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Ionic liquid-based nanocomposites for organic transformations
In this review, catalyst as well as solvent nature of ionic liquids in organic transformations has been described. Ionic liquids have been...
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Catalysis of Hydrosilylation Processes with the Participation of Ionic Liquids
Hydrosilylation processes are still most often catalyzed using homogeneous complexes of transition metals (mainly platinum and rhodium). However, due... -
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Growing Impact of Ionic Liquids in Heterocyclic Chemistry
In the quest for replacing the conventional toxic organic solvents, a continual effort has been made in fabricating a solvent that is versatile,... -
MNP Catalysis in Ionic Liquids
Ionic liquids (ILs)Ionic Liquids (ILs) are the green, versatile and alternative fluids in the fabrication of soluble ‘surface-cleanSurface-clean’... -
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Metal Nanoparticles and Cyclodextrins for Catalytic Applications
The development of efficient catalysts in terms of activity and selectivity has always been a major topic for researchers since several decades. The... -
Synthesis and Characterization of a Novel Series of Amphiphilic Mercapto-1,2,4-Triazole Schiff Base Ligands: Investigation of their Behavior in Hydro-Organic Solutions
A novel series of four Schiff base amphiphiles derived from 3-mercapto-1,2,4-triazole and different alkyl chains were successfully prepared by a new...
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Oxidative desulfurization of fuels using ionic liquids: A review
Extractive oxidation, wherein aromatic sulfurcontaining compounds are extracted and subsequently oxidized to their corresponding sulfones, has proven...
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Preparation of 3,4-dihydropyrimidones via Biginelli reaction in efficient and recyclable PEG1000-DAIL/toluene catalyst-medium combined thermoregulated biphasic system
A facile and efficient protocol for the synthesis of 3,4-dihydropyrimidones via one-pot Biginelli reaction in PEG 1000 -DAIL/toluene system was...
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Ionic Liquids in Transition Metal-Catalyzed Hydroformylation Reactions
The latest state of the art in ionic liquid-based hydroformylation is reviewed in detail in this chapter. This multiphase homogenous catalytic system... -
Pd Nanoparticles in the Thermoregulated Ionic Liquid and Organic Biphasic System: An Efficient and Recyclable Catalyst for Heck Reaction
AbstractA thermoregulated ionic liquid and organic biphasic system composed of ionic liquid [CH 3 (OCH 2 CH 2 ) 16 N + Et 3 ][CH 3 SO 3 − ] (IL PEG750 ) with IL PEG750 -...
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A Novel Thermoregulated Ionic Liquid and Organic Biphasic System With Rh Nanoparticles for Olefin Hydroformylation
AbstractA thermoregulated ionic liquid and organic biphasic system composed of quaternary ammonium-based ionic liquid N , N -dimethyl- N -(2-(2-methoxyethoxy)ethyl)-...
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Efficient and convenient oxidation of alcohols to aldehydes and ketones with H2O2/(NH4)6Mo7O24·4H2O regulated by PEG1000-DIL/methylcyclohexane temperature-dependent biphasic system
AbstractA simple and efficient method for the oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones with H 2 O 2 /(NH4) 6 Mo...
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Efficient dichloromethylation of some aromatic hydrocarbons catalyzed by a new ionic liquid [C12minPEG800]Br under homogeneous catalysis in aqueous media
A series of new imidazolium-type ionic liquids based on polyethylene glycol have been prepared. The new recyclable temperature-dependant...
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Biphasic and Flow Systems Involving Water or Supercritical Fluids
Two processes are described for improving reaction rates for relatively hydrophobic substrates in aqueous biphasic systems. In the first,...
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Reactions In Non-Conventional Media For Sustainable Organic Synthesis
The growing awareness of the pressing need for greener, more sustainable technologies has focused attention on the use of atom efficient catalytic... -
Temperature-induced chirality reversal of induced circular dichroism of premicellar aggregates of acridine orange derivatives and dodecanoyl-l-threonine in aqueous solution
Circular dichroism (CD) and absorption spectra were measured for acridine orange derivatives: 3,6-bis(dimethylamino) acridine (AO),...