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Study on the effects of various incubation conditions on aggregation of SOD1 variants: disulfide bond reduction and demetallation synergistically promote generation of non-amyloid amorphous aggregates from SOD1 mutants
Amyotrophic lateral sclerosis (ALS) is a progressive fetal neurodegenerative disease that affects neural cells in the brainstem and spinal cord,...
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Supramolecular polymer network constructed by a functionalized polyimidazolium salt derived from metal-carbene template approach
In this study, we present a supramolecular templating approach for constructing polyimidazolium salt containing crown ether and cyclobutane moieties....
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The Synthesis of a D4h Symmetric Porphyrin Nanoball Using Selective Demetallation
The synthesis of heterometallated zinc and magnesium porphyrin oligomers allowed selective demetallation to be used as a synthetic tool to prepare a...
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Transition-Metal-Complexed Catenanes and Rotaxanes in Motion: Towards Molecular Machines
In the course of the last decade, many dynamic molecular systems, for which the movements are controlled from the outside, have been elaborated....
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Excited state dynamics of Zn–salophen complexes
Zn–salophen complexes are a promising class of fluorescent chemosensors for nucleotides and nucleic acids. We have investigated, by means of steady...
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Synthesis of contra-helical trefoil knots with mechanically tuneable spin-crossover properties
Molecular knots attract attention on account of their topological intricacies and potential application. Tying molecular knots with different...
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Nicholas Reaction
Hexacarbonyldicobalt-stabilized propargyl cation is captured by a nucleophile. Subsequent oxidative demetallation then gives the propargylated...
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Photoinduced E to Z isomerization of tetraphenylethylene derivatives within organometallic supramolecular assemblies
Isolation of E -1,2-bis(4-bromophenyl)-1,2-diphenyl-ethylene from the E/Z isomer mixture obtained by a McMurry coupling reaction and reaction of this...
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Performance enhancement and degradation mechanism identification of a single-atom Co–N–C catalyst for proton exchange membrane fuel cells
The development of catalysts free of platinum-group metals and with both a high activity and durability for the oxygen reduction reaction in proton...
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A Novel Rhodamine Probe Acting as Chemosensor for Selective Recognition of Cu2+ and Hg2+ Ions: An Experimental and First Principle Studies
Copper and Mercury ions have vital role to play in biological world as their excess or deficiency can cause different type of diseases in human being...
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Unravelling the complex causality behind Fe–N–C degradation in fuel cells
Beyond great advances in initial activity, Fe–N–C catalysts face the next challenge of stability issue in acidic medium that must be overcome to...
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Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts
Fe–N–C catalysts are the most promising platinum group metal-free oxygen-reduction catalysts, but they suffer from a low density of active metal...
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Monosymmetric Fe-N4 sites enabling durable proton exchange membrane fuel cell cathode by chemical vapor modification
The limited durability of metal-nitrogen-carbon electrocatalysts severely restricts their applicability for the oxygen reduction reaction in proton...
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Integrated energy storage and CO2 conversion using an aqueous battery with tamed asymmetric reactions
Develo** a CO 2 -utilization and energy-storage integrated system possesses great advantages for carbon- and energy-intensive industries. Efforts...
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Self-assembly of a layered two-dimensional molecularly woven fabric
Fabrics—materials consisting of layers of woven fibres—are some of the most important materials in everyday life
1 . Previous nanoscale weaves2 –16 ...
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Atomically dispersed iron sites with a nitrogen–carbon coating as highly active and durable oxygen reduction catalysts for fuel cells
Nitrogen-coordinated single atom iron sites (FeN 4 ) embedded in carbon (Fe–N–C) are the most active platinum group metal-free oxygen reduction...
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Metal-Responsive DNA Strand Displacement Reactions Driven by Base Pair Switching of 5-Hydroxyuracil Nucleobases
Toehold-mediated DNA strand displacement reactions (SDRs) are an essential tool for the construction of DNA-based molecular machines. In this...
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Synthesis methods and recent advances in hierarchical zeolites: a brief review
Zeolites are crystalline microporous aluminosilicates that are extensively used as adsorbents and catalysts in the chemical and petrochemical...
