂ in the following, see the Methods section for the details). The sample was first characterized by inductively coupled plasma mass spectrometry (ICP-MS), which shows a Mo to S stoichiometry of 1:1.87 (Supplementary Table 1), corresponding to a Mo average valence state of 3.74. The X-ray absorption near-edge structure (XANES) test was further carried out, with the standard 2H–MoS₂ used as a reference sample. The Mo L₃-edge XANES results (Fig. 1a) demonstrate a decrease in the white line resonance strength in comparison to the standard 2H MoS₂ sample, confirming a reduction in the unoccupied density of state (DOS) of Mo 4d and an average valance state lower than IV.¹⁶ The high-resolution Mo 3d X-ray photoelectron spectroscopy (XPS) measurement directly evidence the concurrent presence of Mo (III) and Mo (IV) (Fig. 1b) with deconvoluted doublets unambiguously assigned to Mo (III) (3d_3/2 at 231.5 eV and 3d_5/2 at 228 eV) and Mo (IV) (3d_3/2 at 231.9 eV and 3d_5/2 at 228.7 eV), respectively.

$$4{\rm{Mo}}^{3 + } \to 3{\rm{Mo}}^{4 + } + 3\mathrm{e}\left( {\rm{left}} \right) + V_{{\rm{Mo}}}'''({\rm{one}}\;{\rm{Mo}}\;{\rm{left}})$$

(1)

$$2{\rm{Mo}}^{4 + } + \mathrm{S}^{2 - } + 2\mathrm{e} \to 2{\rm{Mo}}^{3 + } + V_{\mathrm{S}}^{..}\left( {{\rm{one}}\;{\rm{S}}\;{\rm{left}}} \right)$$

(2)

The Mo (III)/Mo (IV) couple represents a standard electrode potential at –0.04 V. If properly paired with another redox couple, the redox reaction is expected to occur at the MoS₂/liquid or gas interface. It is noted that structural vacancies can be created on the MoS₂ surface during Mo redox process, according to the principles of defect chemistry, i.e., the conservation of mass and charge, and the host structure. As shown in Eqs. 1 and 2, while Mo (III) oxidation creates Mo vacancies, Mo (IV) reduction leads to the formation of SVs. Meanwhile, inter-valence charge transfer between two ions¹⁷ and abundant SVs¹⁸ can also induce the phase transformation into the 1T structure. After carefully screening the transition elements, we deliberately chose Pd (II) to accomplish the interfacial reaction with MoS₂, as illustrated in Fig. 1c. A two-step thermodynamically spontaneous reaction is expected: First, the redox process in Eqn. 3 is a thermodynamically spontaneous reaction ($E^\theta = 1.031\;{\mathrm{V}},\Delta rG^\theta = - 198.98\;{\rm{kJ}}$, Supplementary Note 1), which leads to the reduction of Pd and oxidation of Mo, therefore, creating Mo vacancies due to the principles of conservation of charge. Afterwards, however, metallic Pd is thermodynamically favorable towards anchoring to the energetic Mo vacancies and spontaneously forming the more stable Pd–S bond (Ksp=2.03 × 10⁻⁵⁸, Supplementary Table 2), as shown in Eq. 4, through its incorporation into the MoS₂ backbone ($E^\theta = 0.75\;{\mathrm{V}},\Delta rG^\theta = - 144.75\;{\rm{kJ}}$, Supplementary Note 1). By injecting electrons into the MoS₂ substrates, Mo (IV) is reduced back to Mo (III) and causes the leaching of S into the solution (law of conservation of charge) and the formation of S vacancies (see Eqs. 1–2). Thus, the MoS₂ basal plane is driven to spontaneously incorporate Pd–S covalent bonds and form abundant SVs, presumably accompanied with phase conversion to form 1T-Pd–MoS₂.

$$\begin{array}{l}2{\rm{Mo}}^{3 + } + {\rm{Pd}}^{2 + } \to 2{\rm{Mo}}^{4 + } + {\rm{Pd}}\\ \left( {E^\theta = 1.031\;{\mathrm{V}},\Delta rG^\theta = - 198.98\;{\rm{kJ}}} \right)\end{array}$$

(3)

$$\begin{array}{l}{\rm{Mo}}^{4 + } + {\mathrm{Pd}} + S^{2 - } \to {\rm{Mo}}^{3 + } + {\rm{Pd}}S\\ \left( {E^\theta = 0.75\;{\rm{V}},\Delta rG^\theta = - 144.75\;{\rm{kJ}}} \right)\end{array}$$

