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Materials Chemistry of Group 13 Nitrides
The OMVPE process has been used to grow thin films of group 13 nitrides, namely GaN, InN, and AlN. In recent years there has been a great deal of...
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State of the Art. Chemical Synthesis of Biophosphates and their Analogues via PIII Derivatives
This chapter is concerned with preparation and applications of tricoordinate phosphorus compounds in synthesis of biophosphates and their structural...
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Complexes with a Metal-Phosphorus Triple Bond
A survey of the existing complexes containing a transition metal-phosphorus triple bond is presented. Based on the different types of these...
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DNA Electron Transfer Processes: Some Theoretical Notions
Charge motion within DNA stacks, probed by measurements of electric conductivity and by time-resolved and steady-state damage yield measurements, is...
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Polarons and Transport in DNA
It has been widely considered that the wavefunction of an extra electron or hole on the base stack of a DNA molecule is confined to a single site,...
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Cyclopropanation with Ruthenium Catalysts
In this decade, a variety of ruthenium complexes have been intensively investigated that exhibit catalytic activity for cyclopropanation of olefins...
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Ruthenium Vinylidenes and Allenylidenes in Catalysis
During the last decade, ruthenium catalysis, including asymmetric catalysis, has attracted increasing interest owing to its wide range of...
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Activation of Inert C–H Bonds
The development of catalytic reactions involving carbon–hydrogen bond cleavage is one of the most attractive research subjects in organic and...
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Heat Capacity Studies of Spin Crossover Systems
As the spin crossover phenomena occurring in Oh symmetry involve a transfer of electrons between the eg and t2g orbitals, the metal-to-ligand bond...
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Isokinetic and Isoequilibrium Relationships in Spin Crossover Systems
A thorough statistical mechanical analysis of sources of variations and correlations in ΔE 0 and ΔS 0 of spin crossover...
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A Covalent Chemistry Approach to Giant Macromolecules with Cylindrical Shape and an Engineerable Interior and Surface
This article divides the synthetic routes leading to dendronized polymers into two main categories (attach-to and macromonomer) and compares their...
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Octahedral Zirconium Complexes as Polymerization Catalysts
The synthesis and X-ray structure of various octahedral zirconium complexes and their catalytic properties in the polymerization of α-olefins are...
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Metal Carbene Reactions from Dirhodium(II) Catalysts
The dirhodium(II) core is a template onto which both achiral and chiral ligands are placed so that four exist in a paddle wheel fashion around the...
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Gels as Templates for Nanotubes
The design of artificial models for “biomineralization” processes that utilize sol-gel polycondensation has led to a merging of inorganic materials...
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Carboselenothioic and Carbodiselenoic Acid Derivatives and Related Compounds
In this chapter we consider derivatives of carboselenothioic and carbodiselenoic acids, and compounds related to them. Ammonium salts and inner salts...
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Thio-, Seleno-, Telluro-Amides
Recent developments regarding synthetic methods of producing chalogen isologues of amides are reviewed. Among exhaustive studies on the syntheses,...
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Evidences for Polaron Formation in Cuprates
It is widely believed that the essential physics of high temperature superconducting copper oxides are governed by the properties of their...
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Beads Arraying and Beads Used in DNA Chips
The present article draws a general picture of the bead assisted DNA immobilization on chips. The authors wish to present these systems since...
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Phosphinidenes
Of the low-valent organophosphorus compounds phosphinidenes occupy a special place. In ‘free’ phosphinidenes the phosphorus atom carries a single...
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Asymmetric Processes Catalyzed by Chiral (Salen)Metal Complexes
A wide variety of highly selective asymmetric reactions catalyzed by chiral (salen)metal complexes have been disclosed over the past decade. Salen...