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Rigid and Flexible Lanthanide Complexes with an Infinite Ln–O–Ln Framework: Synthesis, Structure and Properties

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Abstract

A series of new lanthanide coordination polymers, Ln(pydc)(Hglu) (Ln = Nd(1), Pr(2); H2glu = glutaric acid; 2,5-H2pydc = 2,5-pyridine dicarboxylic acid), have been synthesized hydrothermally from the self-assembly of the lanthanide ions (Ln3+) with rigid 2,5-pyridine dicarboxylic acid and flexible glutaric acid. They were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Structural analyses reveal that both of the complexes were crystallized in monoclinic space group P21/c and have intricate 3D net-structures, which contain an infinite 1D Ln–O–Ln chain structure. In addition, the phase purities of the bulk samples were identified by X-ray powder diffraction. The thermogravimetric analysis of 1 is discussed in detail.

Graphical Abstract

A new series of lanthanide coordination polymers have been synthesized hydrothermally from the self-assembly of the lanthanide ions (Ln3+) with rigid 2,5-pyridine dicarboxylic acid and the flexible glutaric acid. Structural analyses reveal that both complexes were crystallized in monoclinic space group P2 1 /c and have intricate 3D net-structures, which contain an infinte 1D Ln-O-Ln chain structure.

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Acknowledgments

This work was supported by the grants of the National Natural Science Foundation of China (Grant No. 20771051), and the Education Foundation of Liaoning Province in China (Grant No. 2007T093, 20060494) for financial assistance.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People’s Republic of China

    Zhuo Wang, Feng-Ying Bai, Yong-Heng **ng, Yan **e & Shu-Yun Niu

  2. Institute of Chemistry, Chinese Academy of Sciences, 100190, Bei**g, People’s Republic of China

    **ao-Qing Zeng & Mao-Fa Ge

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  1. Zhuo Wang
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  2. Feng-Ying Bai
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  3. Yong-Heng **ng
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Correspondence to Yong-Heng **ng.

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Wang, Z., Bai, FY., **ng, YH. et al. Rigid and Flexible Lanthanide Complexes with an Infinite Ln–O–Ln Framework: Synthesis, Structure and Properties. J Inorg Organomet Polym 20, 242–249 (2010). https://doi.org/10.1007/s10904-010-9333-1

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