(4)

Structure alteration due to Pd atomic do**

The redox power of MoS₂ was first confirmed by a series of designed experiments between the pristine MoS₂ sample and the Pd (II), Pt (IV), and Au (III) complex solutions, where the detailed results and explanations are shown in Supporting Information (Supplementary Note 2, Supplementary Figs. 1-2, and Supplementary Tables 3-4). For the final Pd–MoS₂ samples, Pd with varied contents (1–15% Pd–MoS₂) were expectedly immobilized as Pd(II) in MoS₂, confirmed by the presence of the binding energy peaks at 336.7 eV (3d_5/2) and 342 eV (3d_3/2) (Fig. 2a). The Pd introduction does not induce observable morphological changes (Supplementary Figs. 3-4) to the MoS₂ nanosheets, and is (Supplementary Fig. 5) found homogeneously distributed by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and elemental map**, with no Pd-based crystalline phases observed (Fig. 2b). The results from in situ heat-treatment TEM coupled with electron energy loss spectroscopy (EELS, Supplementary Fig. 6) and X-ray diffraction (XRD, Supplementary Fig. 7) tests suggest that Pd was firmly integrated into the MoS₂ backbone without phase segregation even at 600 °C.

To elucidate the Pd local bonding environment and the occupation sites in MoS₂, extended X-ray absorption fine structure (EXAFS) and sub-angstrom resolution aberration-corrected HAADF-STEM were carried out. The Fourier transform of the k³-weighted Pd K-edge EXAFS spectra (Fig. 2c, R-space) for Pd–MoS₂ shows the disappearance of the first-shell Pd–Pd scattering peak at 2.51 Å in comparison with Pd foils, indicating that the Pd species are formed neither as metallic Pd nanoparticles nor as Pd clusters. A prominent peak centered at a much lower R position is observed at 1.84 Å instead, corroborating the dominance of the Pd–S scattering contribution. We further fitted the main Fourier transform peaks from 1.1 to 2.5 Å in the R-space to quantitatively extract the Pd coordination parameters (Supplementary Fig. 8 and Supplementary Table 5). The best fit indicated a Pd–S bond distance of 2.33 Å and a Pd to S coordination number of 4.33, which is smaller than the nominal Mo–S coordination¹⁹. The Mo K-edge EXAFS spectra (Fig. 2d) reveal a decrease in the Mo–S and Mo–Mo peak intensities after Pd do**. While the former can be attributed to newly generated SVs, the latter may originate from the rearrangement of both atoms due to Pd fixation and the formation of SVs. The absence of first-shell Pd–Mo scattering in both Fig. 2c, d excludes the possibility that Pd was directly bound with Mo, thereby confirming that Pd does not occupy the S sites in MoS₂. The sub-angstrom resolution aberration-corrected HAADF-STEM (Supplementary Fig. 9) shows an ordered MoS₂ crystalline structure after Pd fixation, which is evident of the atomic dispersion of Pd. Thus, judging from the successful immobilization of Pd into the MoS₂ frame, the only remaining possibility is that Pd replaces the Mo site, as we expected.

We next examined the influence of Pd atomic do** on the formation of S vacancies by comparing the 1%Pd-MoS₂ with pristine MoS₂. Electron spin resonance (ESR Fig. 2f) is utilized to detect the paramagnetic signals, and the ~337 mT (g = 2) signal intensity reflects the concentration of unsaturated sites with unpaired electrons. The pristine MoS₂ demonstrates a relative intensity at 0.52 × 10³ a.u. mg⁻¹ sites, corresponding to the edges, crystallite interfaces, and in-plane SVs²⁰. Remarkably, the 1%Pd–MoS₂ exhibits a signal intensity (1.55 × 10³ a.u. mg⁻¹) approximately 3 times that of the MoS₂, corroborating the formation of abundant SVs, in accordance with Eqn. 2 and the EXAFS results (with an in-plane Pd–S bond coordination number of 4.3 and a decrease in the scattering strength for the Mo–S path). We further employed positron annihilation lifetime spectroscopy (PALS, Supplementary Fig. 10 and Supplementary Table 6) to understand the form and content of the defects. τ₁ is assigned to the lattice defects, such as structural vacancies (τ_v) or dislocation vacancies (τ_d), while τ₂ is caused by clusters of vacancies. Notably, both τ₁ and τ₂ increased (Table 1) after 1% Pd do**, i.e., from 183.6 ± 5.3 and 355.5 ± 5.9 ps to 206.2 ± 4.7 and 384.6 ± 8.1 ps, respectively, which corresponded to an increase in the defect dimension. At the same time, the τ₁ and τ₂ relative intensities, denoted as I₁ and I₂, are also tuned, showing an increase in I₁ from 49.1% to 57.5% and a decrease in I₂ from 49.2% to 40.8%, which suggested that more single lattice SVs than vacancy clusters are introduced. ICP-OES results show that the final 1%Pd–MoS₂ represents a stoichiometry of Pd_0.02MoS_1.82, with an S ratio significantly lower than that in the pristine MoS_1.87 sample. According to the XPS surface analysis, the total amount of surface SVs created due to Pd do** is estimated to be 16.7% (Supplementary Table 7).

