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Two-electron redox chemistry via single-atom catalyst for reversible zinc–air batteries
Rechargeable zinc–air batteries (ZABs) are considered to be one of the most sustainable alternative systems in a post-lithium-ion future owing to...
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The role of charge in microdroplet redox chemistry
In charged water microdroplets, which occur in nature or in the lab upon ultrasonication or in electrospray processes, the thermodynamics for...
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Photochemical Redox Reactions of Mercury
Mercury is a unique heavy metal element with several oxidation states, whose changes are sensitive to photo energy, directly or indirectly....
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Bacterial hydrogen sulfide drives cryptic redox chemistry in gut microbial communities
Microbial biochemistry contributes to a dynamic environment in the gut. Yet, how bacterial metabolites such as hydrogen sulfide (H 2 S) mechanistically...
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Redox Equilibria
This chapter focuses on equilibria involving electron transfers (redoxRedox reactions). A systematic approach to identify electron transfers and to...
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A theoretical framework for oxygen redox chemistry for sustainable batteries
Lithium-rich layered oxides have emerged as a new model for designing the next generation of cathode materials for batteries to assist the transition...
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Starch-mediated colloidal chemistry for highly reversible zinc-based polyiodide redox flow batteries
Aqueous Zn-I flow batteries utilizing low-cost porous membranes are promising candidates for high-power-density large-scale energy storage. However,...
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Strain-regulated Gibbs free energy enables reversible redox chemistry of chalcogenides for sodium ion batteries
Manipulating the reversible redox chemistry of transition metal dichalcogenides for energy storage often faces great challenges as it is difficult to...
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Bioinorganic Chemistry
In biological systems, metals play an important role. They participate in electron transfer or catalyze important reactions (metalloenzymes). Many of...
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Redox-Active Polymers for Batteries
Electrochemical energy storage is critical in accelerating the transition to a low-carbon future for grid storage and transportation. While most...
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Mo do** provokes two electron reaction in MnO2 with ultrahigh capacity for aqueous zinc ion batteries
Rechargeable aqueous zinc ion batteries (AZIBs) based on manganese dioxide (MnO 2 ) have received much attention for large-scale energy storage...
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Redox Reactions of Coordination Compounds
Chemical reactions can be divided into two categories, substitution reactions and redox reactions. In the previous chapter, we considered the...
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Redox-tunable isoindigos for electrochemically mediated carbon capture
Efficient CO 2 separation technologies are essential for mitigating climate change. Compared to traditional thermochemical methods, electrochemically...
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Oxygen Redox in Battery Cathodes: A Brief Overview
The participation of oxygen or other anionic species in redox activities in cathode materials for lithium- and sodium-ion battery systems is known to...
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Electrochemical radical-polar crossover: a radical approach to polar chemistry
Radical-polar crossover (RPC) reaction bridges the gap between one- and two-electron reactivities, thus providing an ideal solution to overcome the...
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Recent Advances in Redox Flow Batteries Employing Metal Coordination Complexes as Redox-Active Species
Redox flow batteries (RFBs) that employ sustainable, abundant, and structure-tunable redox-active species are of great interest for large-scale...
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Halogen-powered static conversion chemistry
Halogen-powered static conversion batteries (HSCBs) thrive in energy storage applications. They fall into the category of secondary non-flow...
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Selective amide bond formation in redox-active coacervate protocells
Coacervate droplets are promising protocell models because they sequester a wide range of guest molecules and may catalyze their conversion. However,...
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MAO Visible Spectroscopy for Ligand Interactions, Redox Chemistry, and Kinetics of Irreversible Inhibition
The covalently bound FAD cofactor in monoamine oxidase (MAO) is reduced by the amine substrate and reoxidized by oxygen. Visible spectroscopy...
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Geochemistry and mineral chemistry of the armoor granitoids, eastern dharwar craton: implications for the redox conditions and tectono-magmatic environment
The mineralogical and geochemical characteristics of the K-rich granites from the Armoor granitic rocks in the northeastern portion of the Eastern...
