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Synthesis of 1-(1-Adamantyl)-2-[4-(1H-imidazol-1-ylmethyl)phenoxy]ethanone Derivatives
AbstractTwo methods have been developed for the first synthesis of 1-(1-adamantyl)-2-[4-(1 H -imidazol-1-ylmethyl)phenoxy]ethanone derivatives by the...
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Reactions of 1,3-dehydroadamantane with polyfluorinated alcohols
A one-step synthesis of hard-to-reach adamantyl polyfluoroalkyl ethers in yields up to 95% comprises the reaction of strained 1,3-dehydroadamantane...
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Synthesis of 1-(4-Alkoxybenzyl)-1H-(benz)imidazoles
AbstractN -Alkylation of 1 H -imidazole and 1 H -benzimidazole with 4- n -octyloxybenzylchloride, 4- n -hexadecyloxybenzylchloride and...
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1,3-Dehydroadamantane and Its Derivatives: A Versatile Synthetic Platform for the Preparation of Functional Compounds with a Cage Structure. A Review
AbstractA promising strategy in the synthesis of functional compounds with a cage structure is the use of 1,3-dehydroadamantane (tetracyclo[3.3.1.1. 3,7...
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Reaction of Adamantan-1-ol with Lower Alcohols in the Presence of CuBr2
AbstractThe reaction of adamantan-1-ol with lower alcohols (methanol, ethanol) in the presence of water and an equimolar amount of CuBr 2 (with...
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Metal Complex Catalysis in the Synthesis of Ethers
The review systematizes and generalizes modern approaches to the synthesis of ethers using metal complex catalysts.
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Catalytic atroposelective synthesis
Atropisomeric architectures are increasingly encountered in modern materials and medicinally important compounds. More importantly, they are now a...
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The Multifaceted Chemistry of Variously Substituted α,β-Unsaturated Fischer Metalcarbenes
The insertion of an alkyne into an α,β-unsaturated Fischer metalcarbene complex leads to a 1-metalla-1,3,5-hexatriene. This usually undergoes...
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Synthesis of polymers carrying adamantyl substituents in side chain
This review addresses the synthesis of various polymers carrying bulky and rigid adamantyl substituents in their side chains. Synthetic methods for...
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Iron and Manganese Catalyzed Hydrosilylation Reactions
Hydrosilylation reaction has emerged as an important strategy for the preparation of silicone polymers and functionalized silanes. Most of the...
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The Use of N-Heterocyclic Carbenes as Ligands in Palladium-Mediated Catalysis
Recent developments in the use of N-heterocyclic carbenes (NHC) as ligands in palladium-mediated transformations are described. These versatile...
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Synthesis of 1-, 2-Methoxy-, 1,3-Dimethoxyadamantanes And 1-, 4-Methoxydiadamantanes by Reaction of Adamantyl and Diadamantyl Halides with Dimethyl Carbonate in the Presence of Zeolite Catalysts
1-, 2-Methoxy-, 1,3-dimethoxyadamantane, and 1-, 4-methoxydiadamantane were prepared by the reaction of adamantyl and diadamantyl halides with...
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Chemical Amplification Resists for Microlithography
This chapter describes polymers employed in formulation of chemically amplified resists for microlithography, which have become the workhorse in...
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Redox-Active Germylene Based on 2,4,6,8-Tetra-tert-butylphenoxazin-1-one: Synthesis, Structure, and Chemical Properties
AbstractNew complex of low-valent germanium Phenox APGe ( I ) based on the redox-active ligand 2,4,6,8-tetra- tert -butylphenoxazin-1-one is synthesized...
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Microwave-Assisted Multicomponent Reactionsfor the Synthesis of Heterocycles
Multicomponent reactions offer convenient procedures for the introduction of many points of structural diversity into heterocyclic compounds...
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Adamantyl-substituted ligands of colchicine binding site in tubulin: different effects on microtubule network in cancer cells
Four novel conjugates of adamantane connected at a bridgehead position via four-bond linker to structurally different ligands interacting with...
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Diene, Enyne, and Diyne Metathesis in Natural Product Synthesis
With the commercial availability of well-defined ruthenium metathesis catalysts which combine high stability and broad functional group...
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Donor-Acceptor Complexes of Low-Coordinated Cationic π-Bonded Phosphorus Systems
Cationic low-coordinated π-bonded phosphorus compounds add Lewis donors, such as amines or phosphines. In contrast to the trigonal bipyramide formed...
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Conformational energies of reference organic molecules: benchmarking of common efficient computational methods against coupled cluster theory
We selected 145 reference organic molecules that include model fragments used in computer-aided drug design. We calculated 158 conformational...
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Alkyne synthesis through coupling of gem-diborylalkanes with carboxylic acid esters
Alkynes are fundamental molecular building blocks of great importance in synthetic chemistry and materials science. The efficient construction of...