Table 1 Summary of the electrochemical and structural properties of 1%Pd–MoS₂ and MoS₂ catalysts

Full size table

The impact of Pd on the phase conversion was further investigated. Careful examination of the (Fig. 2e, Supplementary Fig. 11 and Supplementary Note 3) reveals structurally distinct domains in the 1%Pd–MoS₂ sample. A trigonal lattice structure corresponding to the 1T–MoS₂ and the common honeycomb lattice area of the 2H–MoS₂^{21, 22} are both clearly visible, as indicated by the circles in Fig. 2e. However, the predominant fraction of 1T–MoS₂ demonstrates the heterogeneous structure (2H + 1T) of the Pd–MoS₂, and Raman spectroscopy provides direct evidence of the 2H to 1T phase conversion. Pristine MoS₂ (Fig. 2g) exhibits two peaks at 378 cm⁻¹ and 404 cm⁻¹, attributable to the 2H phase vibrational configurations of the in-plane Mo–S phonon mode (E_2g) and the out-of-plane Mo-S mode (A_1g), respectively^23,24,25. In contrast, 1%Pd–MoS₂ exhibits new prominent peaks at 146, 278, and 332 cm⁻¹, which were obviously associated with the 1T-MoS₂ phonon modes, along with distinctly weakened 2H–MoS₂ signals (E_2g and A_1g). As a result of the phase conversion, the electronic conductivity (Fig. 2h, see the Supplementary Methods for details) is more than one order of magnitude greater for 1%Pd–MoS₂ (2.619 S cm⁻¹ versus 0.178 S cm⁻¹ for MoS₂) and approached that of 1T–MoS₂ (10–100 S cm⁻¹).²⁶

The HER catalytic behavior

Next, we examined the HER catalytic behavior of Pd–MoS₂ (1–15% do**), MoS₂, Pd/C, and commercial Pt/C catalysts with the representative linear sweep voltammograms (LSVs) summarized in Fig. 3a and Supplementary Fig. 12a-b. First, the pristine MoS₂ exhibited an overpotential of 10 mA cm⁻² (η@10 mA cm⁻²) at 328 mV, being consistent with those reported for 2H–MoS₂ in the literature^{27, 28}. Second, Pd do** leads to a breakthrough in the catalytic performance towards the HER, far exceeds that of the metallic Pd catalysts. The 1%Pd–MoS₂ exhibited a current density of 10 mA cm⁻² at an overpotential of only 89 mV. This result corresponds to the highest performance ever reported for heteroatom-doped MoS₂-based catalysts in acidic media^28,29,30,

The corresponding Tafel plots (Fig. 3b and Supplementary Fig. 12c) show that Pd atomic do** decreases the Tafel slope from 157 to 62–80 mV dec⁻¹ (Pd–MoS₂, 1–10%), demonstrating the transition of the rate determining step (RDS) away from the Volmer discharge reaction (H₃O⁺ + e⁻ → H_ads + H₂O). This transition is expected since Pd do** results in a phase conversion to 1T–Pd–MoS₂, thus making access to the electrons and the formation of H_ads easier at the interface. The exchange current densities (j₀) were further calculated to demonstrate the inherent HER activity, as shown in Fig. 3c. Pd do** is extremely effective for boosting the j₀ because 1%Pd–MoS₂ (805 µA cm⁻², the best of all reported MoS₂ based materials) is significantly better than MoS₂ (37.25 µA cm⁻²) and almost reached that of 20% Pt/C (918 µA cm⁻²) at the same catalyst loading^{7, 27, 33}. The electrochemical impedance spectroscopy (EIS) results explain the exceptional HER behavior of 1%Pd–MoS₂, where the Nyquist plots (Fig. 3d) show a large reduction in the charge transfer resistance (R_ct) from 92.89 Ω cm² for MoS₂ to 1.50 Ω cm² (Supplementary Fig. 13 and Supplementary Table 9) for 1%Pd–MoS₂.

