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Valence Tautomeric Transition Metal Complexes
Valence d-orbital energies of the first row transition metals are close to the frontier π-orbital energies of o-benzoquinones. Complexes prepared...
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Structural Aspects of Spin Crossover. Example of the [FeIILn(NCS)2] Complexes
The interplay between the spin crossover and the structural properties of the complexes in the solid state is still under investigation. In...
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Electrophoretic mobility of colloidal particles in salt-free media
It is shown that the electrophoretic mobility μ of dilute spherical colloidal particles of radius a, carrying charge Q in a salt-free medium...
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Equilibrium Structure of Dendrimers – Results and Open Questions
We review the problem of the structure of dendrimers in solution. Special emphasis is placed on recent theoretical work and computer simulations of...
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Discrete Organic Nanotubes Based on a Combination of Covalent and Non-Covalent Approaches
Tubular organic nanostructures offering precise control over inner and outer surface functionality represent attractive building blocks for the...
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Cycloaddition Reactions of Group 6 Fischer Carbene Complexes
Group 6 heteroatom-stabilised carbene complexes (Fischer carbene complexes) offer many interesting possibilities to build rings (carbocycles and...
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Photoinduced Reactions of Metal Carbenes in Organic Synthesis
The photoinduced reactions of metal carbene complexes, particularly Group 6 Fischer carbenes, are comprehensively presented in this chapter with a...
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Thio-, Seleno-, and Telluro-Carboxylic Acid Esters
This chapter reviews studies into the preparation of thio-, seleno-, and telluro-carboxylic acid esters (referred to thiol, selenol, and tellurol...
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Nanoscale Lattice Fluctuations in Cuprates and Manganites
Local lattice displacements giving a nanoscale inhomogeneous pattern due to mesoscopic phase separation in the correlated transition metal...
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Essential Heterogeneities in Hole-Doped Cuprate Superconductors
An expanded review of recent pertinent experiments in hole-doped cuprates is presented [1]. These include photoemission, inelastic neutron...
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The Construction and Operation of Anion Sensors: Current Status and Future Perspectives
This chapter is intended to provide an insight into the construction and operation of anion sensing devices, rather than the chemistry of anion...
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Palladium-Catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds
For many years, unactivated alkyl electrophiles that contain β hydrogens were generally regarded as unsuitable partners for palladium-catalyzed...
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Macrocycle Synthesis Through Templation
This review highlights the major advances over the last 5 years in the templated synthesis of carbon-based macrocycles. With selected examples, it...
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Recent Advances in the Chemistry of Difunctionalized Organo-Phosphorus and -Sulfur Compounds
Recent results related to the synthesis and reactivity of organocompounds substituted by both phosphorus and sulfur functional groups are reviewed....
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Donor-Acceptor Complexes of Low-Coordinated Cationic π-Bonded Phosphorus Systems
Cationic low-coordinated π-bonded phosphorus compounds add Lewis donors, such as amines or phosphines. In contrast to the trigonal bipyramide formed...
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Biologically Produced Sulfur
Sulfur compound oxidizing bacteria Sulfur compound oxidizing bacteria produce sulfur as an intermediate in the...
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Ligand Field Theoretical Considerations
The phenomenon of the thermal spin transition, as observed for octahedral transition metal complexes having a d...
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Special Classes of Iron(II) Azole Spin Crossover Compounds
In this chapter, selected results obtained so far on Fe(II) spin crossover compounds of 1,2,4-triazole, isoxazole and tetrazole derivatives are...
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Angular momentum and spectral decomposition of ring currents: aromaticity and the annulene model
By a widely accepted criterion, an aromatic (anti-aromatic) π-conjugated system is one that sustains a global diatropic (paratropic) ring current...