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Metal complex catalysts broaden bioorthogonal reactions
Bioorthogonal reactions involving transition metals have diversified applications in imaging, drug development, chemical catalysis and other fields....
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Chiral-at-Metal Complexes as Asymmetric Catalysts
In general, asymmetric catalysts are based on the combination of a chiral organic ligand and a metal ion. Here we show that future research should...
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Metal Carbene Reactions from Dirhodium(II) Catalysts
The dirhodium(II) core is a template onto which both achiral and chiral ligands are placed so that four exist in a paddle wheel fashion around the...
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Mo-V-Based Crystalline Complex Metal Oxide Catalysts
Mo-V-based crystalline complex metal oxide for selective oxidation is one of the most successful solid catalysts and is constructed with crystalline...
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Catalysis Chemistry of Crystalline Complex Metal Oxide Catalysts
Crystalline metal oxide catalysts have contributed to the development of various catalytic reactions for many years and are expected more by the way...
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Metal Phosphates/Phosphonates as Catalysts for HER
As the cleanest renewable resource with the highest gravimetric energy density, hydrogen fuel is considered the preferred alternative to fossil fuels...
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Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts
This chapter summarizes recent advances of group 10 transition metal hydrosilylation catalysts from 2015 onward. Since the discovery of Speier’s...
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Dehydrogenation of Alcohols Using Transition Metal Catalysts: History and Applications
Dehydrogenation of primary or secondary alcohols promoted by transition metal catalysts is the key initial step in many transformations involving...
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Active Pd(II) Complexes as Either Lewis Acid Catalysts or Transition Metal Catalysts
The new frontier of asymmetric catalyses by Pd(II) complexes is reviewed. Asymmetric catalyses of carbon–carbon bond formation by Pd(II) complexes...
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Overview of Crystalline Metal Oxide Catalysts
Crystalline metal oxide catalysts are classified into single atomic type, molecular discrete oxide cluster type, supported oxide cluster type,...
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Double Metal Cyanide (DMC) Catalysts: Synthesis, Structure, and Action Mechanism (A Review)
AbstractDouble metal cyanide (DMC) catalysts have no alternatives for use in the industrial process of propylene oxide (PO) polymerization to obtain...
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(Co)polymerization Reactions with Participation of Cyclic Monomers Catalyzed by Double Metal Cyanide Catalysts
AbstractDouble metal cyanide catalysts are unique heterogeneous catalysts having no alternative in the industrial polymerization of propylene oxide...
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Non-noble metal-based catalysts for acetylene semihydrogenation: from thermocatalysis to sustainable catalysis
Selective semihydrogenation of acetylene in raw olefin streams to ethylene is a key industrial reaction to produce polymer-grade feeds for the...
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CO2 Conversion via MOF-Based Catalysts
Metal–organic framework (MOF)-based catalysts have attracted significant attentions for their distinguished characteristics in CO2 conversion, such...
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Liquid phase oxidation of cyclopentanone over metal-free carbon catalysts
Oxidation of cyclopentanone (CPO) was studied over metal-free carbon catalysts in solvent-free conditions. Norit SX plus (900 m 2 g −1 ) and Vulcan XC72...
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Combinations of electron and proton donors in transition-metal complex mediated nitrogen reduction reactions
Nitrogen fixation is a complex process involving the transfer of six electrons and protons. Diverging from the conventional Haber-Bosch process,...
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Spectroscopic Characterization of Organometallic Centers on Insulator Single Crystal Surfaces:From Metal Carbonyls to Ziegler--Natta Catalysts
A detailed knowledge of the microscopic properties is one of the prerequisites for an understanding of heterogeneous catalysts. A strategy which...
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Miniature physical sphere-in-contact models of heterogeneous catalysts and metal nanoparticles
ContextPhysical molecular models have played a fundamental role in the understanding of chemical reactions on heterogeneous catalysts and on metal...
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Glucose oxidase and metal catalysts combined tumor synergistic therapy: mechanism, advance and nanodelivery system
Cancer has always posed a significant threat to human health, prompting extensive research into new treatment strategies due to the limitations of...
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Noncorrosive Metal Complex Catalysts for Oxidation of Hydrogen Sulfide and Mercaptans in Petroleum Products
AbstractHigh activity of metal complex catalytic systems comprising nitrogenous bases and copper sulfates, acetates, and basic carbonate in...