In addition to having a high HER activity, 1%Pd–MoS₂ is a stable and long-life catalyst. We combined the electrochemical measurements and ICP-OES test to verify the material durability during operation. The chronoamperometry test results (Supplementary Fig. 14) manifest that the 1%Pd–MoS₂ exhibits an outstanding long-term operational stability beyond 100 h with an observed potential increase of only 14 mV. The ultrahigh stability of 1%Pd–MoS₂ was also proved by long-term cyclic voltammetry tests, where no obvious potential decay was observed (Fig. 3e) after 5000 cycles. In contrast, the MoS₂ electrode shows that η@10 mA cm⁻² increased by 10 mV after 5000 cycle tests. The ex situ ICP-OES results present a reduced sulfur concentration (2.724 versus 2.291 ppm) in the testing electrolyte (Fig. 3f), which indicated that the final defective 1%Pd–MoS₂ surface is even more stable than that of the pristine MoS₂. Moreover, we further examined the Pd–MoS₂ catalyst using XPS characterization after the above electrolysis test (Supplementary Fig. 15). Neither the content nor the state of Pd was altered, suggesting that Pd is firmly integrated into the MoS₂ backbone and highly stable under electrolytic conditions. This result is contradicted with those reported in the literature because highly active and defective catalysts are always accompanied by poor stability. Thus, by tailoring the chemical bond characteristics, we designed a MoS₂ material which simultaneously possesses good stability and activity.

Density functional theory calculations

Density functional theory (DFT) calculations were carried out to obtain atomic-scale insight into the do** effect of Pd. First, the energies of the Pd atoms on varied sites were calculated, and it is found that Pd exhibits a strong tendency to replace Mo with an exothermic energy of −2.22 eV compared to replacing S (−0.17 eV) adsorbed on the Mo atop site (1.75 eV) and the hollow site (2.35 eV) (see Supplementary Note 4 and Supplementary Fig. 16), thus supporting our expectation of the thermodynamically driven formation of the Pd–Mo–S_x compound. Second, we calculated the energy for the formation of SVs in MoS₂ and Pd–MoS₂ (Fig. 4b and Supplementary Fig. 17), and the energy for SVs formation decreased by ~1–2 eV due to the Pd do**. Thus, we can use the spontaneous Pd do** strategy to create a large number of SVs on the MoS₂. Third, we explored the influence of Pd do** and the SV concentration on the total phase energy of both the 1T and 2H MoS₂. In Fig. 4a-b, we found that 1T–MoS₂ becomes more stable than 2H–MoS₂ (see Supplementary Note 5 for the detailed results) with the presence of the Pd and SVs at certain concentrations. Specifically, the 1%Pd-MoS₂sample, as confirmed by the XPS (Supplementary Table 7) to possess surface concentrations of Pd at 3.47% and newly generated SVs at 16.7%, corresponding to the higher stability of the 1T versus 2H phase shown in Fig. 4b. Finally, we investigated the effect of Pd do** on the HER activity of the MoS₂ basal plane. The hydrogen adsorption free energy (ΔG_H) was used to evaluate the hydrogen evolution activity. The Pd sites themselves were calculated to be inactive as H does not form a very stable adsorption structure on Pd atop site (Supplementary Fig. 18). The ∆G_H of the SVs in the 1T MoS₂ is 0.09 eV, suggesting more favorable HER catalytic behavior than that of 1T basal-plane (∆G_H = 0.17 eV). Therefore, the increases in SVs concentration unambiguously contribute to the increased catalytic behavior, and we regard this as an increase in the site density. More excitingly, the ΔG_H of the S atop site adjacent to Pd (Pd–S*–Mo) in the 1T–Pd–MoS₂ exhibits an almost thermoneutral value of −0.02 eV, which was far better than the reported most favorable edge sites (Fig. 4c, d and Supplementary Fig. 19)^{4, 34}. In Fig. 4e, the difference in the S atom electronic structures of site 1 (Pd adjacent S site) and site 2 (regular in-plane S site) were elucidated by the projected p-orbital DOSs of S. Because the ionization energy of Mo is less than that of Pd, site 2 receives more electrons from the adjacent three Mo atoms with more p-states filled, which leads to a weaker interaction with hydrogen^{35,Full size image}

