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Syntheses and Characterization of Three Coordination Polymers of Zinc(II) and Cadmium(II) with Dicarboxylates and Bis(thiabendazole) Ligands

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Abstract

Three d 10 coordination polymers formulated as [Zn(L1)2(mip)] n (1), [Zn(L1)(2,6-ndc)] n (2) and [Cd(L2)0.5(bpdc)] n (3) (L1 = 1,1′-(1,3-propanediyl)bis(thiabendazole), L2 = 1,1′-(1,6-hexanediyl)bis(thiabendazole), H2mip = 5-methylisophthalic acid, 2,6-H2ndc = 2,6-naphthalenedicarboxylic acid, H2bpdc = 4,4′-biphenyldicarboxylic acid) were hydrothermally synthesized. Complexes 1–3 were characterized by elemental analysis, IR spectroscopy, X-ray powder diffraction analysis, and single crystal X-ray diffraction. Complexes 1 and 2 present different chain structures, both of them are extended into 2D supramolecular architectures via C–H···O hydrogen bonds, while 3 is a three-fold interpenetrating three-dimensional framework with binodal 4,4-connected mog topology. The thermal stability, UV–visible spectroscopy and luminescence properties of complexes 1–3 were also examined. Furthermore, complex 3 exhibits relatively positive catalytic activity towards the degradation of methyl orange in a Fenton-like process.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, Tangshan, Hebei, 063009, People’s Republic of China

    Xu Zhang, Yan-Qin Zhao, Zeng-Chuan Hao & Guang Hua Cui

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  1. Xu Zhang
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  2. Yan-Qin Zhao
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Correspondence to Guang Hua Cui.

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Zhang, X., Zhao, YQ., Hao, ZC. et al. Syntheses and Characterization of Three Coordination Polymers of Zinc(II) and Cadmium(II) with Dicarboxylates and Bis(thiabendazole) Ligands. J Inorg Organomet Polym 26, 1014–1022 (2016). https://doi.org/10.1007/s10904-016-0397-4

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  • DOI: https://doi.org/10.1007/s10904-016-0397-4

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