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Dopant-induced red emission, paramagnetism, and hydrogen evolution of diluted magnetic semiconductor ZnS: Eu nanoparticles
Cubic-structured europium (Eu) doped zinc sulfide (ZnS) nanoparticles (NPs) were prepared via refluxing at 150 °C. Absolute structural studies showed...
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Intramolecular crossover from unconventional diamagnetism to paramagnetism of palladium ions probed by soft X-ray magnetic circular dichroism
The case of palladium(II) ions in molecular polyoxopalladates highlights the importance of accounting not only for nearest neighbour atoms or ions in...
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A metal–organic framework that exhibits CO2-induced transitions between paramagnetism and ferrimagnetism
With adequate building blocks, metal–organic frameworks (MOFs) can combine magnetic ordering and porosity. This makes MOFs a promising platform for...
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Indole-5,6-quinones display hallmark properties of eumelanin
Melanins are ubiquitous biopolymers produced from phenols and catechols by oxidation. They provide photoprotection, pigmentation and redox activity...
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Rhodamine B- and coumarin-modified chitosan as fluorescent probe for detection of Fe3+ using quenching effect
Iron ion is an essential metal ion that plays a crucial role in various metabolic processes in living organisms. It is involved in cellular...
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o-Benzoquinone Cobalt Complexes Bearing Organosilicon Radicals: Quantum-Chemical Study
AbstractA computer modeling (DFT UTPSSh/6-311++G(d,p)) of electronic structures, geometric parameters, energy characteristics, and magnetic...
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Heterospin iron complexes with dioxolenes functionalized with stable radicals: quantum chemical study
A computational modeling (DFT UTPSSh/6-311++G(d,p)) of the electronic structures, energy characteristics, and magnetic properties of mononuclear iron...
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Nanozymes for Bioimaging and Disease Diagnostics
Nanozymes are nanomaterials exhibiting enzymatic properties. Nanozymes are increasingly popular due to their ability to overcome the limitations of... -
Insight to an efficient and magnetic α-Fe2O3/γ-Fe2O3/Cu2O hybrid catalysis for peroxymonosulfate: preparation, performance, and mechanism
The development of catalysts with high catalytic activity and convenient recycling property is the long-term goal of sulfate-based advanced oxidation...
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Quenching of magnetism in NaO2 due to electrostatic interaction induced partial orbital ordering
The transport properties of sodium superoxide (NaO 2 ) are governed by the transfer of charge between O 2 − complexes. Although it goes through a...
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Quantum-Chemical Study of Cobalt Complexes with o-Quinones Modified with Silicon Triangulene Derivatives
AbstractComputational modeling (DFT UB3LYP/6-311++G(d,p)) of the spatial structure, energy parameters, and magnetic properties of the adducts of...
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Upconversion of NaYF4: Yb, Er Nanoparticles Co-doped with Zr 4+ for Magnetic Phase Transition and Biomedical Imaging Applications
Tracking of cancer cells and cytotoxicity of normal tissue are the leading problem in cancer treatment. The magnetic and fluorescent multifunctional...
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Electronic Structure and Magnetic Properties of Mixed-Ligand Cobalt Complexes Containing Organogermanium Triangulenes
AbstractComputational modeling of cobalt(II) diketonate adducts with o -benzoquinones modified with organogermanium triangular cycles of different...
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Structural characterization and reactivity of a room-temperature-stable, antiaromatic cyclopentadienyl cation salt
The singlet states of cyclopentadienyl (Cp) cations are considered as true prototypes of an antiaromatic system. Unfortunately, their high intrinsic...
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Magnetic Properties
Magnetic properties play a role in many food and packaging materials in the field of food technology, as well as in sensors and nuclear resonance... -
Magnetism
A special feature of the transition metals (d elements), but also of the lanthanides and actinides (f elements), compared to the main group elements... -
Paramagnetism of Fex(Cu0.5In0.5)1– xCr2S4 Solid Solutions
Abstract —We have synthesized Fe x (Cu 0.5 In 0.5 ) 1 – x Cr 2 S 4 solid solutions and measured their magnetic properties in the temperature range 4.2–300 K in...
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Rare–Earths–Nickel–Boron Compounds
The R-Ni-B phase diagrams, where R is a rare earth and yttrium, evidenced the presence of 27 series of ternary compounds. The number of compounds in... -
Magnetic Parameters and Magnetic Functions in Mononuclear Complexes Beyond the Spin-Hamiltonian Formalism
Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Λ-tensor involving only the matrix... -
ESR Spectroscopy in Geochemical Studies of Asphaltenes of Crude Oils from Tatarstan Oil Fields
AbstractESR spectra of asphaltenes from a series of crude oils from the Devonian and Carboniferous deposits of the South-Tatar Dome in Tatarstan with...