Discussion

By combining the experimental and theoretical calculation results, the high catalytic efficiency and the long life-time of the Pd–MoS₂ is confirmed, and the reason for the good HER catalytic feature can be rationally explained. We ascribe the fast Faradaic process to the following reasons: first, the facilitated electrical transport due to the phase conversion in Pd–MoS₂; nevertheless, this cannot be the sole reason since the best activity of pure 1T–MoS₂ reported in the literature was only η@10 mA cm⁻² = 187 mV¹². Second, the creation of abundant SVs, which are catalytically more active than the in-plane S sites in 1T–MoS₂. It is noted that even in the case of 1T–MoS₂ with abundant S vacancies and edges (the degree of defects exceeds 83.7%), the lowest overpotential ever reported was 153 mV³⁸. Moreover, the 1%Pd–MoS₂ exhibits high turnover frequency (TOF) per active site (Supplementary Note 6, Supplementary Table 10), which surpasses most state-of-the-art MoS₂ reported (Supplementary Table 11). Therefore, the exceedingly high HER performance of our catalysts is believed to only partially originate from the SVs in the 1T-MoS₂. Third, the generation of intrinsically more active Pd–S* sites with an almost thermoneutral ∆G_H, (see Supplementary Table 12 and Supplementary Note 7 for details).

Though the positive effect of Pd do** on MoS₂ activation is confirmed, a Pd do** content that was too high (>15%) resulted in the decay in performance, which can be explained as follows: in the Pd–MoS₂ catalyst, Pd atoms are not the active sites, and instead, they function by activating the MoS₂ basal plane through the introduction of SVs and by activating the adjacent S atoms (Pd–S*–Mo). However, a Pd content that is too high will result in a decrease in the site density of Pd–S*–Mo, and a S-vacancy concentration that is too high results in deviation of intrinsic activity from the optimal value^{39, 40}, both of which hinder the final HER performance.

The high in situ operating stability can be ascribed to two reasons: first, although 1T–MoS₂ is believed to be a metastable phase by itself, the incorporation of Pd makes the 1T–MoS₂ more stable than 2H–MoS₂ due to the simultaneous presence of Pd and SVs; second, the high Pd–S bond stability can provide overall stability. The ultralow solubility product of PdS renders the Pd–S bond 20 magnitudes more stable than other transition metal sulfides (Supplementary Table 2). Thus, the exposed undercoordinated in-plane sites are prevented from further leaching, thereby leading to a stabilized defective surface.

In summary, we chemically activated MoS₂ by thermodynamically spontaneous Pd atomic do**. This is the first report to unveil the MoS₂ redox feature and use it to induce interfacial heteroatom do**. We found that Pd replaces Mo at the surface, bonds covalently with S atoms at a coordination number of 4.3, causes SVs formation and phase conversion, and strongly activates the neighboring S sites for HER. The Pd–MoS₂ catalyst exhibits the highest activity towards the HER among phase-pure MoS₂ based materials in acid media. The overpotential for 1%Pd–MoS₂ at 10 mA cm⁻² is only 78 mV cm⁻². More attractively, the more defective Pd–MoS₂ demonstrates better matrix stability than the pristine MoS₂. Therefore, the catalytic efficiency and stability problems for MoS₂ are addressed at the same time, leading to a promising future in replacing Pt-based electrocatalysts for the HER.

Methods

Materials

The ammonium molybdate tetrahydrate ((NH₄)₆Mo₇O₂₄•4H₂O), thiourea (CH₄N₂S), palladium acetate (Pd(OAc)₂, chloroplatinic acid (H₂PtCl₆•6H₂O), Chlorchloric acid (H₂AuCl₄), and 5wt% Nafionionomer was purchased from Aldrich. Commercial 20wt% Pt/C (HiSPEC™ 3000, denoted as Pt/C-JM) was purchased from Johnson Matthey Company. Vulcan carbon black (XC-72) was purchased from Cabot Co. All of the chemicals were used directly without further treatment or purification. Highly purified argon (≥99.99%) was from Changchun Juyang Co Ltd. Ultrapure water with resistivity higher than 18 MΩ cm⁻¹ was used in all the experiments.

