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Synthesis, Structures, and Catalytic Properties of Two Zinc(II) Coordination Polymers Constructed from Polycarboxylate and Bis(Benzimidazole) Ligands

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Abstract

Two Zn(II) coordination polymers, formulated as {[Zn(L1)0.5(btc)0.5(H2O)]·H2O} n (1) and {[Zn(L2)(1,4-ndc)]·2H2O} n (2) [L1 = 1,4-bis(2-methylbenzimidazole-1-ylmethyl)benzene, L2 = 1,4-bis(2-methylbenzimidazole)butane, H4btc = butane-1,2,3,4-tetracarboxylic acid, 1,4-H2ndc = 1,4-naphthalenedicarboxylic acid] have been synthesized and structurally characterized by single crystal X-ray diffraction. Complex 1 features a 3D (3,4)-connected network with the topology of fsh-3,4-P21/c. Complex 2 is a 2D (4,4) grid with sql topology and further extends into a 3D supramolecular framework by π–π stacking interactions. In addition, the thermal stability, fluorescence, and catalytic properties of two complexes for degrading methyl orange dye in a Fenton-like process were investigated.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation—Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. College of Chemical Engineering, North China University of Science and Technology, Tangshan, 063009, Hebei, People’s Republic of China

    Ju-Meng Hu, Yong-Guang Liu, Zeng-Chuan Hao & Guang-Hua Cui

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  1. Ju-Meng Hu
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  2. Yong-Guang Liu
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Correspondence to Guang-Hua Cui.

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Hu, JM., Liu, YG., Hao, ZC. et al. Synthesis, Structures, and Catalytic Properties of Two Zinc(II) Coordination Polymers Constructed from Polycarboxylate and Bis(Benzimidazole) Ligands. J Inorg Organomet Polym 26, 598–605 (2016). https://doi.org/10.1007/s10904-016-0339-1

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  • DOI: https://doi.org/10.1007/s10904-016-0339-1

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