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Preparation of hydrophilic poly(vinyl alcohol)-containing amphiphilic diblock copolymers and their self-association in water
A series of amphiphilic diblock copolymers (PVA m - b -PVPi n : A m P n = A 82 P 6 , A 72 P 26 , and A 70 P 74 ) with different block lengths of hydrophilic poly(vinyl...
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Microphase Separation of Semiflexible Ring Diblock Copolymers
Aiming at the difficult problem of solving the conformation statistics of complex polymers, this study presents a novel and concise conformation...
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Properties of Solutions of Amphiphilic Diblock and Random Copolymers of 2-Perfluorohexylethyl Methacrylate and 2-Hydroxyethyl Methacrylate and Coatings Based on Them
AbstractThe study addresses the relationship between the structure of solutions of amphiphilic diblock and random copolymers of...
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Self-assembly of Amphiphilic Diblock Copolymers Induced by Liquid-Liquid Phase Separation
The liquid-liquid phase separation (LLPS) widely exists in biology, synthetic chemistry, crystallization kinetics and other fields, and it is very...
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Water-soluble polymer micelles formed from amphiphilic diblock copolymers bearing pendant phosphorylcholine and methoxyethyl groups
Amphiphilic diblock copolymers (M 98 E n ) composed of hydrophilic poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC, M) and hydrophobic...
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Diblock copolymers poly(3-hexylthiophene)-block-poly(2-(dimethylamino)ethyl methacrylate-random-1-pyrenylmethyl methacrylate), controlled synthesis and optical properties
In this research, diblock copolymers based on the rod segment of regioregular poly(3-hexylthiophene) (P3HT) and a coil segment of...
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Omniphobic Coatings Based on Amphiphilic Diblock Copolymers of 2-(Perfluorohexyl)ethyl Methacrylate and 2-Hydroxyethyl Methacrylate
AbstractAmphiphilic diblock copolymers of 2-(perfluorohexyl)ethyl methacrylate and 2-hydroxylethyl methacrylate have been synthesized for the first...
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Patternable Block Copolymers
This article is a review of the chemical and physical nature of patternable block copolymers and their use as templates for functional... -
Synthesis of Block Copolymers
This review highlights recent (2000-2004) advances and developments regarding the synthesis of block copolymers with both linear [AB diblocks, ABA... -
Water Solutions of Amphiphilic Polymers: Nanostructure Formation and Possibilities for Catalysis
A concept of amphiphilicity in application to monomer units of water-soluble polymers is presented. Molecular simulation and experimental studies... -
Controlled synthesis and optical investigation of conjugated rod-coil diblock copolymer based on poly(3-hexylthiophene) and poly(2-(dimethylamino)ethyl methacrylate-random-1-pyrenylmethyl methacrylate-random-methacrylate spirooxazine)
This research presents a conjugated rod–coil diblock copolymer P3HT- b -P(DMAEMA- r -PyMA- r -MSp) which was synthesized by a combination of the Kumada...
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pH-responsive amphiphilic copolymers based on N-vinylpyrrolidone and fluoroacrylates with different structures: synthesis via RAFT process and surface properties
The copolymerization of 1,1,1,3,3,3-hexafluoroisopropylacrylate (HFIPA) and 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) with N-vinylpyrrolidone...
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Self-assembly induced by complexation of diblock copolyelectrolytes and oppositely charged homopolymers
We investigate the solution self-assembly of a mixture of positively charged homopolymers and AB diblock copolymers, in which the A blocks are...
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Synthesis, Thermoresponsive Behavior, and Catalytic Properties of Amphiphilic Diblock Copolymers of N-Vinylcaprolactam and N-Vinylimidazole
AbstractThermoresponsive diblock copolymers (DCs) were prepared by two-stage reversible addition-fragmentation chain transfer/macromolecular design...
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Recent Advances in Helical Polyisocyanide-based Block Copolymers: Preparation, Self-assembly and Circularly Polarized Luminescence
P olyisocyanides and their block copolymers have widespread applications in many fields due to their unique helix and self-assembly properties. At...
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Conformation of an Amphiphilic Comb-like Copolymer in a Selective Solvent
We study the conformation of an amphiphilic comb-like copolymer in a selective solvent by using Brownian dynamics simulations. Our results...
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Solution Properties of Polypeptide-based Copolymers
The aggregation behaviour of biomimetic polypeptide hybrid copolymers and copolypeptides is here reviewed with a particular eye on the occurrence... -
Well-defined amphiphilic poly(ε-caprolactone)-b-poly(N-isopropylacrylamide) and thermosensitive micelles formulation
Polymeric nanoparticles, based on amphiphilic copolymers, have been extensively evaluated as a potential material for drug delivery systems (DDS),...
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Microphase separation of double-hydrophilic poly(carboxybetaine acrylate)-poly(2-methoxyethyl acrylate) block copolymers in water
The microphase separation of double-hydrophilic block copolymers in water is of interest when these copolymers are utilized as molecular assemblies...
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Synthesis of functional fluorinated copolymers with different microstructure via reversible addition-fragmentation chain transfer (RAFT) process
Fluoropolymers are attractive due to their high resistance to external influences. However, they are poorly compatible with other materials (for...