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Chemoselectivity of Nitroxylation of Cage Hydrocarbons
AbstractThe composition of reaction mixtures obtained by nitroxylation of 13 cage hydrocarbons with 100% nitric acid and its mixtures with acetic...
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Selective Nitroxylation of Adamantane Derivatives in the System Nitric Acid–Acetic Anhydride
AbstractA number of new nitroxyadamantanes have been synthesized by nitroxylation of the corresponding substrates with nitric acid in acetic...
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Synthesis and Chemical Transformations of 1-Aryladamantanes
Abstract1-Aryladamantanes were synthesized, and their transformations in fuming nitric acid were studied. The nitroxylation of the saturated...
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Protective Effects in the Radiolysis of Acidified Hydrocarbon Solutions of Tributyl Phosphate
AbstractThe effect of radiolysis and postradiation acid hydrolysis on the composition of the degradation products of tributyl phosphate (TBP, 30 wt...
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Thermal and Hydrolytic Stability of Irradiated Tri-n-Butyl Phosphate
AbstractThe dominant radiolytic transformation of tributyl phosphate is the elimination of butoxy and butyl groups with the formation of...
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Synthesis of 3,5-Bis(hydroxymethyl)adamantan-1-ols and 3,5-Bis(nitrooxymethyl)adamantan-1-yl Nitrates
AbstractA convenient method has been developed for the synthesis of 3,5-bis(hydroxymethyl)adamantan-1-ols via successive nitroxylation of...
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Synthesis of Diamantane Derivatives in Nitric Acid Media
Abstract1-Mono- and 1,4-difunctional diamantane derivatives were synthesized by the reaction of diamantane with nitric acid or a HNO 3 –AcOH mixture...
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Reaction of 1,3,5,7-Tetramethyladamantane with Nitric Acid
AbstractThe reaction of 1,3,5,7-tetramethyladamantane with fuming nitric acid leads to a mixture of 1,3,5,7-tetramethyladamantane-2,6-dione and syn / anti...
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Kinetic Study of the Nitrolysis of Haloadamantanes
AbstractThe kinetics of nitrolysis of haloadamantanes containing halogen atoms in the bridging and bridgehead positions with fuming nitric acid have...
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Effect of vaporization on thermal stability of model PUREX-process raffinates
The aqueous phase formed during the regeneration of the irradiated extractant contains organic products that degrade into gases upon heating and...
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Radiation-induced effects during the extraction of Pu-239 nitrate with a solution of tributyl phosphate in octafluoropentanol formal
Extractive treatment of ≥ 0.2 M 239 Pu solution in an acidified mixture of tributyl phosphate and octafluoropentanol formal is accompanied by...
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Synthesis of (3-Hydroxyadamantan-1-yl)methanols
A convenient procedure has been developed for the synthesis of (3-hydroxyadamantan-1-yl)-methanols on the basis of nitroxylation of...
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Synthesis of Cage Acylamino Derivatives in Nitric Acid Medium
AbstractAn efficient procedure has been developed for the synthesis of secondary amides by the Ritter reaction of cage substrates with a wide series...
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Synthesis of Substituted Bridged Carboxylic Acids of the Adamantane Series
AbstractA number of new 1,3,6- and 1,4,4-tri- and 1,3,6,6-tetrasubstituted polyfunctional derivatives were synthesized starting from bridged...
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One-pot synthesis of cage alcohols
An efficient one-pot procedure has been developed for the synthesis of cage alcohols with hydroxy groups in the bridgehead positions. The procedure...
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Synthesis of diacetylamino and diamino derivatives of adamantane series
1,3-Diacetylamino derivatives were synthesized directly from adamantane series hydrocarbons or from adamantan-1-ylacetic acids by a one-pot method...
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Synthesis of nitroxy- and hydroxy-substituted polycarboxylic acids of the adamantane series
Functionalization of polycarboxylic acids of the adamantane series in strongly acidic media afforded their nitroxy- and hydroxy-substituted...
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Modern Trends of Organic Chemistry in Russian Universities
This review is devoted to the scientific achievements of the departments of organic chemistry in higher schools of Russia within the past decade.
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3-(1-Adamantyl)Furazans
The reactivity of 3-(1-adamantyl)-4-aminofurazan was studied. Upon treatment with oxidizing reagents the amino group is oxidized to azo, azoxy, and...
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Mechanisms of activation of C—H bonds in framework compounds: theory and experiment
On the basis of the data from experiments and from modern quantum-chemical calculations using framework hydrocarbons (adamantane, diamondoids, etc.)...
