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Rhodium hydride enabled enantioselective intermolecular C–H silylation to access acyclic stereogenic Si–H
The tremendous success of stereogenic carbon compounds has never ceased to inspire researchers to explore the potentials of stereogenic silicon...
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Chiral emergence in multistep hierarchical assembly of achiral conjugated polymers
Intimately connected to the rule of life, chirality remains a long-time fascination in biology, chemistry, physics and materials science. Chiral...
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Agonist-selective activation of individual G-proteins by muscarinic receptors
Selective activation of individual subtypes of muscarinic receptors is a promising way to safely alleviate a wide range of pathological conditions in...
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Fly ash boosted electrocatalytic properties of PEDOT:PSS counter electrodes for the triiodide reduction in dye-sensitized solar cells
Fly ash solid waste from a power plant was applied in a solar cell application for the first time. A doctor blade was used to coat FTO-glass with a...
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Scaffold repositioning of spiro-acridine derivatives as fungi chitinase inhibitor by target fishing and in vitro studies
The concept of “one target, one drug, one disease” is not always true, as compounds with previously described therapeutic applications can be useful...
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Ligand-enabled Ni-catalysed enantioconvergent intermolecular Alkyl-Alkyl cross-coupling between distinct Alkyl halides
α-Tertiary aliphatic amides are key elements in organic molecules, which are abundantly present in natural products, pharmaceuticals, agrochemicals,...
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A Lattice Distortion Theory for Promotor Containing Clathrate Hydrates
A lattice distortion theory for promotor containing clathrate hydrates is formulated using the statistical thermodynamics based model of van der...
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Evolution of the electronic structure in open-shell donor-acceptor organic semiconductors
Most organic semiconductors have closed-shell electronic structures, however, studies have revealed open-shell character emanating from design...
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A new look at imines and their mixture with PC71BM for organic, flexible photovoltaics
Due to its high electron affinity and electron mobility in a wide absorption range of the visible solar spectrum, [6,6]-phenyl-C71-butyric acid...
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Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy
The C–F bond cleavage and C–C bond formation (i.e., carbodefluorination) of readily accessible (per)fluoroalkyl groups constitutes an atom-economical...
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Synthesis, and docking studies of novel heterocycles incorporating the indazolylthiazole moiety as antimicrobial and anticancer agents
The current study was directed toward develo** a new series of fused heterocycles incorporating indazolylthiazole moiety. The newly synthesized...
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Lithium doped poly(3-hexylthiophene) for efficient hole transporter and sensitizer in metal free quaterthiophene dye treated hybrid solar cells
This work focuses on the role of Lithium doped Poly(3-hexylthiophene)(P3HT) in metal-free quaterthiophene (4T) dye treated Titanium dioxide (TiO 2 )...
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A one-two punch targeting reactive oxygen species and fibril for rescuing Alzheimer’s disease
Toxic amyloid-beta (Aβ) plaque and harmful inflammation are two leading symptoms of Alzheimer’s disease (AD). However, precise AD therapy is...
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Transannular C–H functionalization of cycloalkane carboxylic acids
Cyclic organic molecules are common among natural products and pharmaceuticals
1 ,2 . In fact, the overwhelming majority of small-molecule...
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Functional soft robotic composites based on organic photovoltaic and dielectric elastomer actuator
Improving the energy efficiency of robots remains a crucial challenge in soft robotics, with energy harvesting emerging as a promising approach to...
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Organocatalytic enantioselective dearomatization of thiophenes by 1,10-conjugate addition of indole imine methides
Catalytic asymmetric dearomatization (CADA) is a powerful tool for the rapid construction of diverse chiral cyclic molecules from cheap and easily...
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Unexpected scaffold rearrangement product of pirenzepine found in commercial samples
Pharmacovigilance aims at a better understanding of the molecular events triggered by medications to prevent adverse effects, which despite...
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A replacement strategy for regulating local environment of single-atom Co-SxN4−x catalysts to facilitate CO2 electroreduction
The performances of single-atom catalysts are governed by their local coordination environments. Here, a thermal replacement strategy is developed...
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First theoretical framework for highly efficient photovoltaic parameters by structural modification with benzothiophene-incorporated acceptors in dithiophene based chromophores
Now a days, researchers are constantly doing efforts to upgrade the performance of solar based devices with the aim of increasing the role of...
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Spectroscopic characterization and in vitro studies of biological activity of bradykinin derivatives
Eleven multiple analogs of bradykinin—a peptide that is a natural ligand of B1 and B2 receptors but does not bind or activate the B1 receptor unless...
