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Electron impact ionization of silver clusters Ag n ,n≦36

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

Electron impact ionization of gas phase silver clusters Ag n ,n≦36 has been achieved in the threshold region. The vertical ionization potentials in this region clearly demonstrate the evidence of shell effects as well as a distinct even-odd oscillation up ton≃20. Their general size dependence is somewhat different from that of the alkali metal clusters due to the presence of thed-electrons.

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References

  1. Cf. e.g. 5th International Symposium on Small Particles and Inorganic Clusters, 10–14 September 1990, Konstanz, Federal Republic of Germany

  2. Knight, W.D., Clemenger, K., Heer, W.A. de, Saunders, W.A., Chou, M.Y., Cohen, M.L.: Phys. Rev. Lett.52, 2141 (1984)

    Google Scholar 

  3. Ekardt, W.: Phys. Rev. B29, 1558 (1984)

    Google Scholar 

  4. Koutecký, J., Bonačić-Koutecký, V., Boustani, I., Fantucci, P.: In: Elemental and molecular clusters, p. 214, Benedek, G., Martin, T.P., Pacchioni, G. (eds.) Berlin, Heidelberg, New York: Springer 1987

    Google Scholar 

  5. Knight, W.D.: Solid State Phys.40, 93 (1987)

    Google Scholar 

  6. Katakuse, I., Ichihara, T., Fujita, Y., Matsuo, T., Sakurai, T., Matsuda, H.: Int. J. Mass Spectrom. Ion Proc.67, 229 (1985);

    Google Scholar 

  7. Katakuse, I., Ichihara, T., Fujita, Y., Matsuo, T., Sakurai, T., Matsuda, H.: Int. J. Mass Spectrom. Ion Proc.74, 33 (1986)

    Google Scholar 

  8. LaiHing, K., Cheng, P.Y., Duncan, M.A.: Z. Phys. D — Atoms, Molecules and Clusters -13, 161 (1989)

    Google Scholar 

  9. Kandler, O., Athanassenas, K., Echt, O., Kreisle, D., Leisner, T., Recknagel, E.: 5th International Symposium on Small Particles and Inorganic Clusters, 10–14 September 1990, Konstanz, Federal Republic of Germany; Z. Phys. D — Atoms, Molecules and Clusters19, 151 (1991) Rabin, I., Jackschath, C., Schulze, W., ibid.19, 153 (1991)

    Google Scholar 

  10. Ganteför, G., Gausa, M., Meiwes-Broer, K.H., Lutz, H.O.: J. Chem. Soc. Faraday trans.86, 2483 (1990)

    Google Scholar 

  11. Ho, J., Erwin, K.M., Lineberger, W.C.: J. Chem. Phys.93, 6897 (1990)

    Google Scholar 

  12. Franzreb, K., Wucher, A., Oechsner, H.: Z. Phys. D — Atoms, Molecules and Clusters17, 51 (1990)

    Google Scholar 

  13. Schulze, W., Frank, F., Charlé, K.-P., Tesche, B.: Ber. Bunsenges. Phys. Chem.88, 263 (1984)

    Google Scholar 

  14. Winter, B.: Ph. D. thesis, Freie Universität Berlin (1988)

  15. Goldenfeld, I., Frank, F., Schulze, W., Winter, B.: Int. J. Mass Spectrom. Ion Proc.71, 103 (1986)

    Google Scholar 

  16. Rabin, I.: Ph. D. thesis, Freie Universität Berlin (1990)

  17. Bréchignac, C., Cahuzac, Ph.: Chem. Phys. Lett.117, 365 (1985)

    Google Scholar 

  18. Perdew, J.P.: Phys. Rep. B37, 6175 (1988); Perdew, J.P.: In: Condensed Matter Theories, vol. 4, Keller, J. (ed.) New York: Plenum Press 1989

    Google Scholar 

  19. Seidl, M., Meiwes-Broer, K.-H., Brack, M. (submitted to J. Chem. Phys.)

  20. Schumacher, E.: Chimia42, 357 (1988)

    Google Scholar 

  21. Kappes, M.M., Schär, M., Rothlisberger, U., Yeretzian, Ch., Schumacher, E.: Chem. Phys. Lett.143, 251 (1988)

    Google Scholar 

  22. Charlé, K.-P., Schulze, W., Winter, B.: Z. Phys. D — Atoms, Molecules and Clusters,12, 471 (1989)

    Google Scholar 

  23. Chou, M., Cleland, A., Cohen, M.: Solid State Commun.52, 645 (1984); Penzar, Z., Ekhardt, W.: Z. Phys. D — Atoms, Molecules and Clusters17, 69 (1990)

    Google Scholar 

  24. Flad, J., Igel-Mann, G., Preuss, H., Stoll, H.: Chem. Phys.90, 257 (1984)

    Google Scholar 

  25. Gingerich, K.A.: Faraday Discuss. Chem. Soc.14, 109 (1980)

    Google Scholar 

  26. Ionization potential and appearance potential measurements, Levin, R.D., Lias, S.G. (eds.) NBS (1982); see also [11]

  27. Calzaferri, G.: Chimia40, 74 (1986)

    Google Scholar 

  28. Mostafavi, M., Marignier, J.L., Amblard, J., Belloni, J.: Radiat. Phys. Chem.34, 605 (1989)

    Google Scholar 

  29. Henglein, A.: Curr. Chem.143, 113 (1987)

    Google Scholar 

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Jackschath, C., Rabin, I. & Schulze, W. Electron impact ionization of silver clusters Ag n ,n≦36. Z Phys D - Atoms, Molecules and Clusters 22, 517–520 (1992). https://doi.org/10.1007/BF01426093

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  • DOI: https://doi.org/10.1007/BF01426093

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