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One-Pot Trap** Luminescent Rhodamine 110 into the Cage of MOF-801 for Nitrite Detection in Aqueous Solution

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Abstract

Given to the severely toxic effect on aquatic organisms and serious carcinogen to human being of nitrite, the development of a convenient and sensitive method for its detection is of greatly significance. Herein, a novel Rh110@MOF-801 fluorescent probe was synthesized in a one-pot strategy and was successfully used in the determination of nitrite. This strategy, taking full advantages of fluorescent rhodamine 110 (Rh110) molecules and porous MOFs, could not only overcome the shortcomings of hydrophobicity of dye molecules and preserve its fluorescent properties perfectly, but also facilitate the interaction between nitrite and fluorescent recognition sites thanks to the open structure and good stability of porous MOFs. The results showed that the fluorescence quenching level of Rh110@MOF-801 fluorescent probe was linear with the applied nitrite concentration in the range of 2–7 µM with a limit of detection of 0.2 µM. Furthermore, the well-designed fluorescence probe could specifically recognize nitrite and would hardly be affected by other possibly coexistent interfering substances. It has been successfully used in quantitative detection of nitrite content in water samples mixed with interfering ions, prefiguring its great application potentials for nitrite monitoring.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of China (Grant Nos. 51072053, 51372084), the 111 Project (B14018) and the National Science Foundation of Shanghai (Grant No. 18ZR1408700).

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Authors and Affiliations

  1. Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, China

    Chengjie Huang, Yunxi Ye, Liwei Zhao, Yongsheng Li & **lou Gu

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  1. Chengjie Huang
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Electronic Supplementary Material

Digital pictures of MOF-801 and Rh110@MOF-801 powder, SEM image, DLS picture, N2 sorption isotherm, XRD patterns, UV-Vis spectrum picture, Rh110@MOF-801 photostability picture and image depicting the detection limit of Rh110@MOF-801 sensor, the difference UV-Vis spectrum of Rh110@MOF-801 + nitrite.

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Huang, C., Ye, Y., Zhao, L. et al. One-Pot Trap** Luminescent Rhodamine 110 into the Cage of MOF-801 for Nitrite Detection in Aqueous Solution. J Inorg Organomet Polym 29, 1476–1484 (2019). https://doi.org/10.1007/s10904-019-01111-5

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