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Synthesis and structures of two new Cu(I) frameworks bearing1,3-bis(4-pyridyl)propane and inorganic linkers

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Abstract

Two novel metal-organic coordination polymers [Cu2(bpp)Cl2] (1) and [Cu2(bpp)2SO4] ⋅DMF⋅ 3H2O (2) were prepared from the reactions of 1,3-bis(4-pyridyl)propane (bpp) with CuCl2 and CuSO4, respectively, which were characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and powder X-ray diffraction analysis. 1features inorganic one-dimensional [Cu2Cl2] ribbons, which are linked by the bpp ligands to form a three-dimensional metal-organic framework exhibiting a 3,3,4-connected 3-nodal topology. 2presents [Cu2SO4] inorganic dinuclear secondary building blocks which are further connected by the bpp ligands to construct a two-dimensional framework featuring flask-stacking appearance. They are typical examples of metal-organic framework constructed by the synergistic use of organic and inorganic linkers.

We present two typical metal-organic frame works of Cu(I) constructed by the synergistic use of organic and inorganic linkers, which feature 3,3,4-connected 3-nodal 3D network and 2D framework with flask-stacking appearance, respectively.

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Acknowledgement

The authors thank the financial support by National Natural Foundation of China (grant no. 21261004), Guangxi Natural Science Foundation of China (grant no. 2013GXNSFGA019008 and 2013GXNSFAA01 9039).

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Authors and Affiliations

  1. State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, 541004, P R China

    ZHAOBO HU, WENQIANG JU, YUNING LIANG & ZILU CHEN

  2. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, P R China

    BO LI

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  1. ZHAOBO HU
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  2. BO LI
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  3. WENQIANG JU
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  4. YUNING LIANG
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Corresponding authors

Correspondence to BO LI or ZILU CHEN.

Additional information

Supplementary Information (SI)

Crystallographic data for the two structures in this paper have been deposited in the Cambridge Crystallographic Database Center, CCDC, 12 Union Road, Cambridge CB21EZ, UK. Copies of the data can be obtained free of charge on quoting the depository number CCDC-1418270 for 1 and 1418165 for 2 (Fax: + 44-1223-336-033; E-mail: deposit@ccdc.cam.ac.uk, http://www.ccdc.cam.ac.uk). IR spectra (figures S1, S2), TG (figures S3, S4), XRD (figures S5, S6) and the Space-filling diagram of the two-dimensional sheet of 2 (figure S7) are given in the supplementary information, which is available at www.ias.ac.in/chemsci.

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HU, Z., LI, B., JU, W. et al. Synthesis and structures of two new Cu(I) frameworks bearing1,3-bis(4-pyridyl)propane and inorganic linkers. J Chem Sci 128, 893–898 (2016). https://doi.org/10.1007/s12039-016-1100-6

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  • DOI: https://doi.org/10.1007/s12039-016-1100-6

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