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Thiobenzamide-based ruthenium complexes: chemical reactivity and promising biological investigations against Leukemia cancer cells
Two new metal complexes containing the ligand thiobenzamide (TBz), with the formula cis -[RuCl(TBz)(L) 2 ]PF 6 , where L = 2,2’-bipyridine (bpy) or...
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Synthesis of 3-Alkyl-5-(diethylaminomethyl)-1-(1,3-thiazol-4-yl)-1H-pyrazoles
Abstract3-Alkyl-5-(diethylaminomethyl)pyrazoles reacted with chloroacetyl chloride to give 1-chloroacetyl derivatives which were subjected to...
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CRYSTAL STRUCTURE OF HETEROLIGAND ZINC(II) COMPLEXES WITH PHOSPHORYLATED THIOAMIDE AND DIIMINES
AbstractMolecular and crystal structures of two octahedral zinc complexes with chelated N-phosphorylated thiobenzamide ligands and nitrogen bidentate...
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Sterically crowded thioamides: deviations from planarity as determined by X-ray structure analyses and quantum chemical calculations
The structures of selected thiobenzamides and some corresponding benzamides with two more or less bulky N-substituents have been studied by...
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Thiazole Synthesis by Thionation of C=O to C=S
The heterocyclic compounds play an important role in the construction and exploration of novel physiological/biologically active compounds. The...
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Structure of Two Complexes of N-Thiophosphorylated Thioamides with a Silver(I) Cation and Triphenylphosphine
In order to study the complexation properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula...
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Spiroheterocyclization of Pyrrolobenzoxazinetriones under the Action of Thiobenzamide. Synthesis of Spiro[thiazolo-5,2′-pyrroles]
3-Acylpyrrolo[2,1- c ][1,4]benzoxazine-1,2,4-triones regioselectively react with thiobenzamide forming substituted spiro[thiazolo-5,2′-pyrroles], whose...
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Synthesis, Structure, and Properties of the Iron Nitrosyl Complex with 2-Ethyl-4-pyridinecarbothioamide
AbstractThe synthesis and data on the physicochemical characteristics and biological activity of the new iron nitrosyl complex (Q + ) 2 [Fe 2 (S 2 O 3 ) 2 (NO) 4 ]
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Sigmatropic rearrangements of B(MIDA)-propargylic alcohols towards the diverse synthesis of α-functionalized organoborons
α-Functionalized organoborons are useful building blocks and key structural elements in functional molecules. Their previous synthesis relied on the...
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Metal Complexes as DNA Cleavage and Antimicrobial Agents
In this chapter it is presented an overview regarding some examples presented in the literature regarding photochemical applications of metal...
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Microwave-Assisted Synthesis, Characterization, Docking Studies and Molecular Dynamic of Some Novel Phenyl Thiazole Analogs as Xanthine Oxidase Inhibitor
A series of novel substituted 2-(4-bromophenyl)-4-phenylthiazole compounds 5a–h were synthesized by a simplified two-step process. First, the...
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Design, synthesis and fungicidal activities evaluation of N-(thiazol-4-ylmethyl) benzenesulfonamide derivatives
A series of N- (thiazol-4-ylmethyl) benzenesulfonamide derivatives were designed, synthesized, and characterized by 1 H NMR, 13 C NMR, and HRMS. The...
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Thio-, Seleno-, Telluro-Amides
Recent developments regarding synthetic methods of producing chalogen isologues of amides are reviewed. Among exhaustive studies on the syntheses,...
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An Expeditious Ultrasound-Initiated Green Synthesis of 1,2,4-Thiadiazoles in Water
A convenient, environmentally benign, metal- and catalyst-free protocol has been developed for the conversion of thioamides to the corresponding...
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Thiadiazole Synthesis
The heterocyclic compounds are abundant in nature and have attracted more attention because their structural subunits are present in many natural...
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PHOTOCHEMISTRY OF RUTHENIUM NITROSYL COMPLEXES IN SOLIDS AND SOLUTIONS AND ITS POTENTIAL APPLICATIONS
AbstractThe review is devoted to photochemical transformations of ruthenium nitrosyl complexes in various media and their potential applications in...
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Growing Impact of Ionic Liquids in Heterocyclic Chemistry
In the quest for replacing the conventional toxic organic solvents, a continual effort has been made in fabricating a solvent that is versatile,...
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Advancements in the synthesis of oxazolines
Heterocyclic compounds have always gained much recognition in synthetic organic chemistry. Oxazoline is one of the most important five-membered...
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STRUCTURE OF “COORDINATION OLIGOMERS” BASED ON COMPLEXES OF THIOPHOSPHORYLTHIOUREA COMPOUNDS WITH MONOVALENT COPPER AND SILVER CATIONS
AbstractMolecular and crystal structures of two polynuclear complexes of monovalent silver and copper with chelate thiophosphorylthiocarbamide...