Materials synthesis

The HM–MoS₂ material was synthesized through a solvothermal method. Firstly, 0.5213 g of ammonium molybdate tetrahydrate ((NH₄)₆Mo₇O₂₄.4H₂O) and 1.035 g of thiourea (CH₄N₂S) were dissolved in 30 ml of water in a beaker and then sonicated for 1 h. The resulting homogenous solution was transferred into a 50 ml Teflon-lined stainless-steel autoclave and heated to 180 °C for 24 h. After cooling to room temperature, the precipitate was washed four times using deionized water via centrifugation, then dried at 50 °C for 12 h. The M–MoS₂ (M = Pt, Pd, Au) catalysts were synthesized as follows. In brief, 40 mg of MoS₂ powder was mixed with 30 ml H₂O in a round-bottom flask, and the mixture was ultrasonicated for 1 h; then each precursor solution (Pd (OAc)₂, H₂PtCl₆, H₂AuCl₄, Alfa Aesar) was added respectively and heated to 60 °C for 12 h. The products were obtained by filtration of the suspension, followed by dialysis in deionized water.

Materials characterization

The HAADF-STEM images were obtained by using a Titan 80–300 scanning/transmission electron microscope operated at 300 kV, equipped with a probe spherical aberration corrector. In-situ STEM-EELS was performed using a JEOL 3000 F TEM without Cs corrected. TEM, HAADF-STEM and EDX map** were tested on A Philips TECNAI G2 electron microscope operating at 200 kV accelerating voltage. SEM images were taken using a XL 30 ESEM FEG field emission scanning electron microscope. Mo and Pd K-edge X-ray absorption spectra were performed at the BL14W1 beamline of the Shanghai Synchrotron Radiation Facility, operating at 3.5 GeV with injection currents of 140–210 mA.⁴¹ Si (111) and Si (311) double-crystal monochromators were used to reduce the harmonic component of the monochrome beam. Mo and Pd foils were also tested in transmission mode as references. The Mo L₃-edge XANES spectra were tested at the 4B7A beamline of the Bei**g Synchrotron Radiation Facility (BSRF), China, in total electron yield (TEY) mode, where the sample drain current was collected under pressure smaller than 5 × 10⁻⁸ Pa. The beam from a bending magnet was monochromatic with a varied line-spacing plane grating and was refocused by a toroidal mirror. A Bruker ER 200D spectrometer was used to test the ESR, and the measurements were performed at room temperature. An AXIS Ultra DLD (Kratos Company) was used for XPS measurements, using a monochromic Al X-ray source. PALS data were collected on a fast−slow coincidence ORTEC system, and the time resolution was approximately 195 ps (full width at half-maximum). XRD measurements were performed on a PW-1700 diffractometer using a Cu Kα (λ = 1.5405 Å) radiation source (Philips Co.). Raman spectra were collected on a J-Y T64000 Raman spectrometer with 514.5 nm wavelength incident laser light. Elemental analyses were collected by ICP-AES-MS (Inductively Coupled Plasma-Atomic Emission Spectroscopy-Mass Spectrometry) using a Thermo Elemental IRIS Intrepid.

Electrochemical measurements

The electrochemical performance was measured in a N₂-saturated H₂SO₄ solution (0.5 M) using a standard three-electrode setup using Princeton Applied Research. The glassy carbon electrode (3 mm in diameter) coated with the catalysts served as the working electrode, a saturated calomel electrode (SCE) served as the reference electrode, and a graphite plate served as the counter electrode. Inks were prepared by ultrasonically dispersing 4 mg of the catalysts (MoS₂, Pd–MoS₂, Pd–C, and Pt–C) in a suspension containing 20 μL of a Nafion (5wt%) solution and 1000 μL (V_ethanol/V _{Ultrapure water} = 10:9). The catalyst loading was calculated as approximately 0.222 mg cm⁻², where the geometric area of the glassy carbon electrode used was 0.07065 cm². To calculate the TOF of the catalyst, we also optimized the loading of the catalyst. The HER performances were tested in H₂-saturated 0.5 M H₂SO₄ using the linear sweep voltammetry at a scan rate of 2 mV s⁻¹. All data presented were iR corrected, where the solution resistances were determined by EIS experiments. The potential values shown were with respect to the reversible hydrogen electrode (RHE).

