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Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes
Organosilicon compounds have shown tremendous potential in drug discovery and their synthesis stimulates wide interest. Multicomponent cross-coupling...
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First Synthesis of N-Organyl-S-silylorganyl Derivatives of 2-Mercaptobenzothiazole
AbstractThe alkylation of 2-[dimethyl-(phenyl)/(phenylethynyl)silyl)methylthio]benzothiazoles with α-iodoketones of the aliphatic, aromatic and...
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Organosilicon Derivatives Based on 2-Aminothiazolium Cations
AbstractThe reactions of 2-aminothiazole and 2-aminobenzothiazole with iodomethyl silanes in the absence of a base gave previously unknown...
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Synthesis of Acetylenic [Chloro(iodo)methyl]silanes and 2-Sulfanylbenzothiazoles Based Thereon
AbstractBromomagnesium derivatives of ethynylsilanes [Me 4– n Si(C≡CMgBr) n , n = 1–3] reacted with chloro(chloromethyl)dimethylsilane to give the...
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First Bis-Organosilicon Derivatives of Aminothiazoles
AbstractNew organosilicon 2-aminothiazolium polyiodides were first synthesized by the reaction of 2-aminothiazole or 2-aminobenzothiazole with...
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Synthesis of Novel Carbofunctional Organosilicon Sulfanyl Derivatives of Benzazoles and Triazoles
AbstractPreviously unknown carbofunctional organosilicon derivatives of azoles are synthesized by the reactions of sulfanyl derivatives of...
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Silyl Modification of Biologically Active Compounds. 14. Organosilicon Lipid-like Derivatives of Hydroxyethyl Tetrahydro(iso)quinoline and Thiazole with Antitumour, Antibacterial and Antifungal Properties
PurposeA series of novel lipid-like O- and N-(3-trimethylsilyl)propyl derivatives of N-(2-hydroxyethyl)-1,2,3,4-tetrahydroquinoline,...
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Synthesis of arylaliphatic chlorosilanes by alkylation of aromatic compounds by alkenylchlorosilanes
In combination with HCl or H 2 O, EtAlCl 2 is an active catalyst for alkylation of aromatic compounds by alkenylchlorosilanes, and compounds of boron,...
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Alkylation of aromatic compounds with allylchlorosilanes
1. It was shown that aromatic compounds can be alkylated by allylchlorosilanes in presence of aluminum chloride.
2. The alkylation of aromatic...
