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Metal-organic framework-based sensors for nitrite detection: a short review

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Abstract

Nitrite contamination in food and the environment has attracted incredible public attention owing to its detrimental effects on living systems. It is crucial to develop rapid, easy-to-use, accurate, and cheap analytical techniques to monitor nitrite levels. Metal-organic frameworks are a type of inorganic-organic hybrid crystal material known for their ultrahigh surface area, ordered porous structure, ease of function, as well as their catalytic activity or luminescence in certain situations. This allowed researchers to design a diverse array of sensors for the measurement of nitrite. This article highlights recent progress on the application of metal-organic frameworks towards the sensing of nitrite based on their unique electrical and optical features. According to the design strategies, electrochemical sensors based on metal-organic frameworks can be classified as pristine metal-organic frameworks, metal-organic framework composites, or metal-organic framework derivatives, while optical sensors can be divided into two classes, luminescent metal-organic frameworks, and metal-organic frameworks with luminescent guests. Each category was herein discussed and examples were provided. At the end of the review, current challenges and future trends are also addressed.

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Abbreviations

NPs:

Nanoparticles

MOFs:

Metal-organic frameworks

LMOFs:

Luminescent MOFs

2D:

Two-dimensional

TCPP:

4,4,4,4-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)

MWCNTs:

Multi-walled carbon nanotubes

RSD:

Relative standard deviation

GO:

Graphene oxide

ERGO:

Electrochemically reduced graphene oxide

TDPAT:

2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine

Cyt c:

Cytochrome c

CP:

Carbon polyhedron

Ln-MOFs:

Lanthanide MOFs

Rh110:

Rhodamine 110

LR:

Linear range

LOD:

Limit of detection

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Funding

The authors acknowledge financial support from the Innovative and Entrepreneurial Talent of Jiangsu Province; the Science and Technology Innovation Cultivation Fund of Yangzhou University under Grant 2019CXJ189; and the “Lvyang **feng” talents attracting plan.

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Authors and Affiliations

  1. School of Food Science and Engineering, Yangzhou University, Yangzhou, 225127, Jiangsu, China

    Zhengfei Yang, Yueyue Zhong, **nyong Zhou, Weijia Zhang, Yongqi Yin & Weiming Fang

  2. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225127, Jiangsu, P. R. China

    Zhengfei Yang & Huaiguo Xue

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Correspondence to Weiming Fang or Huaiguo Xue.

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Yang, Z., Zhong, Y., Zhou, X. et al. Metal-organic framework-based sensors for nitrite detection: a short review. Food Measure 16, 1572–1582 (2022). https://doi.org/10.1007/s11694-021-01270-5

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