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Catalysts for Liquid-Phase Oxidation of Organic Compounds with Hydrogen Peroxide: Homogeneous and Phase Transfer Systems
AbstractThe review presents a comparative analysis of promising homogeneous metal complex catalysts and the results of studies on the synthesis and...
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Homogeneous and Heterogeneous α-Diimine Ni(II) Catalysts with Asymmetric Fluorine-Containing Diphenylmethyl Substituents for the Polymerization of Ethylene
To improve the thermal stabilities and polymerization activities of α-diimine nickel catalysts, two asymmetric nickel complexes, Cat1 and Cat2, ...
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Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts
The Mo/Fe nitrogenase enzyme is unique in its ability to efficiently reduce dinitrogen to ammonia at atmospheric pressures and room temperature....
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Homogeneous Redox Catalysts Based on Heteropoly Acid Solutions: 5. Develo** a Two-Stage Process for Propylene Oxidation to Acetone: A Review
AbstractStudies on the development of a homogeneous chloride-free two-stage process (target reaction (first stage) and catalyst regeneration (second...
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Solid catalysts for the dehydrogenation of long-chain alkanes: lessons from the dehydrogenation of light alkanes and homogeneous molecular catalysis
Long-chain alkanes are abundant feedstocks supplied by natural resources and chemical industry. Specially, normal long-chain alkanes are primary...
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Oxidation Using Ruthenium Catalysts
Among the catalysts which have potential for use in selective oxidations, ruthenium takes a special position owing to its versatility. Ruthenium can...
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Immobilization and Study of Homogeneous Catalysts in a Continuous Flow Reactor Using Inorganic Particles Coated with Polymer
We demonstrated that organometallic catalysts can be immobilized in a gas-phase packed bed reactor (PBR) by coating inorganic particles with a...
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Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts
This chapter summarizes recent advances of group 10 transition metal hydrosilylation catalysts from 2015 onward. Since the discovery of Speier’s...
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CO2 Conversion via MOF-Based Catalysts
Metal–organic framework (MOF)-based catalysts have attracted significant attentions for their distinguished characteristics in CO2 conversion, such...
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Homogeneous Catalysis for H-P Bond Addition Reactions
Although patents disclosed transition metal-catalyzed addition of PH3 to formaldehyde and acrylonitrile more than four decades ago, exploration into...
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Eco-friendly Catalysts Revolutionizing Energy and Environmental Applications: An Overview
Catalysts are essential for accelerating chemical reactions without altering the reaction itself. They can be homogeneous or heterogeneous, with...
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Non-covalent Immobilization of Catalysts Based on Chiral Diazaligands
The immobilization of chiral catalysts through non-covalent methods, as opposed to covalent immobilization, allows an easier preparation of chiral...
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Octahedral Zirconium Complexes as Polymerization Catalysts
The synthesis and X-ray structure of various octahedral zirconium complexes and their catalytic properties in the polymerization of α-olefins are...
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Knölker-Type Catalysts for (Asymmetric) Hydrogenation Reactions
The catalytic capabilities of Knölker-type complexes, mostly in the context of (transfer) hydrogenation chemistry, have been intensively studied...
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Parts-Per-Million (Salen)Fe(III) Homogeneous Catalysts for the Production of Biodiesel from Waste Cooking Oils
This work describes the application of a library of iron(III)-salen catalysts in the production of biodiesel from vegetable oils. The conversion of...
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Computational Studies on the Mechanisms for Deaminative Amide Hydrogenation by Homogeneous Bifunctional Catalysts
The deaminative hydrogenation of amides is one of the most convenient pathways for the synthesis of amines and alcohols. The ideal source of reducing...
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Catalysts for Carbonylation of Alcohols to Obtain Carboxylic Acids and Esters
AbstractCarbonylation of alcohols with CO is one of synthetic routes to carboxylic acids and esters, which are demanded by chemical and...
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Supported VPO Catalysts for Maleic Anhydride by Atomic Layer Deposition
The preparation of vanadium-phosphate catalysts by Atomic Layer Deposition (ALD) was studied for application to selective oxidation of n-butane to...
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Metal Phosphates/Phosphonates as Catalysts for HER
As the cleanest renewable resource with the highest gravimetric energy density, hydrogen fuel is considered the preferred alternative to fossil fuels...