DFT calculations

All first-principles calculations were implemented within the framework of DFT in the Vienna ab initio Simulation Packageusing (VASP).^42,43,44,45 The exchange-correlation interactions were treated within the generalized gradient approximation of the Perdew-Burke-Ernzerhof (PBE) type.^46,47,48 The plane-wave cutoff energy was 400 eV and a k-mesh of 3 × 3 × 1 was adopted to sample the Brillouin zone. Lattice geometries and atomic positions were fully relaxed until the forces on each atom were <0.01 eV/Å and the convergence threshold for energy was 10⁻⁴ eV. Vacuum layers of 15 Å were introduced to minimize interactions between adjacent layers in all supercells.

Data availability

The data that support the findings of this study are available from the authors on reasonable request; see author contributions for specific data sets.

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Acknowledgements

The work is supported by the National Natural Science Foundation of China (21633008), the National Key R&D Program of China (Grant No. 2017YFA0204800) the Strategic Priority Research Program of CAS (XDA09030104), Jilin Province Science and Technology Development Program (20160622037JC), Natural Science Funds of China (21525311 and 21773027). We thank the computational resources at the SEU and National Supercomputing Center in Tian**. J.G. thanks for the Hundred Talents Program of Chinese Academy of Science.

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These authors contributed equally: Zhaoyan Luo, Yixin Ouyang.

Authors and Affiliations

State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022, Changchun, China
Zhaoyan Luo, Meiling **ao, Junjie Ge, Changpeng Liu & Wei **ng
University of Science and Technology of China, 230026, Hefei, Anhui, China
Zhaoyan Luo
School of Physics, Southeast University, 211189, Nan**g, China
Yixin Ouyang & **lan Wang
Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 201204, Shanghai, China
Hao Zhang & Zheng Jiang
Synergetic Innovation Center for Quantum Effects and Applications (SICQEA), Hunan Normal University, 410081, Changsha, China
**lan Wang
National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki, 305-0044, Japan
Daiming Tang
Institute of High Energy Physics, Chinese Academy of Sciences, 100049, Bei**g, China
**nzhong Cao

Authors

Zhaoyan Luo
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Yixin Ouyang
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Hao Zhang
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Meiling **ao
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Junjie Ge
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Zheng Jiang
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**lan Wang
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Daiming Tang
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**nzhong Cao
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Changpeng Liu
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Wei **ng
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Contributions

W.X., J.G., J.W., and Z.J. co-supervised the whole work. Z.L. and M.X. contributed to the synthesis of material and the characterization. Z.L., M.X., W.X., J.G. and C.L. contributed to analysis of the electrochemical experiments results. Y.O. and J.W. contributed to the theory calculation. H.Z and Z.J. contributed to the X-ray absorption fine structure spectroscopy and total electron yield spectroscopy. D.T. contributed to the In-situ STEM - EELS,. X.C. contributed to the PALS. The manuscript was primarily written by Z.L., W.X., J.G., J.W. and Z.J. All authors contributed to discussions and manuscript review.

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Correspondence to Junjie Ge, Zheng Jiang, **lan Wang or Wei **ng.

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Luo, Z., Ouyang, Y., Zhang, H. et al. Chemically activating MoS₂ via spontaneous atomic palladium interfacial do** towards efficient hydrogen evolution. Nat Commun 9, 2120 (2018). https://doi.org/10.1038/s41467-018-04501-4

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Received: 23 October 2017
Accepted: 23 April 2018
Published: 29 May 2018
DOI: https://doi.org/10.1038/s41467-018-04501-4
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Chemically activating MoS2 via spontaneous atomic palladium interfacial do** towards efficient hydrogen evolution

Abstract

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Introduction

Results

Design of Pd–MoS2

Structure alteration due to Pd atomic do**

The HER catalytic behavior

Density functional theory calculations

Discussion

Methods

Materials

Materials synthesis

Materials characterization

Electrochemical measurements

DFT calculations

Data availability

References

Acknowledgements

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Chemically activating MoS₂ via spontaneous atomic palladium interfacial do** towards efficient hydrogen evolution

Design of Pd–MoS₂